cpomaemКоррозия: защита материалов и методы исследованийTitle in englishИФХЭ РАН10.61852/2949-3412-2025-3-2-148-168cpomaem-104Research ArticleСтатьиЗащита металлов тонкими гидрофобными покрытиямиProtection of metals with thin hydrophobic coatingsСемилетовА. М.SemiletovA. M.

119071, Москва, Ленинский проспект, д. 31, корп. 4

31-4, Leninsky prospect, 119071 Moscow

КузнецовЮ. И.KuznetsovYu. I.

119071, Москва, Ленинский проспект, д. 31, корп. 4

31-4, Leninsky prospect, 119071 Moscow

kuznetsov@ipc.rssi.ruФедеральное государственное бюджетное учреждение науки Институт физической химии и электрохимии им. А.Н. Фрумкина Российской академии наукРоссияA.N. Frumkin Institute of Physical Chemistry and Electrochemistry Russian Academy of SciencesRussian Federation20251307202502148168Copyright © Семилетов А.М., Кузнецов Ю.И., 20252025Семилетов А.М., Кузнецов Ю.И.Semiletov A.M., Kuznetsov Y.I.This work is licensed under a Creative Commons Attribution 4.0 License.https://www.cpmrm.ru/jour/article/view/104

В статье рассматривается возможность гидрофобизации поверхности металлов и сплавов, как способ замедления их коррозии в агрессивной среде. Эффективность гидрофобной обработки во многом зависит от природы металла, гидрофобного реагента и растворителя. В некоторых случаях возможна пассивация металлов. Формирование тонкого гидрофобного защитного покрытия на металлах осуществляется не только из органических, но и водных растворов, в которых важную роль играет хемосорбция гидрофобного агента. Показана возможность повышения устойчивости гидрофобной поверхности алюминиевого сплава АМг6 и его пассивного состояния при обработке водным раствором олеилсаркозината натрия с добавлением в него аминоэтиламинопропилтриметоксисилана. Рассмотрены способы гидрофобизации меди и ее зашита триазолами, тиазолами и смесевыми ингибиторами коррозии на их основе, а также алкантиолами.

The article discusses the possibility of hydrophobization of the metal surface as a way to reduce their corrosion in an aggressive environment. The effectiveness of hydrophobic treatment depends on the metal, the hydrophobic reagent and the solvent. In some cases, passivation of metals is possible. Formation of a thin hydrophobic protective coating on metals is carried out not only from organic, but also from aqueous solutions, in which chemisorption of the hydrophobic agent plays an important role. The possibility of increasing the stability of the hydrophobic surface of the aluminum alloy AMg6 and its passive state during treatment with an aqueous solution of sodium oleyl sarcosinate with the addition of aminoethylaminopropyltrimethoxysilane is shown. Methods of copper hydrophobization and its protection with triazoles, thiazoles and mixed corrosion inhibitors based on them, as well as alkanethiols are considered.

