cpomaemКоррозия: защита материалов и методы исследованийTitle in englishИФХЭ РАН10.61852/2949-3412-2024-2-3-44-67cpomaem-65Research ArticleСтатьиРастительные экстракты как ингибиторы коррозии меди. Обзор. Часть IБилгичС.

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Университет Анкары, факультет естественных наук, отдел химииТурция202416092024034467Copyright © Билгич С., 20242024Билгич С.Билгич С.This work is licensed under a Creative Commons Attribution 4.0 License.https://www.cpmrm.ru/jour/article/view/65

Один из методов предотвращения коррозии заключается в добавлении в агрессивную среду химических соединений, называемых ингибиторами. Ингибиторы могут представлять собой неорганические или органические соединения. Однако эти соединения могут быть опасны для здоровья человека и окружающей среды из-за своего токсичного действия. К тому же добыть их может быть сложно и дорого. По этой причине в последние годы предметом многих исследований являются нетоксичные, биосовместимые, безвредные для здоровья человека и окружающей среды ингибиторы коррозии, которые можно легко и дешево получить. Многие исследователи сосредоточились на новом классе ингибиторов, таких как растительные экстракты, экстракты фруктов и овощей и эфирные масла. Растительные экстракты представляют собой наиболее изученный класс этих ингибиторов, называемых зелеными ингибиторами. Защитное действие растительных экстрактов обусловлено адсорбцией их молекул на поверхности металла. Они обеспечивают металл защитной пленкой, блокируя активные центры. Формирование пленки обеспечивает для металлической поверхности физический барьер от агрессивных сред и обеспечивает защитный эффект от коррозивных воздействий. Медь ‒ благородный металл, и благодаря этому свойству она устойчива к коррозии. Однако определенные условия могут вызвать коррозию меди, например, загрязненный воздух, окисляющие кислоты, окисляющие соли тяжелых металлов, сернистый аммиак и некоторые соединения серы и аммиака. Поэтому исследование коррозии меди имеет важное значение. В данном обзоре обобщены исследования экстрактов растений, оказывающих ингибирующее действие на коррозию меди.

One of the corrosion prevention methods is to add chemical compounds called inhibitors in corrosive environments. Inhibitors can be inorganic or organic compounds. However, these compounds are dangerous for human health and environment because of their toxicity effects. In addition to obtain them is difficult and expensive. For this reason, corrosion inhibitors that are non-toxic, biocompatible, not harmful to human health and the environment, and which can be obtained easily and cheaply, are the subject of many researches in recent years. Scientists have focused on a new class of inhibitors such as plant extracts, fruit and vegetable extracts and essential oils. Plant extracts are the most studied class of these inhibitors, called green inhibitors. The protection effects of plant extracts are due to the adsorption of their molecules on the metal surface. They provide the metal with a protective film by blocking the active sites. The formation of film provides the metal surface with a physical barrier from corrosive media, and supplies protection effects from corrosive attacks. Copper is noble metal and as a result of this property, it shows to resist against to corrosion. However, certain conditions can cause corrosion on copper, such as polluted air, oxidizing acids, oxidizing heavy metal salts, sulfur ammonia and some sulfur and ammonia compounds. Therefore, the investigation of copper corrosion is significant. In this review, studies are summarized with plant extracts, which have an inhibitory effect on the corrosion of copper.

коррозиямедьингибиторрастительные экстрактыcorrosioncopperinhibitorplant extractsReferencesF. Bentiss, M. Traisnel and M. Lagrenee, The substituted 1,3,4-oxadiazoles: a new class of corrosion inhibitors of mild steel in acidic media, Corros. Sci., 2000, 42, 127–146. doi: 10.1016/S0010-938X(99)00049-9F. Bentiss, M. Traisnel and M. Lagrenee, The substituted 1,3,4-oxadiazoles: a new class of corrosion inhibitors of mild steel in acidic media, Corros. Sci., 2000, 42, 127–146. doi: 10.1016/S0010-938X(99)00049-9A. Popova, E. Sokolova, S. Raicheva and M. Christov, AC and DC study of the temperature effect on mild steel corrosion in acid media in the presence of benzimidazole derivatives, Corros. Sci., 2003, 45, 33–58 doi: 10.1016/S0010-938X(02)00072-0A. Popova, E. Sokolova, S. Raicheva and M. Christov, AC and DC study of the temperature effect on mild steel corrosion in acid media in the presence of benzimidazole derivatives, Corros. Sci., 2003, 45, 33–58 doi: 10.1016/S0010-938X(02)00072-0S.A. Abd El Maksoud and A.S. Fouda, Some pyridine derivatives as corrosion inhibitors for carbon steel in acidic medium, Mater. Chem. Phys., 2005, 93, 84–90 doi: 10.1016/j.matchemphys.2005.02.020S.A. Abd El Maksoud and A.S. Fouda, Some pyridine derivatives as corrosion inhibitors for carbon steel in acidic medium, Mater. Chem. Phys., 2005, 93, 84–90 doi: 10.1016/j.matchemphys.2005.02.020M. Karakuş, M. Şahin and S. Bilgiç, An investigation on the inhibition effects of some new dithiophosphonic acid monoesthers on the corrosion of steel in 1 M HCl medium, Mater. Chem. Phys., 2005, 92, 565–571 doi: 10.1016/j.matchemphys.2005.02.010M. Karakuş, M. Şahin and S. Bilgiç, An investigation on the inhibition effects of some new dithiophosphonic acid monoesthers on the corrosion of steel in 1 M HCl medium, Mater. Chem. Phys., 2005, 92, 565–571 doi: 10.1016/j.matchemphys.2005.02.010S.D. Shetty, P. Shetty and V.S. Nayak, Inhibition of mild steel corrosion in acidic media by N-(2-thiophenyl)-N’-phenyl thiourea, J. Chil. Chem. Soc., 2006, 51, 849–853.S.D. Shetty, P. Shetty and V.S. Nayak, Inhibition of mild steel corrosion in acidic media by N-(2-thiophenyl)-N’-phenyl thiourea, J. Chil. Chem. Soc., 2006, 51, 849–853.R. Hasanov, S. Bilge, S. Bilgiç, G. Gece and Z. Kılıç, Experimental and theoretical calculations on corrosion inhibition of steel in 1 M H2SO4 by crown type polyethers, Corros. Sci., 2010, 52, 984–990 doi: 10.1016/j.corsci.2009.11.022R. Hasanov, S. Bilge, S. Bilgiç, G. Gece and Z. Kılıç, Experimental and theoretical calculations on corrosion inhibition of steel in 1 M H2SO4 by crown type polyethers, Corros. Sci., 2010, 52, 984–990 doi: 