cpomaemКоррозия: защита материалов и методы исследованийTitle in englishИФХЭ РАН10.61852/2949-3412-2025-3-4-94-110cpomaem-124Research ArticleСтатьиПрименение метода лазерной десорбционной массспектрометрии для исследования поверхности композитных материаловApplication of laser desorption mass spectrometry to study the surface of composite materialsМиненковаИ. В.MinenkovaI. V.

119071, г. Москва, Ленинский проспект, д. 31, корп. 4

31-4, Leninsky prospect, 119071 Moscow

КузнецоваЕ. С.KuznetsovaE. S.

119071, г. Москва, Ленинский проспект, д. 31, корп. 4

31-4, Leninsky prospect, 119071 Moscow

ПыцкийИ. С.PytskyI. S.

119071, г. Москва, Ленинский проспект, д. 31, корп. 4

31-4, Leninsky prospect, 119071 Moscow

ivanpic4586@gmail.comФедеральное государственное бюджетное учреждение науки Институт физической химии и электрохимии им. А.Н. Фрумкина Российской академии наукРоссияFrumkin Institute of Physical Chemistry and Electrochemistry Russian Academy of SciencesRussian Federation2025181220250494110Copyright © Миненкова И.В., Кузнецова Е.С., Пыцкий И.С., 20252025Миненкова И.В., Кузнецова Е.С., Пыцкий И.С.Minenkova I.V., Kuznetsova E.S., Pytsky I.S.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://www.cpmrm.ru/jour/article/view/124

Работа посвящена анализу материалов на основе модельного адаптивного композита разного состава. Продемонстрированы возможности масс-спектрометрии с визуализацией с целью исследования поверхности материалов, включая боковые срезы. Построены двумерные диаграммы распределения ионов по исследуемым поверхностям. Разработанная методика позволила обнаружить как органические, так и неорганические компоненты модельных композитов. Представленная методика визуализации массспектрометрических данных с лазерной десорбцией/ионизацией позволяет анализировать поверхность композитных материалов, оценивать степень воздействия агрессивной среды на них и получать важную информацию о структуре поверхности и распределении соединений по глубине на всю толщину образца, что демонстрирует уникальность предлагаемого подхода.

The work is devoted to the analysis of materials based on a model adaptive composite of different compositions. The possibilities of mass spectrometry with visualization are demonstrated in order to study the surface of materials, including side cuts. Two-dimensional diagrams of ion distribution over the studied surfaces are constructed. The developed technique made it possible to detect both organic and inorganic components of model composites. The presented method for visualizing mass spectrometric data with laser desorption/ionization allows for the analysis of the surface of composite materials, the assessment of their exposure to aggressive environments, and the acquisition of important information about the surface structure and the distribution of compounds throughout the thickness of the sample, demonstrating the uniqueness of the proposed approach.