коррозияингибиторы коррозииадсорбцияпассивациягидрофобизацияcorrosioncorrosion inhibitorsadsorptionpassivationhydrophobizationИсследование выполнено в рамках НИОКТР (2025−2027 гг.): «Развитие физикохимических основ процессов коррозии металлов и сплавов и методов их защиты», (Регистрационный номер 125012200581-1)ReferencesR.A. Scherrer and S.M. Howard, Use of distribution coefficients in quantitative structure-activity relationships, J. Med. Chem., 1977, 20, no. 1, 53−58. doi: 10.1021/jm00211a010R.A. Scherrer and S.M. Howard, Use of distribution coefficients in quantitative structure-activity relationships, J. Med. Chem., 1977, 20, no. 1, 53−58. doi: 10.1021/jm00211a010J.I. Bregman, Corrosion inhibitors, Macmillan, New York, 1963, 320 pp.J.I. Bregman, Corrosion inhibitors, Macmillan, New York, 1963, 320 pp.Yu.I. Kuznetsov and G.V. Redkina, Thin protective coatings on metals formed by organic corrosion inhibitors in neutral media, Coatings, 2022, 12, no. 2, 149. doi: 10.3390/coatings12020149Yu.I. Kuznetsov and G.V. Redkina, Thin protective coatings on metals formed by organic corrosion inhibitors in neutral media, Coatings, 2022, 12, no. 2, 149. doi: 10.3390/coatings12020149Yu.I. Kuznetsov, Organic inhibitors of corrosion of metals, Plenum Press, New York and London, 1996, 283 pp. doi: 10.1007/978-1-4899-1956-4Yu.I. Kuznetsov, Organic inhibitors of corrosion of metals, Plenum Press, New York and London, 1996, 283 pp. doi: 10.1007/978-1-4899-1956-4Yu.I. Kuznetsov, Organic corrosion inhibitors: where are we now? A review. Part II. Passivation and the role of chemical structure of carboxylates, Int. J. Corros. Scale Inhib., 2016, 5, no. 4, 282–318. doi: 10.17675/2305-6894-2016-5-4-1Yu.I. Kuznetsov, Organic corrosion inhibitors: where are we now? A review. Part II. Passivation and the role of chemical structure of carboxylates, Int. J. Corros. Scale Inhib., 2016, 5, no. 4, 282–318. doi: 10.17675/2305-6894-2016-5-4-1Yu.I. Kuznetsov, Organic corrosion inhibitors: where are we now? A review. Part III. Passivation and the role of the chemical structure of organophosphates, Int. J. Corros. Scale Inhib., 2017, 6, no. 4, 282–318. doi: 10.17675/2305-6894-2017-6-3-1Yu.I. Kuznetsov, Organic corrosion inhibitors: where are we now? A review. Part III. Passivation and the role of the chemical structure of organophosphates, Int. J. Corros. Scale Inhib., 2017, 6, no. 4, 282–318. doi: 10.17675/2305-6894-2017-6-3-1M. Weinert, J.S. Gutmann and M. Dornbusch, Hydrophobic phytic acid conversion layers for corrosion protection of steel surfaces, J. Coat. Technol. Res., 2024, 21, no. 2, 703–736. doi: 10.1007/s11998-023-00852-wM. Weinert, J.S. Gutmann and M. Dornbusch, Hydrophobic phytic acid conversion layers for corrosion protection of steel surfaces, J. Coat. Technol. Res., 2024, 21, no. 2, 703–736. doi: 10.1007/s11998-023-00852-wH.E. Mohammadloo and A.A. Sarabi, Titanium-phytic acid nano structured conversion coating formation on CRS substrate, Prog. Org. Coat., 2016, 101, 391–399. doi: 10.1016/j.porgcoat.2016.09.009H.E. Mohammadloo and A.A. Sarabi, Titanium-phytic acid nano structured conversion coating formation on CRS substrate, Prog. Org. Coat., 2016, 101, 391–399. doi: 10.1016/j.porgcoat.2016.09.009G. Boisier, N. Portail and N. Pébère, Corrosion inhibition