10.1016/j.corsci.2009.11.022K.F. Khaled, N.S. Abdel-Shafi and N.A. Al-Mobarak, Understanding Corrosion Inhibition of iron by 2- Thiophenecarboxtlic Acid Methyl Ester: Electrochemical and Computational Study, Int. J. Electrochem. Sci., 2012, 7, 1027–1044.K.F. Khaled, N.S. Abdel-Shafi and N.A. Al-Mobarak, Understanding Corrosion Inhibition of iron by 2- Thiophenecarboxtlic Acid Methyl Ester: Electrochemical and Computational Study, Int. J. Electrochem. Sci., 2012, 7, 1027–1044.A.A. Khadom, Effect of corrosion solution motion on copper-nickel alloy pipe in presence of napthylamine as a corrosion inhibitor, J. Mater. Environ. Sci., 2013, 4, 510– 519A.A. Khadom, Effect of corrosion solution motion on copper-nickel alloy pipe in presence of napthylamine as a corrosion inhibitor, J. Mater. Environ. Sci., 2013, 4, 510– 519Y.G. Avdeev, M.V. Tyurina and Y.I. Kuznetsov, Protection of low-carbon steel in phosphoric acid solution by mixtures a substituted triazole with sulfur-containing compounds, Int. J. Corros. Scale Inhib., 2014, 3, no. 4, 246–253 doi: 10.17675/2305-6894-2014-3-4-246-253Y.G. Avdeev, M.V. Tyurina and Y.I. Kuznetsov, Protection of low-carbon steel in phosphoric acid solution by mixtures a substituted triazole with sulfur-containing compounds, Int. J. Corros. Scale Inhib., 2014, 3, no. 4, 246–253 doi: 10.17675/2305-6894-2014-3-4-246-253V.P. Grigor’ev, E.V. Plekhanova, E.E. Verbitskaya and L.D. Popov, The inhibitive effects of 8-mercaptoquinoline and its iron chelate complex in the acid corrosion of iron in 1 M HCl, Int. J. Corros. Scale Inhib., 2014, 3, no. 4, 215–226. doi: 10.17675/2305-6894-2014-3-4-215-226V.P. Grigor’ev, E.V. Plekhanova, E.E. Verbitskaya and L.D. Popov, The inhibitive effects of 8-mercaptoquinoline and its iron chelate complex in the acid corrosion of iron in 1 M HCl, Int. J. Corros. Scale Inhib., 2014, 3, no. 4, 215–226. doi: 10.17675/2305-6894-2014-3-4-215-226A. Khadraoui, A. Khelifa, K. Hachama, H. Boutoumi and B. Hammaouti, Synergistic effect of potassium iodide ion controlling the corrosion of steel in acid medium by Menttha pulegium extract, Res. Chem. Intermed., 2015, 41, 7973–7980. doi: 10.1007/s11164-014-1870-8A. Khadraoui, A. Khelifa, K. Hachama, H. Boutoumi and B. Hammaouti, Synergistic effect of potassium iodide ion controlling the corrosion of steel in acid medium by Menttha pulegium extract, Res. Chem. Intermed., 2015, 41, 7973–7980. doi: 10.1007/s11164-014-1870-8A. Nnanna and I.O. Owate, Electrochemical study of corrosion inhibition of mild steel in acidic solution using Gnetum africana leaves extract, Br. J. Appl. Sci. Technol., 2015, 5, 556–567.A. Nnanna and I.O. Owate, Electrochemical study of corrosion inhibition of mild steel in acidic solution using Gnetum africana leaves extract, Br. J. Appl. Sci. Technol., 2015, 5, 556–567.S. Mo and H.Q. Li, N.B. Li, Plant extracts as green corrosion inhibitors for steel in sulphuric acid, Chem. Pap., 2016, 70, 1131–1143 doi: 10.1515/chempap-2016-0055S. Mo and H.Q. Li, N.B. Li, Plant extracts as green corrosion inhibitors for steel in sulphuric acid, Chem. Pap., 2016, 70, 1131–1143 doi: 10.1515/chempap-2016-0055S.A. Adzor and B.O. Udaye, Corrosion Inhibitive Effects of Coconot (Cocus Nucifera Linn) Water for Mild Steel in Acidic Medium, Eur. J. Mater. Sci., 2016, 3, 1–12.S.A. Adzor and B.O. Udaye, Corrosion Inhibitive Effects of Coconot (Cocus Nucifera Linn) Water for Mild Steel in Acidic Medium, Eur. J. Mater. Sci., 2016, 3, 1–12.A. Khadraoui, A. Khelifa, H. Bautomi, Y. Karzazi, B. Hammouti and S.S. Al-Deyab, The Oil from Mentha Rotundifolia as Green Inhibitor of Carbon Steel Corrosion in Hydrochloric Acid, Chem. Eng. Commun., 2016, 203, 270–277 doi: 10.1080/00986445.2014.993469A. Khadraoui, A. Khelifa, H. Bautomi, Y. Karzazi, B. Hammouti and S.S. Al-Deyab, The Oil from Mentha Rotundifolia as Green Inhibitor of Carbon Steel Corrosion in Hydrochloric Acid, Chem. Eng. Commun., 2016, 203, 270–277 doi: 10.1080/00986445.2014.993469E. Dharmaraj, C. Paragathiswaran, P. Govinthan, P.A. Sahayaraj, A.J. Amalraj and V. Dharmalingam, Corrosion Inhibition of Mild Steel by Plant Extracts in Acid Media, Int. J. Nano. Corr. Sci. Engg., 2017, 4, 106–120.E. Dharmaraj, C. Paragathiswaran, P. Govinthan, P.A. Sahayaraj, A.J. Amalraj and V. Dharmalingam, Corrosion Inhibition of Mild Steel by Plant Extracts in Acid Media, Int. J. Nano. Corr. Sci. Engg., 2017, 4, 106–120.H. Louis, J. Japari, A. Sadia, M. Philip and A. Bamanga, Photochemical screening and corrosion inhibition of Poupartia birrea back extracts as a potential green inhibitor for mild steel in 0.5 M H2O4 medium, World News Nat. Sci., 2017, 10, 95–100.H. Louis, J. Japari, A. Sadia, M. Philip and A. Bamanga, Photochemical screening and corrosion inhibition of Poupartia birrea back extracts as a potential green inhibitor for mild steel in 0.5 M H2O4 medium, World News Nat. Sci., 2017, 10, 95–100.M. Rana, S. Joshi and J. Bahattaraj, Extract of different plants Nepalese origin as Green Corrosion Inhibitor for Mild Steel in 0.5 M NaCl Solution, Asian J. Chem., 2017, 29, 1130–1134. doi: 10.14233/ajchem.2017.20449M. Rana, S. Joshi and J. Bahattaraj, Extract of different plants Nepalese origin as Green Corrosion Inhibitor for Mild Steel in 0.5 M NaCl Solution, Asian J. Chem., 2017, 29, 1130–1134. doi: 10.14233/ajchem.2017.20449N.B. Iroha and M.A. Chidiebere, Evaluation of the Inhibitive effect of Annona Muricata. L Leaves Extract on Low-Carbon Steel Corrosion in Acidic Media, Int. J. Mater. Chem., 2017, 7, 47–54.N.B. Iroha and M.A. Chidiebere, Evaluation of the Inhibitive effect of Annona Muricata. L Leaves Extract on Low-Carbon Steel Corrosion in Acidic Media, Int. J. Mater. Chem., 2017, 7, 47–54.R. Haldhar, D. Prasad and A. Saxena, Myristica fragrans extract as an eco-friendly corrosion inhibitor for mild steel in 0.5 M H2SO4 solution, J. Environ. Chem. Eng., 2018, 6, 2290–2301 doi: 10.1016/j.jece.2018.03.023R. Haldhar, D. Prasad and A. Saxena, Myristica fragrans extract as an eco-friendly corrosion inhibitor for mild steel in 0.5 M H2SO4 solution, J. Environ. Chem. Eng., 2018, 6, 2290–2301 doi: 10.1016/j.jece.2018.03.023R. Haldhar, D. Prasad and A. Saxena, Armoracia rusticana as sustainable and ecofriendly corrosion inhibitor for mild steel in 0.5 M sulphuric acid: experimental and theoretical investigations, J. Environ. Chem. Eng., 2018, 8, 5230–5238 doi: 