cpomaemКоррозия: защита материалов и методы исследованийTitle in englishИФХЭ РАН10.61852/2949-3412-2024-2-3-82-94cpomaem-67Research ArticleСтатьиПовышение коррозионной стойкости оксидно-керамических композитов методом циклической анодной поляризацииEnhancing the corrosion resistance of oxide-ceramic composites by the cyclic anodic polarization techniqueРешетниковС. М.ReshetnikovS. M.

ул. Университетская, 1, Ижевск, 426034

ул. Т. Барамзиной, 34, Ижевск, 426067

Universitetskaya str., 1, 426034 Izhevsk

Barmazina str., 34, 426067 Izhevsk

ТюкаловА. В.TyukalovA. V.

ул. Университетская, 1, Ижевск, 426034

Universitetskaya str., 1, 426034 Izhevsk

teentyk@mail.ruГильмутдиновФ. З.Gil’mutdinovF. Z.

ул. Т. Барамзиной, 34, Ижевск, 426067

Barmazina str., 34, 426067 Izhevsk

ХаранжевскийЕ. В.KharanzhevskiiE. V.

ул. Университетская, 1, Ижевск, 426034

Universitetskaya str., 1, 426034 Izhevsk

ГазизяноваА. Р.GazizyanovaA. R.

ул. Университетская, 1, Ижевск, 426034

Universitetskaya str., 1, 426034 Izhevsk

ШиробоковаА. С.ShirobokovaA. S.

ул. Университетская, 1, Ижевск, 426034

Universitetskaya str., 1, 426034 Izhevsk

ЧукавинА. И.ChukavinA. I.

ул. Т. Барамзиной, 34, Ижевск, 426067

Barmazina str., 34, 426067 Izhevsk

ФГБОУ ВО «Удмуртский государственный университет»; Удмуртский федеральный исследовательский центр Уральского отделения РАНРоссияUdmurt State University; Udmurt Federal Research Center, Ural Branch, Russian Academy of SciencesRussian FederationФГБОУ ВО «Удмуртский государственный университет»РоссияUdmurt State UniversityRussian FederationУдмуртский федеральный исследовательский центр Уральского отделения РАНРоссияUdmurt Federal Research Center, Ural Branch, Russian Academy of SciencesRussian Federation202417092024038294Copyright © Решетников С.М., Тюкалов А.В., Гильмутдинов Ф.З., Харанжевский Е.В., Газизянова А.Р., Широбокова А.С., Чукавин А.И., 20242024Решетников С.М., Тюкалов А.В., Гильмутдинов Ф.З., Харанжевский Е.В., Газизянова А.Р., Широбокова А.С., Чукавин А.И.Reshetnikov S.M., Tyukalov A.V., Gil’mutdinov F.Z., Kharanzhevskii E.V., Gazizyanova A.R., Shirobokova A.S., Chukavin A.I.This work is licensed under a Creative Commons Attribution 4.0 License.https://www.cpmrm.ru/jour/article/view/67

Исследовано влияние циклической электрохимической поляризации на коррозионные свойства оксидно-керамических покрытий, состоящих из оксидов переходных металлов, карбида и нитрида бора. Покрытия наносили методом лазерного сплавления порошковых смесей на поверхности низкоуглеродистой нелегированной стали с помощью оптоволоконного лазера. Полученные покрытия обладают улучшенными триботехническими свойствами. Исследованы состав, состояние поверхности и устойчивость образцов к электрохимической коррозии. Вольтамперные кривые были сняты в нейтральном буферном растворе. Показано, что нитрид бора в составе покрытий приводит к депассивации поверхности стали. Установлена принципиальная возможность повышения коррозионной стойкости образцов с покрытием B4C-BN-Bi2O3-MnO2 путем циклической поляризации.

The effect of cyclic electrochemical polarization on the corrosion properties of oxide-ceramic coatings consisting of transition metal oxides, boron carbide, and boron nitride was studied. The coatings were applied by laser melting of powder mixtures on the surface of low-carbon unalloyed steel using a fiber-optic laser. The resulting coatings feature enhanced tribological properties. The composition, surface condition, and resistance of samples to electrochemical corrosion were studied. Voltammetric curves were recorded in a neutral buffer solution. It was shown that the presence of boron nitride in the coating composition leads to depassivation of the steel surface. The conceptual possibility of enhancing the corrosion resistance of samples coated with B4C-BN-Bi2O3-MnO2 by cyclic polarization was shown.

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The authors declare that there are no conflicts of interest present.