of 2024 aluminium alloy by sodium decanoate, Electrochim. Acta, 2010, 55, no. 21, 6182–6189. doi: 10.1016/j.electacta.2009.10.080G. Boisier, N. Portail and N. Pébère, Corrosion inhibition of 2024 aluminium alloy by sodium decanoate, Electrochim. Acta, 2010, 55, no. 21, 6182–6189. doi: 10.1016/j.electacta.2009.10.080G.A. Salensky, M.G. Cobb and D.S. Everhart, Corrosion inhibitor orientation on steel, Ind. Eng. Chem. Prod. Res. Dev., 1986, 25, no. 2, 133–140. doi: 10.1021/i300022a002G.A. Salensky, M.G. Cobb and D.S. Everhart, Corrosion inhibitor orientation on steel, Ind. Eng. Chem. Prod. Res. Dev., 1986, 25, no. 2, 133–140. doi: 10.1021/i300022a002A.M. Semiletov, Yu.I. Kuznetsov and A.A. Chirkunov, On the hydrophobization of the surface of AMg6 alloy and its protection from atmospheric corrosion by mixtures of higher carboxylates acids, Prot. Met. Phys. Chem. Surf., 2022, 58, no. 7, 1255–1261. doi: 10.1134/S2070205122070140A.M. Semiletov, Yu.I. Kuznetsov and A.A. Chirkunov, On the hydrophobization of the surface of AMg6 alloy and its protection from atmospheric corrosion by mixtures of higher carboxylates acids, Prot. Met. Phys. Chem. Surf., 2022, 58, no. 7, 1255–1261. doi: 10.1134/S2070205122070140G. Boisier, A. Lamure, N. Pébère, N. Portail and M. Villatte, Corrosion protection of AA2024 sealed anodic layers using the hydrophobic properties of carboxylic acids, Surf. Coat. Tech., 2009, 203, no. 22, 3420–3426. doi: 10.1016/j.surfcoat.2009.05.008G. Boisier, A. Lamure, N. Pébère, N. Portail and M. Villatte, Corrosion protection of AA2024 sealed anodic layers using the hydrophobic properties of carboxylic acids, Surf. Coat. Tech., 2009, 203, no. 22, 3420–3426. doi: 10.1016/j.surfcoat.2009.05.008C.C. Landry, N. Pappé, M.R. Mason, A.W. Apblett, A.N. Tyler, A.N. MacInnes and A.R. Barron, From minerals to materials: synthesis of alumoxanes from the reaction of boehmite with carboxylic acids, J. Mater. Chem., 1995, 5, no. 2, 331–341, doi: 10.1039/JM9950500331C.C. Landry, N. Pappé, M.R. Mason, A.W. Apblett, A.N. Tyler, A.N. MacInnes and A.R. Barron, From minerals to materials: synthesis of alumoxanes from the reaction of boehmite with carboxylic acids, J. Mater. Chem., 1995, 5, no. 2, 331–341, doi: 10.1039/JM9950500331M.W. Kendig, A.J. Davenport and H.S. Isaacs, Mechanism of corrosion inhibition by chromate conversion coatings from X-ray absorption near edge spectroscopy (XANES), Cor. Sci., 1993, 34, no. 1, 41–49. doi: 10.1016/0010-938X(93)90257HM.W. Kendig, A.J. Davenport and H.S. Isaacs, Mechanism of corrosion inhibition by chromate conversion coatings from X-ray absorption near edge spectroscopy (XANES), Cor. Sci., 1993, 34, no. 1, 41–49. doi: 10.1016/0010-938X(93)90257HG.P. Shulman and A.J. Bauman, Corrosion protection with organic acid sealants for anodized aluminum, in book: Organic coatings for corrosion control, 1998, 420–422. doi: 10.1021/bk-1998-0689.ch034G.P. Shulman and A.J. Bauman, Corrosion protection with organic acid sealants for anodized aluminum, in book: Organic coatings for corrosion control, 1998, 420–422. doi: 10.1021/bk-1998-0689.ch034G. Žerjav and I. Milošev, Carboxylic acids as corrosion inhibitors for Cu, Zn and Brasses in simulated urban rain, Int. J. Electrochem. Sci., 2014, 9, 2696–2715. doi: 10.1016/S1452-3981(23)07957-9G. Žerjav