10.1016/j.jece.2018.08.025R. Haldhar, D. Prasad and A. Saxena, Armoracia rusticana as sustainable and ecofriendly corrosion inhibitor for mild steel in 0.5 M sulphuric acid: experimental and theoretical investigations, J. Environ. Chem. Eng., 2018, 8, 5230–5238 doi: 10.1016/j.jece.2018.08.025N.H.Z. Leena, Hukuman, A.R.Biju and M.Jisha, Studies on Methanolic Extract of Lepidagathis keralensis as Green Corrosion Inhibitor for Mild Steel in 1M HCl, J. Electrochem. Sci. Technol., 2019, 10, 231–243 doi: 10.5229/JECST.2019.10.2.231N.H.Z. Leena, Hukuman, A.R.Biju and M.Jisha, Studies on Methanolic Extract of Lepidagathis keralensis as Green Corrosion Inhibitor for Mild Steel in 1M HCl, J. Electrochem. Sci. Technol., 2019, 10, 231–243 doi: 10.5229/JECST.2019.10.2.231Y. Fang, B. Suganthan and R.P. Ramasamy, Electrochemical characterzation of aromatic corrosion inhibitors from plant extracts, J. Electroanal. Chem., 2019, 840, 74–83. doi: 10.1016/j.jelechem.2019.03.052Y. Fang, B. Suganthan and R.P. Ramasamy, Electrochemical characterzation of aromatic corrosion inhibitors from plant extracts, J. Electroanal. Chem., 2019, 840, 74–83. doi: 10.1016/j.jelechem.2019.03.052A. Zaher, A. Chaouiki and M. Ouhssine, Inhibition of Mild Steel Corrosion in 1 M Hydrochloric Acid Medium by the Methanolic extract of Ammi visnaga L. Sam Seeds, Int. J. Corros., 2020, 9764206 doi: 10.1155/2020/9764206A. Zaher, A. Chaouiki and M. Ouhssine, Inhibition of Mild Steel Corrosion in 1 M Hydrochloric Acid Medium by the Methanolic extract of Ammi visnaga L. Sam Seeds, Int. J. Corros., 2020, 9764206 doi: 10.1155/2020/9764206K.V. Thomas, K.J. Thomas, P.V. Rapheal, A.S. Sabu, K. Ragi and R. Johnson, Tinospora cordifolia extract as an environmentally benign green corrosion inhibitor in acid media: electrochemical, surface morphological, quantum chemical, and statical investigations, Mater. Today Sustain., 2021, 13, 100076 doi: 10.1016/j.mtsust.2021.100076K.V. Thomas, K.J. Thomas, P.V. Rapheal, A.S. Sabu, K. Ragi and R. Johnson, Tinospora cordifolia extract as an environmentally benign green corrosion inhibitor in acid media: electrochemical, surface morphological, quantum chemical, and statical investigations, Mater. Today Sustain., 2021, 13, 100076 doi: 10.1016/j.mtsust.2021.100076M.E.H.N. Tehrani, P. Ghahremani, M. Ramezanzadeh, G. Bahlakeh and B. Ramezanzadeh, Theoretical and experimental assessment of a green corrosion inhibitor extracted from Malva sylvestris, J. Environ. Chem. Eng., 2021, 9, 105256 doi: 10.1016/j.jece.2021.105256M.E.H.N. Tehrani, P. Ghahremani, M. Ramezanzadeh, G. Bahlakeh and B. Ramezanzadeh, Theoretical and experimental assessment of a green corrosion inhibitor extracted from Malva sylvestris, J. Environ. Chem. Eng., 2021, 9, 105256 doi: 10.1016/j.jece.2021.105256M. Abdallah, M. Alfakeer, M. Alshareef, H. Hawsawi, S.S. Al-Juaid, R.S. Abdelhameed and M. Sobhi, Natural Sweet Almond Oil as an Effective Green Inhibitor for Aluminum Corrosion in Sulfuric Acid Medium, Int. J. Electrochem. Sci., 2022, 17, 220949 doi: 10.20964/2022.09.18M. Abdallah, M. Alfakeer, M. Alshareef, H. Hawsawi, S.S. Al-Juaid, R.S. Abdelhameed and M. Sobhi, Natural Sweet Almond Oil as an Effective Green Inhibitor for Aluminum Corrosion in Sulfuric Acid Medium, Int. J. Electrochem. Sci., 2022, 17, 220949 doi: 10.20964/2022.09.18M.R. Rathod, S.K. Rajappa, R.l. Minagalaver, B.M. Praveen, B.K. Devendra and A.A. Kittur, Investigation of African mangosteen leaves extract as an environmentfriendly inhibitor for low carbon steel in H2SO4, Inorg. Chem. Commun., 2022 140, 109488 doi: 10.1016/j.inoche.2022.109488M.R. Rathod, S.K. Rajappa, R.l. Minagalaver, B.M. Praveen, B.K. Devendra and A.A. Kittur, Investigation of African mangosteen leaves extract as an environmentfriendly inhibitor for low carbon steel in H2SO4, Inorg. Chem. Commun., 2022 140, 109488 doi: 10.1016/j.inoche.2022.109488O.A. Hatem, Computational and Experimental evaluation of Inhibition Potential of a New Ecologically Friendly Inhibitor Leaves of Date Palm (Phoenix dactylifera L.) for Aluminium Corrosion in an acidic Media, Int. J. Corros., 2022, 5953561 doi: 10.1155/2022/5953561O.A. Hatem, Computational and Experimental evaluation of Inhibition Potential of a New Ecologically Friendly Inhibitor Leaves of Date Palm (Phoenix dactylifera L.) for Aluminium Corrosion in an acidic Media, Int. J. Corros., 2022, 5953561 doi: 10.1155/2022/5953561G.K. Shamnamol, J. Sam and M.J. Jaya, Experimental and theoretical evidence for effective corrosion mitigation in mild steel using Garcinia gummi-gutta leaf extract, Anti-Corros. Methods Mater., 2022, 69, 540–549 doi: 10.1108/ACMM-03-2022-2630G.K. Shamnamol, J. Sam and M.J. Jaya, Experimental and theoretical evidence for effective corrosion mitigation in mild steel using Garcinia gummi-gutta leaf extract, Anti-Corros. Methods Mater., 2022, 69, 540–549 doi: 10.1108/ACMM-03-2022-2630J.R.T. Hernandez, E.D.A. Meraz and E.F. Corvo Perez, Tradescantia spathacea: New green corrosion inhibitor for SAE 1010 steel in acid medium, Int. J. Corros. Scale Inhib., 2023, 12, 61–83 doi: 10.17675/2305-6894-2023-12-1-4J.R.T. Hernandez, E.D.A. Meraz and E.F. Corvo Perez, Tradescantia spathacea: New green corrosion inhibitor for SAE 1010 steel in acid medium, Int. J. Corros. Scale Inhib., 2023, 12, 61–83 doi: 10.17675/2305-6894-2023-12-1-4X. Wang, Q. Zhang, H. Jiang, Y. Gu, X. Li and L-l. Xu, Pueraria lobata leaf extract as green corrosion inhibitor for low carbon steel in 1.0 M HCl solution, Res. Chem. Intermed., 2021, 47, 1051–1069 doi: 10.1007/s11164-020-04316-3X. Wang, Q. Zhang, H. Jiang, Y. Gu, X. Li and L-l. Xu, Pueraria lobata leaf extract as green corrosion inhibitor for low carbon steel in 1.0 M HCl solution, Res. Chem. Intermed., 2021, 47, 1051–1069 doi: 10.1007/s11164-020-04316-3J.S. Chauhan, Anticorosion behaviour of Zenthoxylum alatum Extract in Acidic Media, Asian J. Chem, 2009, 21, 1975–1978.J.S. Chauhan, Anticorosion behaviour of Zenthoxylum alatum Extract in Acidic Media, Asian J. Chem, 2009, 21, 1975–1978.U.K. Garg, V. Kumpawat, R. Chauhan and R.K. Tak, Corrosion inhibition of copper by natural occuring plant Acacia senegal, J. Ind. Chem. Soc., 2011, 88, 513–519U.K. Garg, V. Kumpawat, R. Chauhan and R.K. Tak, Corrosion inhibition of copper by natural occuring plant Acacia senegal, J. Ind. Chem. Soc., 2011, 88, 513–519R.D. Syarif and