cpomaemКоррозия: защита материалов и методы исследованийTitle in englishИФХЭ РАНcpomaem-20Research ArticleСтатьиМодификация поверхности магния в растворах органических ингибиторов коррозии послойным методомModification of magnesium surface in solutions of organic corrosion inhibitors by layer-by-layer methodЛучкинаВ. А.LuchkinaV. A.

Ленинский пр., д. 31/4, 119071, Москва

Leninsky av. 31/4, 119071 Moscow

masildik@mail.ruВершокД. Б.VershokD. B.

Ленинский пр., д. 31/4, 119071, Москва

Leninsky av. 31/4, 119071 Moscow

ЧиркуновА. А.ChirkunovA. A.

Ленинский пр., д. 31/4, 119071, Москва

Leninsky av. 31/4, 119071 Moscow

ФГБУН Институт физической химии и электрохимии им. А.Н. Фрумкина РАНРоссияA.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of SciencesRussian Federation202331102023033750Copyright © Лучкина В.А., Вершок Д.Б., Чиркунов А.А., 20232023Лучкина В.А., Вершок Д.Б., Чиркунов А.А.Luchkina V.A., Vershok D.B., Chirkunov A.A.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://www.cpmrm.ru/jour/article/view/20

В настоящей работе, исследована возможность повышения коррозионной стойкости Мг90 методом послойной модификации его поверхности в растворах 13 мМ олеата натрия и 3 мМ 8-гидроксихинолина. Оценено влияние, как последовательности нанесения ингибиторов, так и толщины оксидно‑гидроксидного подслоя. Показано, что покрытие 13 мМ олеата натрия //3 мМ 8-гидрокихинолина, сформированное на воздушно‐окисленном Мг90, обеспечивало наиболее эффективную защиту металла от коррозии, чем их индивидуальные слои. Увеличение толщины оксидного подслоя не способствовало повышению защитного действия полислойных покрытий, однако существенно повышало коррозионную стойкость Мг90 с пленками индивидуальных ингибиторов.

In the present work, the possibility of increasing the corrosion resistance of Mg90 by layer-by-layer modification of its surface in solutions of 13 mM sodium oleate and 3 mM 8‑hydroxyquinoline was investigated. The influence of both the sequence of inhibitor application and the thickness of the oxide-hydroxide sublayer was evaluated. It is shown that the coating of 13 mM sodium oleate//3 mM 8-hydroxyquinoline formed on air‑oxidized Mg90 provided the most effective corrosion protection of metal than their individual layers. Increasing the thickness of the oxide sublayer did not contribute to increasing the protective effect of the multilayer coatings, but significantly increased the corrosion resistance of Mg90 with films of individual inhibitors.

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The authors declare that there are no conflicts of interest present.