and I. Milošev, Carboxylic acids as corrosion inhibitors for Cu, Zn and Brasses in simulated urban rain, Int. J. Electrochem. Sci., 2014, 9, 2696–2715. doi: 10.1016/S1452-3981(23)07957-9P.M. Karlsson, A.E.C. Palmqvist and K. Holmberg, Adsorption of sodium dodecyl sulfate and sodium dodecyl phosphate on aluminum, studied by QCM-D, XPS, and AAS, Langmuir, 2008, 24, no. 23, 13414–13419. doi: 10.1021/la802198sP.M. Karlsson, A.E.C. Palmqvist and K. Holmberg, Adsorption of sodium dodecyl sulfate and sodium dodecyl phosphate on aluminum, studied by QCM-D, XPS, and AAS, Langmuir, 2008, 24, no. 23, 13414–13419. doi: 10.1021/la802198sP.M. Karlsson, M. W. Anderson and A.E.C. Palmqvist, Adsorption of sodium dodecyl sulfate and sodium dodecyl phosphate at the surface of aluminium oxide studied with AFM, Cor. Sci., 2010, 52, no. 4, 1103–1105. doi: 10.1016/j.corsci.2009.11.014P.M. Karlsson, M. W. Anderson and A.E.C. Palmqvist, Adsorption of sodium dodecyl sulfate and sodium dodecyl phosphate at the surface of aluminium oxide studied with AFM, Cor. Sci., 2010, 52, no. 4, 1103–1105. doi: 10.1016/j.corsci.2009.11.014D-H. Xia, C. Pan, Z. Qin, B. Fan, S. Song, W. Jin and W. Hu, Covalent surface modification of LY12 aluminum alloy surface by self-assembly dodecyl phosphate film towards corrosion protection, Prog. Org. Coat., 2020, 143, 105638, doi: 10.1016/j.porgcoat.2020.105638D-H. Xia, C. Pan, Z. Qin, B. Fan, S. Song, W. Jin and W. Hu, Covalent surface modification of LY12 aluminum alloy surface by self-assembly dodecyl phosphate film towards corrosion protection, Prog. Org. Coat., 2020, 143, 105638, doi: 10.1016/j.porgcoat.2020.105638C. Pan, X. Wang, Y. Behnamian, Z. Wu, Z. Qin, D-H. Xia and W. Hu, Monododecyl phosphate film on LY12 aluminum alloy: pH-controlled self-assembly and corrosion resistance, J. Electrochem. Soc., 2020, 167, 161510. doi: 10.1149/1945-7111/abd3bbC. Pan, X. Wang, Y. Behnamian, Z. Wu, Z. Qin, D-H. Xia and W. Hu, Monododecyl phosphate film on LY12 aluminum alloy: pH-controlled self-assembly and corrosion resistance, J. Electrochem. Soc., 2020, 167, 161510. doi: 10.1149/1945-7111/abd3bbY. Kobayashi and Y. Fujiwara, Corrosion protection of cerium conversion coating modified with a self-assembled layer of phosphoric acid mono-n-alkyl ester, Electrochem. Sol. Let., 2006, 9, no. 3, B15–B18. doi: 10.1149/1.2162328Y. Kobayashi and Y. Fujiwara, Corrosion protection of cerium conversion coating modified with a self-assembled layer of phosphoric acid mono-n-alkyl ester, Electrochem. Sol. Let., 2006, 9, no. 3, B15–B18. doi: 10.1149/1.2162328G. Brunoro, A. Frignani, A. Colledan and C. Chiavari, Organic films for protection of copper and bronze against acid rain corrosion, Cor. Sci., 2003, 45, no. 10, 2219–2231. doi: 10.1016/S0010-938X(03)00065-9G. Brunoro, A. Frignani, A. Colledan and C. Chiavari, Organic films for protection of copper and bronze against acid rain corrosion, Cor. Sci., 2003, 45, no. 10, 2219–2231. doi: 10.1016/S0010-938X(03)00065-9G. Žerjav and I. Milošev, Protection of copper against corrosion in simulated urban rain by the combined action of benzotriazole, 2-mercapto-benzimidazole and stearic acid, Cor. Sci., 2015, 98, 180–191. doi: 10.1016/j.corsci.2015.05.023G. Žerjav and I. Milošev, Protection of copper