S.P. Suryadarma, Utilization of Natural Tannin Extract for Copper Corrosion Inhibitor in Hydrochloric Solution, Chem. Mater. Res., 2015, 7, 76–80R.D. Syarif and S.P. Suryadarma, Utilization of Natural Tannin Extract for Copper Corrosion Inhibitor in Hydrochloric Solution, Chem. Mater. Res., 2015, 7, 76–80M. Shabani-Nooshabadi, S.F. Hereiny and Y. Jafari, Green Approach to Corrosion Inhibition of Copper by the Extract Calligonum comosum in Strong Acid Medium, Metal. Mater. Trans. A, 2015, 46, 293–299M. Shabani-Nooshabadi, S.F. Hereiny and Y. Jafari, Green Approach to Corrosion Inhibition of Copper by the Extract Calligonum comosum in Strong Acid Medium, Metal. Mater. Trans. A, 2015, 46, 293–299K.W. Swami, D. Sharma and S. Kumar, Corrosion inhibition of copper by acid of Tecomella undulata, Int. J. Chem. Sci, 2013, 11, 1457–1463.K.W. Swami, D. Sharma and S. Kumar, Corrosion inhibition of copper by acid of Tecomella undulata, Int. J. Chem. Sci, 2013, 11, 1457–1463.J.S. Chauhan, and D.K. Gupta, The anti-corrosive characteristic of Betalains (Bougainvillea flower extract), Elixir Corrosion & Dye, 2015, 80, 30781–30784J.S. Chauhan, and D.K. Gupta, The anti-corrosive characteristic of Betalains (Bougainvillea flower extract), Elixir Corrosion & Dye, 2015, 80, 30781–30784A. Sharma, A. Varshney and S. Varshney, Sesmum indicum Oil as a Potential Inhibitor for the Corrosion of Copper in Acidic Environment, Orient. J. Chem., 2016, 32, 2769– 2775 doi: 10.13005/ojc/320551A. Sharma, A. Varshney and S. Varshney, Sesmum indicum Oil as a Potential Inhibitor for the Corrosion of Copper in Acidic Environment, Orient. J. Chem., 2016, 32, 2769– 2775 doi: 10.13005/ojc/320551B. M.Maibulangu, M.B. Ibrahim and L.K. Akinola, Inhibitory Effect of African Pumpkin (Momordica balsamina Linn) Leaf Extract on copper corrosion in acidic media, J. App. Sci. Environ. Manage, 2017, 21, 1067–1071 doi: 10.4314/jasem.v21i6.12B. M.Maibulangu, M.B. Ibrahim and L.K. Akinola, Inhibitory Effect of African Pumpkin (Momordica balsamina Linn) Leaf Extract on copper corrosion in acidic media, J. App. Sci. Environ. Manage, 2017, 21, 1067–1071 doi: 10.4314/jasem.v21i6.12P.S. Pratihar and J. Rawat, Corrosion Inhibition of Copper Metal by Prosopis Cineraria Leaves as Green Corrosion Inhibitor in Acidic Medium, Int. J. Res. Appl. Sci. Engg. Tech., 2017, 5, 2412–2421.P.S. Pratihar and J. Rawat, Corrosion Inhibition of Copper Metal by Prosopis Cineraria Leaves as Green Corrosion Inhibitor in Acidic Medium, Int. J. Res. Appl. Sci. Engg. Tech., 2017, 5, 2412–2421.R.K. Ahmed and S. Zhang, Bee pollen extract as an eco-friendly corrosion inhibitor for pure copper in hydrochloric acid, J. Mol. Liq., 2020 316, 113849 doi: 10.1016/j.molliq.2020.113840R.K. Ahmed and S. Zhang, Bee pollen extract as an eco-friendly corrosion inhibitor for pure copper in hydrochloric acid, J. Mol. Liq., 2020 316, 113849 doi: 10.1016/j.molliq.2020.113840A. Jmiami, B. El-Ibrahimi, A. Tara, M. Chadili, S.El- Issami, O. Jbara, A. Khallaayoun and L. Bazzi, Application of Zizyphus Lotuse-pulp of Jujube extract as green and promising corrosion inhibitor for copper in acidic medium, J. Mol. Liq., 2018, 268, 102– 113 doi: 1016/j.molliq.2018.06.091A. Jmiami, B. El-Ibrahimi, A. Tara, M. Chadili, S.El- Issami, O. Jbara, A. Khallaayoun and L. Bazzi, Application of Zizyphus Lotuse-pulp of Jujube extract as green and promising corrosion inhibitor for copper in acidic medium, J. Mol. Liq., 2018, 268, 102– 113 doi: 1016/j.molliq.2018.06.091A. Büyüksağis and M. Dilek, The use of Papever somniferum L Plant Extract as Corrosion Inhibitor, Prot. Met. Phy. Chem. Surf., 2019, 55, 1182–1194 doi: 10.1134/S2070205119060042A. Büyüksağis and M. Dilek, The use of Papever somniferum L Plant Extract as Corrosion Inhibitor, Prot. Met. Phy. Chem. Surf., 2019, 55, 1182–1194 doi: 10.1134/S2070205119060042а. A. Samontha and K. Lugsanangarm, Corrosion Inhibition and adsorption mechanism of Eugenol on Copper in HCl Medium, Prot. Met. Phys. Chem. Surf., 2019, 55, 187–194 doi: 10.1134/S2070205119010192; b. A. Samontha and N. Jitsamak, Effect of temperature on Inhibition efficiency of Eugenol for Copper Corrosion, Life Sci. Environ. J., 2019, 20, 165–171а. A. Samontha and K. Lugsanangarm, Corrosion Inhibition and adsorption mechanism of Eugenol on Copper in HCl Medium, Prot. Met. Phys. Chem. Surf., 2019, 55, 187–194 doi: 10.1134/S2070205119010192; b. A. Samontha and N. Jitsamak, Effect of temperature on Inhibition efficiency of Eugenol for Copper Corrosion, Life Sci. Environ. J., 2019, 20, 165–171A. Jmiai, A. Tara, S. El-Issami, M. Hilali, O. Jbara and L. Bazzi, A new trend in corrosion protection of copper in acidic medium by using Jujube shell extract as an effective green and environmentally safe corrosion inhibitor: Experimental, quantum chemistry approach and Monte Carlo simulation study, J. Mol. Liq., 2021, 332, 114509 doi: 10.1016/j.molliq.2020.114509A. Jmiai, A. Tara, S. El-Issami, M. Hilali, O. Jbara and L. Bazzi, A new trend in corrosion protection of copper in acidic medium by using Jujube shell extract as an effective green and environmentally safe corrosion inhibitor: Experimental, quantum chemistry approach and Monte Carlo simulation study, J. Mol. Liq., 2021, 332, 114509 doi: 10.1016/j.molliq.2020.114509R. Ahmed and S. Zhang, Alchemilla Vulgaris Extract as Green Inhibitor of Copper Corrosion in Hydrocholoric Acid, Int. J. Electrochem. Sci., 2019, 14, 10657–10669 doi: 10.20964/2019.11.43R. Ahmed and S. Zhang, Alchemilla Vulgaris Extract as Green Inhibitor of Copper Corrosion in Hydrocholoric Acid, Int. J. Electrochem. Sci., 2019, 14, 10657–10669 doi: 10.20964/2019.11.43M. Shabani-Nooshabadi, F.S. Hoseiny and Y. Jafari, Corrosion Inhibition of Copper by Ephedra sarcocarpa Plant Extract as Green Corrosion Inhibitor in Strong Acid Medium, Anal. Bioanal. Electrochem., 2014, 6, no. 3, 341–354M. Shabani-Nooshabadi, F.S. Hoseiny and Y. Jafari, Corrosion Inhibition of Copper by Ephedra sarcocarpa Plant Extract as Green Corrosion Inhibitor in Strong Acid Medium, Anal. Bioanal. Electrochem., 2014, 6, no. 3, 341–354M.A. Deyab, Egyptian licorice extract as a green corrosion inhibitor for copper in hydrocholoric acid solution, J. Ind. Eng. Chem., 2015, 22, 384–389 doi: 10.1016/j.jiec.2014.07.036M.A. Deyab, Egyptian licorice extract as a green corrosion inhibitor for copper in hydrocholoric acid solution, J. Ind. Eng. Chem., 2015, 22, 384–389 doi: 10.1016/j.jiec.2014.07.036а. H. Kalada and A.O. James, The inhibitive effect of Aloe vera Barbadensis Gel on copper in Hydrocholoric acid medium, J. Emerging Trends Eng. Appl. Sci., 2014, 5, 24– 49; b. K. Hart and A.O. James, Corrosion Inhibition of Copper in Hydrocholoric Acid and Tetraoxosulphate (VI) Acid Solutions Using Aloe Vera Barbadensis Gel, Br. J. Appl. Sci. Technol., 2014, 4, 4052–4065.