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<article article-type="research-article" dtd-version="1.3" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xml:lang="ru"><front><journal-meta><journal-id journal-id-type="publisher-id">cpomaem</journal-id><journal-title-group><journal-title xml:lang="ru">Коррозия: защита материалов и методы исследований</journal-title><trans-title-group xml:lang="en"><trans-title>Title in english</trans-title></trans-title-group></journal-title-group><publisher><publisher-name>ИФХЭ РАН</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.61852/2949-3412-2024-2-1-1-22</article-id><article-id custom-type="elpub" pub-id-type="custom">cpomaem-37</article-id><article-categories><subj-group subj-group-type="heading"><subject>Research Article</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="ru"><subject>Статьи</subject></subj-group></article-categories><title-group><article-title>Раскрытие химической автоконденсации и растворения диоксида кремния в охлаждающих жидкостях двигателя: применение в технологии органических присадок для автомобильных охлаждающих жидкостей (OAT)</article-title><trans-title-group xml:lang="en"><trans-title>Unraveling silica auto-condensation and dissolution chemistry in engine coolant fluids: Applications in automotive coolant organic additive technology (OAT)</trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Скордалу</surname><given-names>Г.</given-names></name><name name-style="western" xml:lang="en"><surname>Skordalou</surname><given-names>G.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Кампус Вутес, Ираклион, Крит, GR-71003</p></bio><bio xml:lang="en"><p>Voutes Campus, Heraklion, Crete, GR-71003</p></bio><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Клерик</surname><given-names>С.</given-names></name><name name-style="western" xml:lang="en"><surname>Clerick</surname><given-names>S.</given-names></name></name-alternatives><bio xml:lang="ru"><p>B-9051 Синт-Денийс-Вестрем</p></bio><bio xml:lang="en"><p>B-9051 Sint-Denijs-Westrem</p></bio><xref ref-type="aff" rid="aff-2"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Буйтаерт</surname><given-names>Г.</given-names></name><name name-style="western" xml:lang="en"><surname>Buytaert</surname><given-names>G.</given-names></name></name-alternatives><bio xml:lang="ru"><p>B-9051 Синт-Денийс-Вестрем</p></bio><bio xml:lang="en"><p>B-9051 Sint-Denijs-Westrem</p></bio><xref ref-type="aff" rid="aff-2"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Верлент</surname><given-names>И.</given-names></name><name name-style="western" xml:lang="en"><surname>Verlent</surname><given-names>I.</given-names></name></name-alternatives><bio xml:lang="ru"><p>B-9051 Синт-Денийс-Вестрем</p></bio><bio xml:lang="en"><p>B-9051 Sint-Denijs-Westrem</p></bio><xref ref-type="aff" rid="aff-2"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Ливенс</surname><given-names>С.</given-names></name><name name-style="western" xml:lang="en"><surname>Lievens</surname><given-names>S.</given-names></name></name-alternatives><bio xml:lang="ru"><p>B-9051 Синт-Денийс-Вестрем</p></bio><bio xml:lang="en"><p>B-9051 Sint-Denijs-Westrem</p></bio><xref ref-type="aff" rid="aff-2"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Демадис</surname><given-names>К. Д.</given-names></name><name name-style="western" xml:lang="en"><surname>Demadis</surname><given-names>K. D.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Кампус Вутес, Ираклион, Крит, GR-71003</p></bio><bio xml:lang="en"><p>Voutes Campus, Heraklion, Crete, GR-71003</p></bio><email xlink:type="simple">demadis@uoc.gr</email><xref ref-type="aff" rid="aff-1"/></contrib></contrib-group><aff-alternatives id="aff-1"><aff xml:lang="ru">Лаборатория разработки, выращивания и проектирования кристаллов, Химический факультет, Университет Крита<country>Греция</country></aff><aff xml:lang="en">Crystal Engineering, Growth and Design Laboratory, Department of Chemistry, University of Crete<country>Greece</country></aff></aff-alternatives><aff-alternatives id="aff-2"><aff xml:lang="ru">Arteco NV<country>Бельгия</country></aff><aff xml:lang="en">Arteco NV<country>Belgium</country></aff></aff-alternatives><pub-date pub-type="collection"><year>2024</year></pub-date><pub-date pub-type="epub"><day>11</day><month>04</month><year>2024</year></pub-date><volume>0</volume><issue>1</issue><fpage>1</fpage><lpage>22</lpage><permissions><copyright-statement>Copyright &amp;#x00A9; Скордалу Г., Клерик С., Буйтаерт Г., Верлент И., Ливенс С., Демадис К.Д., 2024</copyright-statement><copyright-year>2024</copyright-year><copyright-holder xml:lang="ru">Скордалу Г., Клерик С., Буйтаерт Г., Верлент И., Ливенс С., Демадис К.Д.</copyright-holder><copyright-holder xml:lang="en">Skordalou G., Clerick S., Buytaert G., Verlent I., Lievens S., Demadis K.D.</copyright-holder><license license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>This work is licensed under a Creative Commons Attribution 4.0 License.