against corrosion in simulated urban rain by the combined action of benzotriazole, 2-mercapto-benzimidazole and stearic acid, Cor. Sci., 2015, 98, 180–191. doi: 10.1016/j.corsci.2015.05.023A.T. Simonović, Ž.Z. Tasić, M.B. Radovanović, M.B. Petrović Mihajlović and M.M. Antonijević, Influence of 5-chlorobenzotriazole on inhibition of copper corrosion in acid rain solution, ACS Omega, 2020, 5, no 22, 12832–12841. doi: 10.1021/acsomega.0c00553A.T. Simonović, Ž.Z. Tasić, M.B. Radovanović, M.B. Petrović Mihajlović and M.M. Antonijević, Influence of 5-chlorobenzotriazole on inhibition of copper corrosion in acid rain solution, ACS Omega, 2020, 5, no 22, 12832–12841. doi: 10.1021/acsomega.0c00553B.V. Appa Rao, M. Narsihma Reddy and B. Sreedhar, Self-assembled 1-octadecyl-1H1,2,4-triazole films on copper for corrosion protection, Prog. Org. Coat., 2014, 77, no. 1, 202–212. doi: 10.1016/j.porgcoat.2013.09.009B.V. Appa Rao, M. Narsihma Reddy and B. Sreedhar, Self-assembled 1-octadecyl-1H1,2,4-triazole films on copper for corrosion protection, Prog. Org. Coat., 2014, 77, no. 1, 202–212. doi: 10.1016/j.porgcoat.2013.09.009H. Tian, W. Li, K. Cao and B. Hou, Potent inhibition of copper corrosion in neutral chloride media by novel non-toxic thiadiazole derivatives, Cor. Sci., 2013, 73, 281–291. doi: 10.1016/j.corsci.2013.04.017H. Tian, W. Li, K. Cao and B. Hou, Potent inhibition of copper corrosion in neutral chloride media by novel non-toxic thiadiazole derivatives, Cor. Sci., 2013, 73, 281–291. doi: 10.1016/j.corsci.2013.04.017A. Rajalakshmi Devi, S. Ramesh and V. Periasamy, Corrosion protection of copper using amino acid self assembled monolayers, JOS, 2015, 5, no. 8, 583–598. doi: 10.21276/josA. Rajalakshmi Devi, S. Ramesh and V. Periasamy, Corrosion protection of copper using amino acid self assembled monolayers, JOS, 2015, 5, no. 8, 583–598. doi: 10.21276/josW. Chen, S. Hong, H.B. Li, H.Q. Luo, M. Li and N.B. Li, Protection of copper corrosion in 0.5 M NaCl solution by modification of 5-mercapto-3-phenyl-1,3,4-thiadiazole-2thione potassium self-assembled mono-layer, Cor. Sci., 2012, 61, 53–62. doi: 10.1016/j.corsci.2012.04.023W. Chen, S. Hong, H.B. Li, H.Q. Luo, M. Li and N.B. Li, Protection of copper corrosion in 0.5 M NaCl solution by modification of 5-mercapto-3-phenyl-1,3,4-thiadiazole-2thione potassium self-assembled mono-layer, Cor. Sci., 2012, 61, 53–62. doi: 10.1016/j.corsci.2012.04.023Ž. Petrović, M. Metikoš-Huković and R. Babić, Modification of copper with selfassembled organic coatings, Prog. Org. Coat., 2008, 61, no. 1, 1–6. doi: 10.1016/j.porgcoat.2007.08.006Ž. Petrović, M. Metikoš-Huković and R. Babić, Modification of copper with selfassembled organic coatings, Prog. Org. Coat., 2008, 61, no. 1, 1–6. doi: 10.1016/j.porgcoat.2007.08.006H.Y. Ma, C. Yang, S.H. Chen, Y.L. Jiao, S.X. Huang, D.G. Li and J.L. Luo, Electrochemical investigation of dynamic interfacial processes at 1-octadecanethiolmodified copper electrodes in halide-containing solutions, Electrochim. Acta, 2003, 48, no. 28, 4277–4289. doi: 10.1016/j.electacta.2003.08.003H.Y. Ma, C. Yang, S.H. Chen, Y.L. Jiao, S.X. Huang, D.G. Li and J.L. Luo, Electrochemical investigation of dynamic interfacial processes at 1-octadecanethiolmodified copper electrodes in halide-containing