а. H. Kalada and A.O. James, The inhibitive effect of Aloe vera Barbadensis Gel on copper in Hydrocholoric acid medium, J. Emerging Trends Eng. Appl. Sci., 2014, 5, 24– 49; b. K. Hart and A.O. James, Corrosion Inhibition of Copper in Hydrocholoric Acid and Tetraoxosulphate (VI) Acid Solutions Using Aloe Vera Barbadensis Gel, Br. J. Appl. Sci. Technol., 2014, 4, 4052–4065.S. Yadav and A. Sharma, Effect of temperature on protective propensity of Acacia nilotica on acid corrosion of copper, Rev. Res., 2013, 2, 1–15S. Yadav and A. Sharma, Effect of temperature on protective propensity of Acacia nilotica on acid corrosion of copper, Rev. Res., 2013, 2, 1–15а. A.M. Shah, A.A. Rahim, S. Yahya, PB. Raja and S.A. Hamid, Acid corrosion inhibition of copper by mangrove tannin, Pigm. Resin Technol., 2011, 40, 118–122 doi: 10.1108/03699421111113783; b. A.M. Shah, A.A. Rahim, S.A. Hamid and S. Yahya, Green Inhibitors for Copper Corrosion by Mangrove Tannin, Int. J. Electrochem. Sci., 2013, 8, 2140–2153.а. A.M. Shah, A.A. Rahim, S. Yahya, PB. Raja and S.A. Hamid, Acid corrosion inhibition of copper by mangrove tannin, Pigm. Resin Technol., 2011, 40, 118–122 doi: 10.1108/03699421111113783; b. A.M. Shah, A.A. Rahim, S.A. Hamid and S. Yahya, Green Inhibitors for Copper Corrosion by Mangrove Tannin, Int. J. Electrochem. Sci., 2013, 8, 2140–2153.S. Yadav, G. Chaudhary and A. Sharma, Green approach to corrosion inhibition of aluminium and copper by Ziziphus mauritiana fruit extract in hydrochloric acid solution, Int. J. Chem. Tech. Res., 2013, 5, 1815–1823.S. Yadav, G. Chaudhary and A. Sharma, Green approach to corrosion inhibition of aluminium and copper by Ziziphus mauritiana fruit extract in hydrochloric acid solution, Int. J. Chem. Tech. Res., 2013, 5, 1815–1823.S. Yadav, A. Sharma, G. Chaudhary, Monika and A. Sharma, Inhibitive and adsorption properties of Ethanolic Extract of fruit Azadirachta indica on the corrosion of copper in HCl, International Journal of Innovative Research in Science, Engineering and Technology, 2014, 3, 16127–16136 doi: 10.15680/IJIRSET.2014.0309048S. Yadav, A. Sharma, G. Chaudhary, Monika and A. Sharma, Inhibitive and adsorption properties of Ethanolic Extract of fruit Azadirachta indica on the corrosion of copper in HCl, International Journal of Innovative Research in Science, Engineering and Technology, 2014, 3, 16127–16136 doi: 10.15680/IJIRSET.2014.0309048L. Cai, Q. Fu, R. Shi, Y. Tang, Yi-Tao Long, Xiao-Peng He, Y. Jin, G. Liu, Guo-Rang Chen and K. Chen, Purgent Copper Surface Resists Acid Corrosion in Strong HCl Solutions, Ind. Eng. Chem. Res., 2013, 53, 64–69. doi: 10.1021/ie402609gL. Cai, Q. Fu, R. Shi, Y. Tang, Yi-Tao Long, Xiao-Peng He, Y. Jin, G. Liu, Guo-Rang Chen and K. Chen, Purgent Copper Surface Resists Acid Corrosion in Strong HCl Solutions, Ind. Eng. Chem. Res., 2013, 53, 64–69. doi: 10.1021/ie402609gP. Deivanayagam, I. Malarvizhi and S. Selvaraj, Wrightia tinctoria leaves extract as effective corrosion inhibitor on copper in acid environment, Int. J. Chem. Pharm. Anal., 2016, 3, 969P. Deivanayagam, I. Malarvizhi and S. Selvaraj, Wrightia tinctoria leaves extract as effective corrosion inhibitor on copper in acid environment, Int. J. Chem. Pharm. Anal., 2016, 3, 969R.S. Oguike, O. Oni1, A.U. Barambu, D. Balarak, Ch.U. Okeke, L.S. Momoh, S. Onimisi, W.J. Nwada and T. Buba, Computational Stimulation and Experimental Study on Corrosion Inhibition Qualities of Emilia sonchifolia Leaf Extract for Copper (CU131729) in Hydrocholoric Acid, Comput. Chem., 2021, 09, 18–36 doi: 10.4236/cc.2021.91002R.S. Oguike, O. Oni1, A.U. Barambu, D. Balarak, Ch.U. Okeke, L.S. Momoh, S. Onimisi, W.J. Nwada and T. Buba, Computational Stimulation and Experimental Study on Corrosion Inhibition Qualities of Emilia sonchifolia Leaf Extract for Copper (CU131729) in Hydrocholoric Acid, Comput. Chem., 2021, 09, 18–36 doi: 10.4236/cc.2021.91002P.S. Pratihar, M.P.S. Verma and A. Sharma, Capparis decidua seeds: potential green inhibitor to combat acid corrosion of copper, Rasayan J. Chem., 2015, 8, 411–421P.S. Pratihar, M.P.S. Verma and A. Sharma, Capparis decidua seeds: potential green inhibitor to combat acid corrosion of copper, Rasayan J. Chem., 2015, 8, 411–421A. Bright, M.R. Maragatham, I.M. Vizhi, K.Dr. Kalirajan and S.Dr. Selvaraj, Corrosion Inhibition of Pure Copper Using Pisonia Grandis Leaves Extract in Acid Environment, Int. J. Curr. Res., 2015, 7, 20566–20573.A. Bright, M.R. Maragatham, I.M. Vizhi, K.Dr. Kalirajan and S.Dr. Selvaraj, Corrosion Inhibition of Pure Copper Using Pisonia Grandis Leaves Extract in Acid Environment, Int. J. Curr. Res., 2015, 7, 20566–20573.M.S. Rani and C. Subha, Adsorption and Inhibitive Properties of Coccinia Grandis Fruit Extract as Green Corrosion Inhibitor for Copper in acid Media, J. Emerging Trends Eng. Appl. Sci., 2019, 9, 63–73M.S. Rani and C. Subha, Adsorption and Inhibitive Properties of Coccinia Grandis Fruit Extract as Green Corrosion Inhibitor for Copper in acid Media, J. Emerging Trends Eng. Appl. Sci., 2019, 9, 63–73N. Kavitha, J. Ravichandran and A.M. Urugesh, An Eco-friendly Leucas Aspera Leaves Extract Inhibitor for Copper Corrosion in Hydrochloric Acid Medium, J. Bio- and TriboCorros., 2020, 6, 103 doi: 10.1007/s40735-020-00400-8N. Kavitha, J. Ravichandran and A.M. Urugesh, An Eco-friendly Leucas Aspera Leaves Extract Inhibitor for Copper Corrosion in Hydrochloric Acid Medium, J. Bio- and TriboCorros., 2020, 6, 103 doi: 10.1007/s40735-020-00400-8R.H. Ahmed and S.Zhang, Atriplex leucoclada extract: A promising eco-friendly anticorrosive agent for copper in aqueous media, J. Ind. Eng. Chem., 2021, 99, 334–343 doi: 10.1016/j.jiec.2021.04.042R.H. Ahmed and S.Zhang, Atriplex leucoclada extract: A promising eco-friendly anticorrosive agent for copper in aqueous media, J. Ind. Eng. Chem., 2021, 99, 334–343 doi: 10.1016/j.jiec.2021.04.042S. Kathiravan, S. Jathi, G. Ayyannan, J. Ravichandran