лазерная десорбция/ионизациямасс-спектрометриядвумерные диаграммы распределениякластерыlaser desorption/ionizationmass spectrometrytwo-dimensional distribution diagramsclustersРабота выполнена при финансовой поддержке Министерства высшего образования и науки Российской Федерации.ReferencesH. Awad, M.M. Khamis and A. El-Aneed, Mass spectrometry, review of the basics: ionization, Applied Spectroscopy Reviews, 2015, 50, no. 2, 158−175. doi: 10.1080/05704928.2014.954046H. Awad, M.M. Khamis and A. El-Aneed, Mass spectrometry, review of the basics: ionization, Applied Spectroscopy Reviews, 2015, 50, no. 2, 158−175. doi: 10.1080/05704928.2014.954046G.L. Glish and R.W. Vachet, The basics of mass spectrometry in the twenty-first century, Nature reviews drug discovery, 2003, 2, no. 2, 140−150. doi: 10.1038/nrd1011G.L. Glish and R.W. Vachet, The basics of mass spectrometry in the twenty-first century, Nature reviews drug discovery, 2003, 2, no. 2, 140−150. doi: 10.1038/nrd1011P.L. Urban, Quantitative mass spectrometry: an overview, Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, 2016, 374, no. 2079, 1−5. doi: 10.1098/rsta.2015.0382P.L. Urban, Quantitative mass spectrometry: an overview, Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, 2016, 374, no. 2079, 1−5. doi: 10.1098/rsta.2015.0382S. Tamara, M.A. den Boer and A.J. Heck, High-resolution native mass spectrometry, Chemical reviews, 2021, 122, no. 8, 7269−7326. doi: 10.1021/acs.chemrev.1c00212S. Tamara, M.A. den Boer and A.J. Heck, High-resolution native mass spectrometry, Chemical reviews, 2021, 122, no. 8, 7269−7326. doi: 10.1021/acs.chemrev.1c00212S.R. Shuken, An introduction to mass spectrometry-based proteomics, Journal of proteome research, 2023, 22, no. 7, 2151−2171. doi: 10.1021/acs.jproteome.2c00838S.R. Shuken, An introduction to mass spectrometry-based proteomics, Journal of proteome research, 2023, 22, no. 7, 2151−2171. doi: 10.1021/acs.jproteome.2c00838A.К. Буряк, Н.П. Платонова, И.С. Пыцкий и А.В. Ульянов, Масс-спектрометрия для исследования коррозионных процессов на поверхностях конструкционных материалов, Аналитика, 2019, 9, no. 2, 126−135. doi: 10.22184/2227572X.2019.9.2.126.135A.К. Буряк, Н.П. Платонова, И.С. Пыцкий и А.В. Ульянов, Масс-спектрометрия для исследования коррозионных процессов на поверхностях конструкционных материалов, Аналитика, 2019, 9, no. 2, 126−135. doi: 10.22184/2227572X.2019.9.2.126.135A.K. Buryak and T.M. Serdyuk, Chromatography–mass spectrometry in aerospace industry, Russian Chemical Reviews, 2013, 82, no. 4, 366−392. doi: 10.1070/RC2013v082n04ABEH004304A.K. Buryak and T.M. Serdyuk, Chromatography–mass spectrometry in aerospace industry, Russian Chemical Reviews, 2013, 82, no. 4, 366−392. doi: 10.1070/RC2013v082n04ABEH004304S.D. Iartsev, I.S. Pytskii, A.S. Belova and A.K. Buryak, Mass spectrometry detection of nitrobenzoic acids and their salts on the surface of construction materials, Journal of analytical chemistry, 2018, 73, no. 1, 46−51. doi: 10.1134/S1061934818010124S.D. Iartsev, I.S. Pytskii, A.S. Belova and A.K. Buryak, Mass spectrometry detection of nitrobenzoic acids and their salts on the surface of construction materials, Journal of analytical chemistry, 2018, 73, no. 1, 46−51. doi: 10.1134/S1061934818010124S.D. Iartsev, I.S. Pytskii, I.G. Zenkevich and A.K. Buryak, Chromatographic and massspectrometric study of the surfaces of construction materials after contact with 1,1dimethylhydrazine, Journal of Analytical Chemistry, 2017, 72, no. 6, 624–631. doi: 10.1134/S106193481706017XS.D. Iartsev, I.S. Pytskii, I.G. Zenkevich and A.K. Buryak, Chromatographic and massspectrometric study of the surfaces of construction materials after contact with 1,1dimethylhydrazine, Journal of Analytical Chemistry, 2017, 72, no. 6, 624–631. doi: 10.1134/S106193481706017XE.S. Kuznetsova, I.S. Pytsky and A.K. Buryak, Introducing catonization agents in the soft ionization of short-chain peptides: Laser desorption and electrospraying, Russian Journal of Physical Chemistry A, 2025, 99, no. 1, 98−104. doi: 10.1134/S0036024424702686E.S. Kuznetsova, I.S. Pytsky and A.K. Buryak, Introducing catonization agents in the soft ionization of short-chain peptides: Laser desorption and electrospraying, Russian Journal of Physical Chemistry A, 2025, 99, no. 1, 98−104. doi: 10.1134/S0036024424702686I.S. Pytskii, E.S. Kuznetsova, S.D. Iartsev and A.K. Buryak, Methodological features of mass-spectrometric studies of oxidized metal surfaces, Colloid Journal, 2017, 79, 526C531. doi: 10.1134/S1061933X17040111I.S. Pytskii, E.S. Kuznetsova, S.D. Iartsev and A.K. Buryak, Methodological features of mass-spectrometric studies of oxidized metal surfaces, Colloid Journal, 2017, 79, 526C531. doi: 10.1134/S1061933X17040111I.S. Pytskii, E.S. Kuznetsova and A.K. Buryak, Express search and characterization of nitro compounds via visualization mass spectrometry, Russian Journal of Physical Chemistry A, 2023, 97, no. 11, 2559−2563. doi: 10.1134/S0036024423110262I.S. Pytskii, E.S. Kuznetsova and A.K. Buryak, Express search and characterization of nitro compounds via visualization mass spectrometry, Russian Journal of Physical Chemistry A, 2023, 97, no. 11, 2559−2563. doi: 10.1134/S0036024423110262I.S. Pytskii, E.S. Kuznetsova and A.K. Buryak, Surface imaging in applied research, Russian Journal of Physical Chemistry A, 2022, 96, no. 10, 2215–2221. doi: 10.1134/S0036024422100260I.S. Pytskii, E.S. Kuznetsova and A.K. Buryak, Surface imaging in applied research, Russian Journal of Physical Chemistry A, 2022, 96, no. 10, 2215–2221. doi: 10.1134/S0036024422100260

The authors declare that there are no conflicts of interest present.