solutions, Electrochim. Acta, 2003, 48, no. 28, 4277–4289. doi: 10.1016/j.electacta.2003.08.003D.A. Hutt and Ch. Liu, Oxidation protection of copper surfaces using self-assembled monolayers of octadecanethiol, Appl. Surf. Sci., 2005, 252, no. 2, 400–411. doi: 10.1016/j.apsusc.2005.01.019D.A. Hutt and Ch. Liu, Oxidation protection of copper surfaces using self-assembled monolayers of octadecanethiol, Appl. Surf. Sci., 2005, 252, no. 2, 400–411. doi: 10.1016/j.apsusc.2005.01.019N. Wei, Y. Jiang, Y. Ying, X. Guo, Y. Wu, Y. Wen and H. Yang, Facile construction of a polydopamine-based hydrophobic surface for protection of metals against corrosion, RSC Advances, 2017, 7, no. 19, 11528–11536. doi: 10.1039/c7ra00267jN. Wei, Y. Jiang, Y. Ying, X. Guo, Y. Wu, Y. Wen and H. Yang, Facile construction of a polydopamine-based hydrophobic surface for protection of metals against corrosion, RSC Advances, 2017, 7, no. 19, 11528–11536. doi: 10.1039/c7ra00267jY. Yamamoto, H. Nishihara and K. Aramaki, Self-assembled layers of alkanethiols on copper for protection against corrosion, J. Electrochem. Soc., 1993, 140, no. 2, 436. doi: 10.1149/1.2221064Y. Yamamoto, H. Nishihara and K. Aramaki, Self-assembled layers of alkanethiols on copper for protection against corrosion, J. Electrochem. Soc., 1993, 140, no. 2, 436. doi: 10.1149/1.2221064F. Sinapi, S. Julien, D. Auguste, L. Hevesi, J. Delhalle and Z. Mekhalif, Monolayers and mixed-layers on copper towards corrosion protection, Electrochim. Acta, 2008, 53, no. 12, 4228–4238. doi: 10.1016/j.electacta.2007.12.061F. Sinapi, S. Julien, D. Auguste, L. Hevesi, J. Delhalle and Z. Mekhalif, Monolayers and mixed-layers on copper towards corrosion protection, Electrochim. Acta, 2008, 53, no. 12, 4228–4238. doi: 10.1016/j.electacta.2007.12.061F. Sinapi, J. Delhalle and Z. Mekhalif, XPS and electrochemical evaluation of twodimensional organic films obtained by chemical modification of self-assembled monolayers of (3-mercaptopropyl)trimethoxysilane on copper surfaces, Mater. Sci. Eng. C, 2002, 22, no. 2, 345–353. doi: 10.1016/S0928-4931(02)00210-2F. Sinapi, J. Delhalle and Z. Mekhalif, XPS and electrochemical evaluation of twodimensional organic films obtained by chemical modification of self-assembled monolayers of (3-mercaptopropyl)trimethoxysilane on copper surfaces, Mater. Sci. Eng. C, 2002, 22, no. 2, 345–353. doi: 10.1016/S0928-4931(02)00210-2F. Sinapi, I. Lejeune, J. Delhalle and Z. Mekhalif, Comparative protective abilities of organothiols SAM coatings applied to copper dissolution in aqueous environments, Electrochim. Acta, 2007, 52, no. 16, 5182–5190. doi: 10.1016/j.electacta.2006.12.087F. Sinapi, I. Lejeune, J. Delhalle and Z. Mekhalif, Comparative protective abilities of organothiols SAM coatings applied to copper dissolution in aqueous environments, Electrochim. Acta, 2007, 52, no. 16, 5182–5190. doi: 10.1016/j.electacta.2006.12.087A. Ulman, Formation and structure of self-assembled monolayers, Chem. Rev., 1996, 96, no. 4, 1533−1554. doi: 10.1021/cr9502357A. Ulman, Formation and structure of self-assembled monolayers, Chem. Rev., 1996, 96, no. 4, 1533−1554. doi: 10.1021/cr9502357M. Itoh, H. Nishihara and K. Aramaki, A chemical modification of alkanethiol selfassembled monolayers with alkyltrichlorosilanes for the protection of copper against corrosion, J. Electrochem. Soc., 1994, 141, no. 8, 2018−2023, doi: 10.1149/1.2055053M. Itoh, H. Nishihara and K. Aramaki, A chemical modification of alkanethiol selfassembled monolayers with alkyltrichlorosilanes for the protection of copper against corrosion, J. Electrochem. Soc., 1994, 141, no. 8, 2018−2023, doi: 10.1149/1.2055053П.