and G. Raja, Inhibitory action of aqueous Ruellia Tuberosa L leaves extract on the corrosion of copper in HCl solution, J. Ind. Chem. Soc., 2021, 98, 100207 doi: 10.1016/j.jics.2021.100207S. Kathiravan, S. Jathi, G. Ayyannan, J. Ravichandran and G. Raja, Inhibitory action of aqueous Ruellia Tuberosa L leaves extract on the corrosion of copper in HCl solution, J. Ind. Chem. Soc., 2021, 98, 100207 doi: 10.1016/j.jics.2021.100207O.A. Odunlami, O.S. Fayomi, I.O. Elendu and J.O. Ojediran, Zea Mays surfactant as corrosion inhibition of Copper and its Electrochemical Assessment in hot Acidic Solution for Chemo-Mechanical Application, Mater. Sci Forum, 2022, 1050, 81–91 doi: 10.4028/www.scientific.net/MSF.1050.81O.A. Odunlami, O.S. Fayomi, I.O. Elendu and J.O. Ojediran, Zea Mays surfactant as corrosion inhibition of Copper and its Electrochemical Assessment in hot Acidic Solution for Chemo-Mechanical Application, Mater. Sci Forum, 2022, 1050, 81–91 doi: 10.4028/www.scientific.net/MSF.1050.81A. Diab and S.M. Abd El-Haleem, Corrosion Inhibition of copper in Acidic Solution by using a Natural Product as Henna (Lawsonia inermis L) Extract, Egypt. J. Chem., 2022, 65, 103–111.A. Diab and S.M. Abd El-Haleem, Corrosion Inhibition of copper in Acidic Solution by using a Natural Product as Henna (Lawsonia inermis L) Extract, Egypt. J. Chem., 2022, 65, 103–111.F. Kaya, R. Solmaz and İ.H. Geçibesler, The Use of Rheum Ribes (ışgın) Extracts for Copper Protection in Acidic Media, Türk Doğa ve Fen Dergisi, 2022, 11, 94–101 (in Turkish) doi: 10.46810/tdfd.1166367F. Kaya, R. Solmaz and İ.H. Geçibesler, The Use of Rheum Ribes (ışgın) Extracts for Copper Protection in Acidic Media, Türk Doğa ve Fen Dergisi, 2022, 11, 94–101 (in Turkish) doi: 10.46810/tdfd.1166367R. Thivagaran, N. Salim and N.H. Abu Bakar, Ethanolic Mangifera Indica Leaves Extract as Green Corrosion Inhibitor, J. Adv. Res. Appl. Sci. Eng. Technol., 2023, 29, 228–234 doi: 10.37934/araset.29.3.228234R. Thivagaran, N. Salim and N.H. Abu Bakar, Ethanolic Mangifera Indica Leaves Extract as Green Corrosion Inhibitor, J. Adv. Res. Appl. Sci. Eng. Technol., 2023, 29, 228–234 doi: 10.37934/araset.29.3.228234а. T.V. Sangeetha and M. Fredimoses, Inhibition of Mild Copper Metal Corrosion in HNO3 Medium by Acid Extract of Azadirachta Indica seed, E-J. Chem., 2011, 8, 135952 doi: 10.1155/2011/135952; b. K.K. Patel and R.T. Vashi, Azadirachta Indica Extract as Corrosion Inhibitor for Copper in Nitric Acid Medium, Res. J. Chem. Sci., 2015, 5, 59– 66; c. L. Mitu, R. Rubavathi, M. Subramani, T. Linda and S. Balakumar, Azadirachta indica Leaf as a Corrosion Inhibitor for Copper in Nitric Acid, Rev. Chim, 2019, 70, 581– 584 doi: 10.37358/RC.19.2.6960а. T.V. Sangeetha and M. Fredimoses, Inhibition of Mild Copper Metal Corrosion in HNO3 Medium by Acid Extract of Azadirachta Indica seed, E-J. Chem., 2011, 8, 135952 doi: 10.1155/2011/135952; b. K.K. Patel and R.T. Vashi, Azadirachta Indica Extract as Corrosion Inhibitor for Copper in Nitric Acid Medium, Res. J. Chem. Sci., 2015, 5, 59– 66; c. L. Mitu, R. Rubavathi, M. Subramani, T. Linda and S. Balakumar, Azadirachta indica Leaf as a Corrosion Inhibitor for Copper in Nitric Acid, Rev. Chim, 2019, 70, 581– 584 doi: 10.37358/RC.19.2.6960N. Ogborna, C.M. Matthew and D.O. Okechukwu, Inhibition of copper corrosion by acid extracts of Gnetum africana and Musa acuminate peel, Int. J. Multidiscip. Sci. Eng., 2011, 2, 5–9N. Ogborna, C.M. Matthew and D.O. Okechukwu, Inhibition of copper corrosion by acid extracts of Gnetum africana and Musa acuminate peel, Int. J. Multidiscip. Sci. Eng., 2011, 2, 5–9S. Houbani, M. Essahli and A. Lamiri, Inhibition of Copper Corrosion in 2 M HNO3 by the Essential Oil of Tyme Morocco, Port. Electrochim. Acta, 2013, 31, 221–233 doi: 10.4152/pea.201304221S. Houbani, M. Essahli and A. Lamiri, Inhibition of Copper Corrosion in 2 M HNO3 by the Essential Oil of Tyme Morocco, Port. Electrochim. Acta, 2013, 31, 221–233 doi: 10.4152/pea.201304221A.S. Fouda, K. Shalabi and A.A. Idress, Thymus Vulgarise Extract as Nontoxic Corrosion Inhibitor for Copper and α-Brass in 1 M HNO3 Solutions, Int. J. Electrochem. Sci., 2014, 9, 5126–5154A.S. Fouda, K. Shalabi and A.A. Idress, Thymus Vulgarise Extract as Nontoxic Corrosion Inhibitor for Copper and α-Brass in 1 M HNO3 Solutions, Int. J. Electrochem. Sci., 2014, 9, 5126–5154S. Houbairi, A. Lamiri and M. Essahli, Oil Ricinus communis for Copper in 2 M Nitric Acid Solution, Int. J. Eng. Res. Sci. Technol., 2014, 3, 698–707S. Houbairi, A. Lamiri and M. Essahli, Oil Ricinus communis for Copper in 2 M Nitric Acid Solution, Int. J. Eng. Res. Sci. Technol., 2014, 3, 698–707A.S. Fouda, Y.M. Abdallah, G.Y. Elawady and R.M. Ahmed, Zygophllum coccineum L Extract as green corrosion inhibitor for copper in 1M HNO3 solutions, Int. J. Adv. Res., 2014, 2, 517–531.A.S. Fouda, Y.M. Abdallah, G.Y. Elawady and R.M. Ahmed, Zygophllum coccineum L Extract as green corrosion inhibitor for copper in 1M HNO3 solutions, Int. J. Adv. Res., 2014, 2, 517–531.S. Fouda, K. Shalabi and A.A. Idress, Ceratonia siliqua extract as a green corrosion inhibitor for copper and brass in nitric acid solutions, Green Chem. Lett. Rev., 2015, 8, 17–29 doi: 10.1080/17518253.2015.1073797S. Fouda, K. Shalabi and A.A. Idress, Ceratonia siliqua extract as a green corrosion inhibitor for copper and brass in nitric acid solutions, Green Chem. Lett. Rev., 2015, 8, 17–29 doi: 10.1080/17518253.2015.1073797R.M. Younis, H.M. Hassan, R.A. Mansour and A.M. El-desoky, Corrosion Inhibition of Carapichea Ipecacuanha Extract (CIE) on Copper in 1 M HNO3 Solution, Int. J. Sci. Eng. Res., 2015, 6, 761–770R.M. Younis, H.M. Hassan, R.A. Mansour and A.M. El-desoky, Corrosion Inhibition of Carapichea Ipecacuanha Extract (CIE) on Copper in 1 M HNO3 Solution, Int. J. Sci. Eng. Res., 2015, 6, 761–770Y.M. Abdallah and K. Shalabi, Comprehensive study of the Behavior of Copper Inhibition in 1 M HNO3 by Euphorbia Helioscopia linn. Extract as Green inhibitor, Prot. Met. Phys. Chem. Surf., 2015, 51, 275–284 doi: 10.1134/S2070205115020021Y.M. Abdallah and K. Shalabi, Comprehensive study of the Behavior of Copper Inhibition in 1 M HNO3 by Euphorbia Helioscopia linn. Extract as Green inhibitor, Prot. Met. Phys. Chem. Surf., 2015, 51, 275–284 doi: 10.1134/S2070205115020021A.M. Eeldesoky, A.S. Fouda, G.E. Bekheit