cpomaemКоррозия: защита материалов и методы исследованийTitle in englishИФХЭ РАН10.61852/2949-3412-2024-3-1-1-60cpomaem-86Research ArticleСтатьиАнтикоррозионная эффективность супергидрофобных покрытий на металлах. Обзор.Anti-corrosion effectiveness of superhydrophobic coatings on metals. OverviewЦыганковаЛ. Е.TsygankovaL. E.

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Тамбовский государственный университет им. Г.Р. ДержавинаРоссияDerzhavin State UniversityRussian FederationВсероссийский научно-исследовательский институт по использованию техники и нефтепродуктов ; Angara GmbHРоссияAll-Russian Scientific Research Institute for the Use of Machinery and Oil Products in Agriculture ; Angara GmbHRussian Federation20251404202501160Copyright © Цыганкова Л.Е., Вигдорович М.В., 20252025Цыганкова Л.Е., Вигдорович М.В.Tsygankova L.E., Vigdorowitsch M.V.This work is licensed under a Creative Commons Attribution 4.0 License.https://www.cpmrm.ru/jour/article/view/86

В последние два десятилетия создание гидрофобных и супергидрофобных покрытий на металлах и практическое применение этих покрытий для самоочистки, защиты от обледенения, разделения масляно-водяной смеси и особенно для защиты от коррозии интенсивно обсуждались в исследовательском сообществе. В этом обзоре рассматриваются металлы и их соответствующая защита от коррозии в различных условиях (в воде, в хлоридных растворах, в атмосфере с агрессивными компонентами) с помощью супергидрофобных материалов и методов их изготовления. Рассматриваются как технологически более совершенные методы, основанные на лазерном текстурировании поверхности металла или плазменном травлении для создания многомодальной шероховатости с последующим нанесением слоя вещества с низкой поверхностной энергией, в первую очередь, фтороксисиланов, так и более простые, обычно экологически чистые и менее затратные подходы, основанные на химическом травлении поверхности металла, химическом или электрохимическом осаждении металлов одинаковой или разной природы с последующей обработкой гидрофобизирующими агентами, такими, как миристиновая или стеариновая кислоты. Исследования антикоррозионных свойств покрытий проводились преимущественно методами электрохимической поляризации и электрохимической импедансной спектроскопии, а в редких случаях – прямыми коррозионными испытаниями. В настоящем обзоре основное внимание уделено защите железа, сталей, меди, цинка, алюминия и магния.

In the last two decades, fabrication of hydrophobic and superhydrophobic coatings on metals and practical application of those for self-cleaning, anti-icing, oil-water separation and especially anti-corrosion purposes has been intensively discussed in the research community. This review addresses metals and their relevant protection against corrosion under various conditions (in water, in chloride solutions, in atmosphere with aggressive components) through superhydrophobic materials and methods of fabrication of these. Under consideration are both technologically more advanced methods based on laser texturing of a metal surface or plasma etching to create multimodal roughness, followed by deposition of a layer of substance with low surface energy, primarily fluoroxysilanes, and also simpler, ordinarily environmentally friendly and less expensive approaches based on chemical etching of the metal surface, chemical or electrochemical deposition of metals of the same or different nature, followed by treatment with hydrophobising agents such as myristic or stearic acids. Studies of anti-corrosion properties of coatings were carried out predominantly by methods of electrochemical polarisation and electrochemical impedance spectroscopy and, in rare cases, by direct corrosion tests. This review mainly focuses on protection of iron, steels, copper, zinc, aluminium and magnesium.

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The authors declare that there are no conflicts of interest present.