А. Акользин, Коррозия и защита металла теплоэнергетического оборудования, 1982, Энергоиздат, Москва, 304 с.П.А. Акользин, Коррозия и защита металла теплоэнергетического оборудования, 1982, Энергоиздат, Москва, 304 с.В.Ф. Тяпков и Н.Л. Харитонова, Применение пленкообразующих аминов для обеспечения коррозионной стойкости конструкционных материалов оборудования и трубопроводов на энергоблоках АЭС (обзор), Теплоэнергетика, 2022, № 9, 22−32 doi: 10.56304/S0040363622090089В.Ф. Тяпков и Н.Л. Харитонова, Применение пленкообразующих аминов для обеспечения коррозионной стойкости конструкционных материалов оборудования и трубопроводов на энергоблоках АЭС (обзор), Теплоэнергетика, 2022, № 9, 22−32 doi: 10.56304/S0040363622090089В.П. Исаченко, Теплообмен при конденсации, 1977, Энергия, Москва, 240 с.В.П. Исаченко, Теплообмен при конденсации, 1977, Энергия, Москва, 240 с.Г.А. Филиппов, Г.А. Салтанов и А.Н. Кукушкин, Гидродинамика и тепломассообмен в присутствии поверхностно-активных веществ, 1988, Энергоатомиздат, Москва, 184 с.Г.А. Филиппов, Г.А. Салтанов и А.Н. Кукушкин, Гидродинамика и тепломассообмен в присутствии поверхностно-активных веществ, 1988, Энергоатомиздат, Москва, 184 с.O.A. Goncharova, A.Yu. Luchkin, N.N. Andreev, N.P. Andreeva and S.S. Vesely, Triazole derivatives as chamber inhibitors of copper corrosion, Int. J. Corros. Scale Inhib., 2018, 7, no. 4, 657–672. doi: 10.17675/2305-6894-2018-7-4-12O.A. Goncharova, A.Yu. Luchkin, N.N. Andreev, N.P. Andreeva and S.S. Vesely, Triazole derivatives as chamber inhibitors of copper corrosion, Int. J. Corros. Scale Inhib., 2018, 7, no. 4, 657–672. doi: 10.17675/2305-6894-2018-7-4-12A.Yu. Luchkin, O.A. Goncharova, S.S. Vesely, T.T. Trang, D.D. Trung, P.N. Tu, M.V. Minh, C.N. Linh, N.V. Thang, S.G. Gubin, S.V. Bel’skii, I.K. Bel’skaya, N.N. Andreev and V.A. Karpov, Field tests of the efficiency of a mixture of octadecylamine and benzotriazole in the chamber protection of metals in the tropics, Int. J. Corros. Scale Inhib., 2022, 11, no. 4, 1668–1678. doi: 10.17675/2305-6894-2022-11-4-16A.Yu. Luchkin, O.A. Goncharova, S.S. Vesely, T.T. Trang, D.D. Trung, P.N. Tu, M.V. Minh, C.N. Linh, N.V. Thang, S.G. Gubin, S.V. Bel’skii, I.K. Bel’skaya, N.N. Andreev and V.A. Karpov, Field tests of the efficiency of a mixture of octadecylamine and benzotriazole in the chamber protection of metals in the tropics, Int. J. Corros. Scale Inhib., 2022, 11, no. 4, 1668–1678. doi: 10.17675/2305-6894-2022-11-4-16D. Yu and J. Tian, Superhydrophobicity: Is it really better than hydrophobicity on anticorrosion? Coll. Surf. A: Physicochem. Eng. Aspects, 2014, 445, 75−78. doi: 10.1016/j.colsurfa.2014.01.016D. Yu and J. Tian, Superhydrophobicity: Is it really better than hydrophobicity on anticorrosion? Coll. Surf. A: Physicochem. Eng. Aspects, 2014, 445, 75−78. doi: 10.1016/j.colsurfa.2014.01.016

The authors declare that there are no conflicts of interest present.