and N.S. Elsheikh, Adsorption and Corrosion Inhibition of Alkanna Tincotria Extract (ATE) on Copper in 1 M HNO3 Solution, Int. J. Adv. Res., 2015, 3, 991–1007A.M. Eeldesoky, A.S. Fouda, G.E. Bekheit and N.S. Elsheikh, Adsorption and Corrosion Inhibition of Alkanna Tincotria Extract (ATE) on Copper in 1 M HNO3 Solution, Int. J. Adv. Res., 2015, 3, 991–1007Y.M. Abdallah, G.Y. Elawady and R.M. Ahmed, Electrochemical study on the effectively of Hyoscyamus muticus extract as a green inhibitor for corrosion of copper in 1 M HNO3, J. Mater. Environ. Sci., 2014, 5, 1519–1531Y.M. Abdallah, G.Y. Elawady and R.M. Ahmed, Electrochemical study on the effectively of Hyoscyamus muticus extract as a green inhibitor for corrosion of copper in 1 M HNO3, J. Mater. Environ. Sci., 2014, 5, 1519–1531Savita, P. Mourya, N. Chaubey, V.K. Singh and M.M.S. Singh, Eco-Friendly Inhibitors for Copper Corrosion in Nitric Acid: Experimental and Theoretical Evaluation, Metal. Mater. Trans. B, 2015, 47, 47–57 doi: 10.1007/s11663-015-0488-6Savita, P. Mourya, N. Chaubey, V.K. Singh and M.M.S. Singh, Eco-Friendly Inhibitors for Copper Corrosion in Nitric Acid: Experimental and Theoretical Evaluation, Metal. Mater. Trans. B, 2015, 47, 47–57 doi: 10.1007/s11663-015-0488-6N.C. Savita, M. Punita, V.K. Singh and M.M. Singh, Fruit extract as green inhibitor for copper corrosion in Nitric acid solution, Int. J. Innov. Res. Sci. Eng. Tech, 2015, 4, 4545– 4553N.C. Savita, M. Punita, V.K. Singh and M.M. Singh, Fruit extract as green inhibitor for copper corrosion in Nitric acid solution, Int. J. Innov. Res. Sci. Eng. Tech, 2015, 4, 4545– 4553B. Aicha, H. Mustapha, B. Lahcen, E. Souad and Z. Hanene, Study of Copper Corrosion Inhibition by the Mineralization of the Red Alga Gellidium in Nitric Acid Investigated by Chemical and Spectroscopic Techniques, Amer. J. Innov. Res. Appl. Sci., 2018, 7, 159–168B. Aicha, H. Mustapha, B. Lahcen, E. Souad and Z. Hanene, Study of Copper Corrosion Inhibition by the Mineralization of the Red Alga Gellidium in Nitric Acid Investigated by Chemical and Spectroscopic Techniques, Amer. J. Innov. Res. Appl. Sci., 2018, 7, 159–168V. Kouakcu, P.M. Niamien, A.J. Yapo, S. Diaby and A. Trokourey, Experimental and DFT Studies on the behavior of Caffeine as Effective Corrosion inhibitor of Copper in 1M HNO3, Orbital: Electro. J. Chem., 2016, 8, 66–79. doi: 10.17807/orbital.v8i2.804V. Kouakcu, P.M. Niamien, A.J. Yapo, S. Diaby and A. Trokourey, Experimental and DFT Studies on the behavior of Caffeine as Effective Corrosion inhibitor of Copper in 1M HNO3, Orbital: Electro. J. Chem., 2016, 8, 66–79. doi: 10.17807/orbital.v8i2.804A.S. Fouda, A.E. Mohamed and M.A. Khalid, Trigonella stellate extract as corrosion inhibitor for copper in 1M HNO3 solution, J. Chem. Pharm. Res. 2016, 8, 86–98A.S. Fouda, A.E. Mohamed and M.A. Khalid, Trigonella stellate extract as corrosion inhibitor for copper in 1M HNO3 solution, J. Chem. Pharm. Res. 2016, 8, 86–98S. Savita, P. Mourya, N. Chaubey, S. Kumar, V.K. Singh and M. M.Singh, Strychnos nuxvomica, Piper longum and Mucuna pruriens seed extracts as eco-friendly corrosion inhibitors for copper in nitric acid, RSC Adv, 2016, 6, 95644–95655. doi: 10.1039/c6ra16481aS. Savita, P. Mourya, N. Chaubey, S. Kumar, V.K. Singh and M. M.Singh, Strychnos nuxvomica, Piper longum and Mucuna pruriens seed extracts as eco-friendly corrosion inhibitors for copper in nitric acid, RSC Adv, 2016, 6, 95644–95655. doi: 10.1039/c6ra16481aF.Z. Al-Wediar, M.A. Qudah and G.M. Al-Mazaideh, Corrosion Inhibition of Copper by Capparis spinosa L.extract in Strong acid Mediım: Experimental and Density Functional Theory, Int. J. Electrochem. Sci., 2017, 12, 4664–4676. doi: 10.20964/2017.06.47F.Z. Al-Wediar, M.A. Qudah and G.M. Al-Mazaideh, Corrosion Inhibition of Copper by Capparis spinosa L.extract in Strong acid Mediım: Experimental and Density Functional Theory, Int. J. Electrochem. Sci., 2017, 12, 4664–4676. doi: 10.20964/2017.06.47A.S. Fouda, S.H. Etaiw, D.M.A. El-Aziz and O.A. Elbaz, Synergistic effect of barium chloride on corrosion inhibition of copper by aqueous extract of lupine seeds in nitric acid, Int. J. Electrochem. Sci., 2017, 12, 5934–5950. doi: 10.20964/2017.07.08A.S. Fouda, S.H. Etaiw, D.M.A. El-Aziz and O.A. Elbaz, Synergistic effect of barium chloride on corrosion inhibition of copper by aqueous extract of lupine seeds in nitric acid, Int. J. Electrochem. Sci., 2017, 12, 5934–5950. doi: 10.20964/2017.07.08A.S. Fouda, A.A. Aal and E.A. Haleem, Calotropis Procera Extract (CPE) as Corrosion Inhibitor for Copper in Nitric Acid Medium, Bull. Fac. Sci., Zagazig Univ., 2017, 39, 204–227A.S. Fouda, A.A. Aal and E.A. Haleem, Calotropis Procera Extract (CPE) as Corrosion Inhibitor for Copper in Nitric Acid Medium, Bull. Fac. Sci., Zagazig Univ., 2017, 39, 204–227A.S. Fouda, M.A. Elmorsi and B.S. Abou-Elmagd, Adsorption and inhibitive properties of Methanol extract of Eeuphorbia heterophlla for the corrosion of copper in 0.5 M nitric acid solutions, Pol. J. Chem. Technol., 2017, 19, 95–103. doi: 10.1515/pjct-2017-0014A.S. Fouda, M.A. Elmorsi and B.S. Abou-Elmagd, Adsorption and inhibitive properties of Methanol extract of Eeuphorbia heterophlla for the corrosion of copper in 0.5 M nitric acid solutions, Pol. J. Chem. Technol., 2017, 19, 95–103. doi: 10.1515/pjct-2017-0014A.S. Fouda and E.A. Haleem, Berry Leaves Extract as Green Effective Corrosion Inhibitor for Cu in Nitric Acid Solutions, Surf. Eng. Appl. Electrochem., 2018, 54, 498– 507A.S. Fouda and E.A. Haleem, Berry Leaves Extract as Green Effective Corrosion Inhibitor for Cu in Nitric Acid Solutions, Surf. Eng. Appl. Electrochem., 2018, 54, 498– 507A.S. Fouda and H.M. Elabbasy, Corrosion Inhibition Effect of Methanol Extract of Nerium Oleander on Copper in Nitric Acid Solutions, Int. J. Electrochem. Sci., 2019, 14, 6884–6901. doi: 10.20964/2019.07.31A.S. Fouda and H.M. Elabbasy, Corrosion Inhibition Effect of Methanol Extract of Nerium Oleander on Copper in Nitric Acid Solutions, Int. J. Electrochem. Sci., 2019, 14, 6884–6901. doi: 10.20964/2019.07.31M.M. Motavea, A. El-Hossiany and A.S. Fouda, Corrosion Control of Copper in Nitric Acid Solution Using Chenopodium Extract, Int. J. Electrochem. Sci., 2019, 14, 1372– 1387. doi: 10.20964/2019.02.29M.M. Motavea, A. El-Hossiany and A.S. Fouda, Corrosion Control of Copper in