</license-p></license></permissions><self-uri xlink:href="https://www.cpmrm.ru/jour/article/view/37">https://www.cpmrm.ru/jour/article/view/37</self-uri><abstract><p>Охлаждающие жидкости двигателя представляют собой смеси воды и гликолей (чаще всего моноэтиленгликоля, МЭГ), содержащие ингибиторы коррозии материалов системы. В настоящее время органические ингибиторы обычно используются в сочетании с неорганическими ингибиторами, такими как силикаты. Чтобы эффективно создать такую охлаждающую жидкость для двигателя, крайне важно понять поведение силиката в «полуводной» среде. Поликонденсация силиката была тщательно изучена в водных растворах, а также основных факторах, влияющих на ее водный химический состав, четко контролируемых (т.е. pH, температура, концентрация и т.д.). В этой статье тщательно изучена химия поликонденсации силиката в различных частях смеси МЭГ/вода и исследовано влияние нескольких экспериментальных параметров, таких как рабочий pH, время конденсации и соотношение МЭГ:вода. Присутствие МЭГ в смесях МЭГ/вода обеспечивает автоконденсацию силиката с образованием аморфного кремнезема при всех изученных значениях pH. Конденсация силиката начинается в течение 10 мин после регулирования pH и происходит быстрее с введением МЭГ. Самые низкие уровни активного силиката наблюдались в пределах pH от 8,0 до 8,5 (наиболее распространенный pH для охлаждающих жидкостей двигателя). Поведение силиката также изучалось в обычных охлаждающих жидкостях (которые, кроме МЭГ, содержат органические ингибиторы коррозии). В обоих случаях конденсация значительно усиливается. Температурно-зависимое растворение частиц аморфного кремнезема было изучено в выбранных смесях МЭГ/вода и было обнаружено, что оно незначительно при температуре окружающей среды независимо от соотношения МЭГ:вода, тогда как оно существенно при 90°C в чистой воде. Определение химического состава силикатов в матрицах охлаждающих жидкостей будет ценной информацией для разработки более эффективных составов охлаждающих жидкостей для двигателей.</p></abstract><trans-abstract xml:lang="en"><p>Engine coolants are mixtures of water and glycols (most commonly monoethylene glycol, MEG), formulated with corrosion inhibitors to protect the system materials. Nowadays, organic corrosion inhibitors are generally used in combination with inorganic corrosion inhibitors, such as silicates. To effectively formulate such engine coolant, it is of crucial importance to understand the behavior of silicate in a “semi-aqueous” environment. Silicate polycondensation has been thoroughly studied in aqueous solutions and the key factors influencing its aqueous chemistry are well defined (i.e. pH, temperature, concentration, etc.). In this paper the polycondensation chemistry of silicate in a wide range of MEG/water mixtures is thoroughly studied and the influence of several experimental parameters, such as working pH, condensation time and the MEG:water ratio, is investigated. The presence of MEG in MEG/water mixtures enhances silicate auto-condensation to form amorphous silica, at all pH values studied. Silicate condensation starts to occur within 10 minutes of pH adjustment and is faster with increasing MEG. The lowest levels of active silicate were observed in the pH region 8.0 to 8.5 (most common pH for engine coolants). The behavior of silicate was also studied in a generic coolant (which contains organic corrosion inhibitors in addition to MEG). In both cases condensation is severely enhanced. Temperature-driven amorphous silica particle dissolution was studied in selected MEG/water mixtures and it was found that it is negligible at ambient temperature regardless of the MEG:water ratio, whereas it is substantial at 90°C in pure water. Delineating silicate chemistry in coolant matrices will be valuable information for designing betterperforming formulations for engine coolant applications.</p></trans-abstract><kwd-group xml:lang="ru"><kwd>силикат</kwd><kwd>охлаждающая жидкость двигателя</kwd><kwd>моноэтиленгликоль</kwd><kwd>МЭГ</kwd><kwd>поликонденсация</kwd><kwd>ингибитор коррозии</kwd></kwd-group><kwd-group xml:lang="en"><kwd>silicate</kwd><kwd>engine coolant</kwd><kwd>monoethylene glycol</kwd><kwd>MEG</kwd><kwd>polycondensation</kwd><kwd>corrosion inhibitor</kwd></kwd-group><funding-group xml:lang="ru"><funding-statement>К.Д.Д. и GS благодарят Arteco NV за финансовую поддержку исследовательского проекта CoLoBRI – Coolant Lobrid Technology (исследовательский проект, спонсируемый Агентством инноваций и предпринимательства Фландрии и частично управляемый Специальным счетом для исследований в Университете Крита, KA 10583).</funding-statement></funding-group></article-meta></front><back><ref-list><title>References</title><ref id="cit1"><label>1</label><citation-alternatives><mixed-citation xml:lang="ru">M. 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