Nitric Acid Solution Using Chenopodium Extract, Int. J. Electrochem. Sci., 2019, 14, 1372– 1387. doi: 10.20964/2019.02.29H.M. Elabbasy, Investigation of Withania somnifera Extract as Corrosion Inhibitor for Copper in Nitric Acid Solutions, Int. J. Electrochem. Sci., 2019, 14, 5355–5372. doi: 10.20964/2019.06.23H.M. Elabbasy, Investigation of Withania somnifera Extract as Corrosion Inhibitor for Copper in Nitric Acid Solutions, Int. J. Electrochem. Sci., 2019, 14, 5355–5372. doi: 10.20964/2019.06.23S.Y. Al-Nami and A.S. Fouda, Corrosion Inhibition Effect and Adsorption Activities of methanolic myrrh extract for Cu in 2 M HNO3, Int. J. Electrochem. Sci., 2020, 15, 1187– 1205. doi: 10.20964/2020.02.23S.Y. Al-Nami and A.S. Fouda, Corrosion Inhibition Effect and Adsorption Activities of methanolic myrrh extract for Cu in 2 M HNO3, Int. J. Electrochem. Sci., 2020, 15, 1187– 1205. doi: 10.20964/2020.02.23A.A. Idress and A.S. Fouda, Investigation of the inhibition of copper and α-brass corrosion in nitric acid solutions by Pistacia atlantica extract, The Third Int. Conf. Basic Sci. & Their Appl., June 2019, Omar Al-Mukhtar Univ, El-Beida-Libya. https://doi.org/10.53555/eijas.v6i2.97A.A. Idress and A.S. Fouda, Investigation of the inhibition of copper and α-brass corrosion in nitric acid solutions by Pistacia atlantica extract, The Third Int. Conf. Basic Sci. & Their Appl., June 2019, Omar Al-Mukhtar Univ, El-Beida-Libya. https://doi.org/10.53555/eijas.v6i2.97а. O.C. Nkuzinna, M.C. Menkiti, O.D. Onukwuli, G.O. Mbah, B.I. Okolo, M.C. Egbujor and R.M. Goverment, Application of Factorial Design of Experiment for Optimization of Inhibition Effect of Acid Extract of Gnetum africana on Copper Corrosion, Nat. Resour., 2014, 5, 299–307. doi: 10.4236/nr.2014.57028; b. J. Saka, O.N. Ahmed and A.S. Adekunle, On the use of factorial experiments for optimizing inhibition effect of acid extract of Gnetum Africana on copper corrosion, Int. J. Corros. Scale Inhib., 2020, 9, no. 1, 284–299. doi: 10.17675/2305-6894-2020-9-1-18а. O.C. Nkuzinna, M.C. Menkiti, O.D. Onukwuli, G.O. Mbah, B.I. Okolo, M.C. Egbujor and R.M. Goverment, Application of Factorial Design of Experiment for Optimization of Inhibition Effect of Acid Extract of Gnetum africana on Copper Corrosion, Nat. Resour., 2014, 5, 299–307. doi: 10.4236/nr.2014.57028; b. J. Saka, O.N. Ahmed and A.S. Adekunle, On the use of factorial experiments for optimizing inhibition effect of acid extract of Gnetum Africana on copper corrosion, Int. J. Corros. Scale Inhib., 2020, 9, no. 1, 284–299. doi: 10.17675/2305-6894-2020-9-1-18Abd El-Aziz Fouda, Abd-El Moneim, M. Ahmed, S.M. El-Danier and S.E. Badr, Fagonia arabica extract as a save-environment green corrosion inhibitor for Cu in HNO3, J. Chin. Chem. Soc., 2021, 68, 1445–1455. doi: 10.1002/jccs.202000571Abd El-Aziz Fouda, Abd-El Moneim, M. Ahmed, S.M. El-Danier and S.E. Badr, Fagonia arabica extract as a save-environment green corrosion inhibitor for Cu in HNO3, J. Chin. Chem. Soc., 2021, 68, 1445–1455. doi: 10.1002/jccs.202000571M.I. El-Tantawy, H.S. Gadow, I.G. Rashed, Abd El-Aziz and S. Fouda, Inhibition of Copper Corrosion by Rice Straw Extract in 2 M Solution of Nitric Acid, Biointerface Res. App. Chem., 2022, 12, 83–104. doi: 10.33263/BRIAC121.083104M.I. El-Tantawy, H.S. Gadow, I.G. Rashed, Abd El-Aziz and S. Fouda, Inhibition of Copper Corrosion by Rice Straw Extract in 2 M Solution of Nitric Acid, Biointerface Res. App. Chem., 2022, 12, 83–104. doi: 10.33263/BRIAC121.083104а. I. Kusumaningrum, R. Soenoko, E. Siswanto and F. Gapsari, Investigation of Artocarpus Heterophyllus peel extract as non –toxic corrosion inhibitor for pure copper protection in nitric acid, Case Stud. Chem. Environ. Eng., 2022, 6, 100223. doi: 10.1016/j.cscee.2022.100223; b. J. He, Q. Xu, Q. Li, R. Marzouki and W. Li, Insight into the corrosion inhibition property of Artocarpus heterophyllus Lam leaves extract, J. Ind. Eng. Chem., 2021, 102, 260–270. doi: 10.1016/j.jiec.2021.07.007а. I. Kusumaningrum, R. Soenoko, E. Siswanto and F. Gapsari, Investigation of Artocarpus Heterophyllus peel extract as non –toxic corrosion inhibitor for pure copper protection in nitric acid, Case Stud. Chem. Environ. Eng., 2022, 6, 100223. doi: 10.1016/j.cscee.2022.100223; b. J. He, Q. Xu, Q. Li, R. Marzouki and W. Li, Insight into the corrosion inhibition property of Artocarpus heterophyllus Lam leaves extract, J. Ind. Eng. Chem., 2021, 102, 260–270. doi: 10.1016/j.jiec.2021.07.007M.F.A.de Alencar, R. da S.G. Alves, J.L. Cardoso and M.J.S. Maura, Evaluation of Sapindus saponaria L extract as an acid medium corrosion inhibitor, Materia, 2022, 27. doi: 10.1590/S1517-707620220002.1378M.F.A.de Alencar, R. da S.G. Alves, J.L. Cardoso and M.J.S. Maura, Evaluation of Sapindus saponaria L extract as an acid medium corrosion inhibitor, Materia, 2022, 27. doi: 10.1590/S1517-707620220002.1378B.A. Al Jahdaly, Rosmarinus officinalis extract as eco- friendly corrosion inhibitor for copper in 1 M nitric acid solution: Experimental and theoretical studies, Arabian J. Chem., 2023, 16, 104411. doi: 10.1016/j.arabjc.2022.104411B.A. Al Jahdaly, Rosmarinus officinalis extract as eco- friendly corrosion inhibitor for copper in 1 M nitric acid solution: Experimental and theoretical studies, Arabian J. Chem., 2023, 16, 104411. doi: 10.1016/j.arabjc.2022.104411N.S.M. Ramadan and Z.W. Ahmed, Effect of garlic extract as corrosion inhibitor for copper in acidic medium, Eurasian Chem. Commun., 2023, 5, 28–36. doi: 10.22034/ecc.2023.348732.1493N.S.M. Ramadan and Z.W. Ahmed, Effect of garlic extract as corrosion inhibitor for copper in acidic medium, Eurasian Chem. Commun., 2023, 5, 28–36. doi: 10.22034/ecc.2023.348732.1493A. El-Asri, M.M. Rguiti, A. Jmiai, R. Oukhrib, H. Bourzi, Y. Lin and S. El Issami, Carissa macrocarpa extract (ECM) as a new efficient and ecologically friendly corrosion inhibitor for copper in nitric acid: Experimental and theoretical approach, J. Taiwan Inst. Chem. Eng., 2023, 142, 104633.A. El-Asri, M.M. Rguiti, A. Jmiai, R. Oukhrib, H. Bourzi, Y. Lin and S. El Issami, Carissa macrocarpa extract (ECM) as a new efficient and ecologically friendly corrosion inhibitor for copper in nitric acid: Experimental and theoretical approach, J. Taiwan Inst. Chem. Eng., 2023, 142, 104633.

The authors declare that there are no conflicts of interest present.