cpomaemКоррозия: защита материалов и методы исследованийTitle in englishИФХЭ РАН10.61852/2949-3412-2025-3-1-137-163cpomaem-93Research ArticleСтатьиВлияние имидазолатного каркаса ZIF-8 на ингибирующий эффект аспартатов при атмосферной коррозии низкоуглеродистой сталиInfluence of ZIF-8 on the inhibition effect of aspartates for atmospheric corrosion of mild steelЯнХайниYangH.

Шанхай 201306 

МаЛянMaL.

Шанхай 201306 

ЧжанДацюаньZhangD.

Шанхай 201306 

АньСифэйAnS.

Шанхай 201306 

ЦуйЧжэньиCuiZ.

Шанхай 201306 

АндреевН. Н.AndreevN. N.

19071, Москва, Ленинский проспект, д.31, корп. 4 

n.andreev@mail.ruШанхайский университет электроэнергетикиКитайФГБУН Институт физической химии и электрохимии им. А.Н. Фрумкина Российской академии наук (ИФХЭ РАН)Россия20251404202501137163Copyright © Ян Х., Ма Л., Чжан Д., Ань С., Цуй Ч., Андреев Н.Н., 20252025Ян Х., Ма Л., Чжан Д., Ань С., Цуй Ч., Андреев Н.Н.Yang H., Ma L., Zhang D., An S., Cui Z., Andreev N.N.This work is licensed under a Creative Commons Attribution 4.0 License.https://www.cpmrm.ru/jour/article/view/93

Цель данного исследования – разработка нового нанокомпозитного летучего ингибитора коррозии (ZIF-AD) низкоуглеродистой стали за счет реакции между аспарагиновой кислотой и ди-н-бутиламином (AD) на цеолитном имидазолатном каркасе (zeolitic imidazolate framework-8, ZIF-8). Пористая структура ZIF-8 способствует распределению молекул аспарагиновой кислоты, уменьшая их агломерацию и повышая летучесть. Ингибирующее действие ZIF-AD в условиях окружающей среды достигается благодаря летучести этого соединения и его способности к адсорбции. Показано, что при использовании ингибитора на поверхности стали образуется защитная пленка, эффективно подавляющая катодную реакцию. Полученные результаты показывают, что ZIF-AD может потенциально использоваться в качестве высокоэффективного ингибитора коррозии низкоуглеродистой стали в атмосферных условиях.

This study aims to develop a novel volatile corrosion inhibitor for mild steel by preparing a nanocomposite (ZIF-AD) through a salt-forming reaction between aspartic acid (AD) and din-butylamine, with zeolitic imidazolate framework-8 (ZIF-8) as the template material. The ZIF-8's porous structure is beneficial to disperse AD molecules, reducing agglomeration and enhancing volatility. Under ambient atmosphere, ZIF-AD achieves corrosion inhibition properties through volatilization and adsorption. It demonstrates that a protective film is formed on mild steel surfaces, effectively inhibiting the cathodic process of corrosion. Compared to AD alone, the incorporation of ZIF-8 increased the inhibition efficiency to 91%. These findings highlight the potential of ZIF-AD as a highly efficient corrosion inhibitor for mild steel in atmospheric environments.

летучий ингибитор коррозиинизкоуглеродистая стальатмосферная коррозияаспарагиновая кислотаZIF-8volatile corrosion inhibitormild steelatmospheric corrosionaspartic acidZIF-8electrochemical mechanismРабота выполнена при поддержке Национального фонда естественных наук Китая (52071198) и Открытого фонда Шанхайской ведущей лаборатории защиты материалов и современных материалов в электроэнергетике, а также Министерства образования и науки РФ.ReferencesE. Vuorinen, P. Ngobeni, G.H. Van der Klashorst, W. Skinner, E. de Wet and W.S. Ernst, Derivatives of cyclobexylamine and morpholine as volatile corrosion inbibitors, Br. Corros. J., 1994; 29, no 2, 120–121. doi: 10.1179/000705994798267845E. Vuorinen, P. Ngobeni, G.H. Van der Klashorst, W. Skinner, E. de Wet and W.S. Ernst, Derivatives of cyclobexylamine and morpholine as volatile corrosion inbibitors, Br. Corros. J., 1994; 29, no 2, 120–121. doi: 10.1179/000705994798267845D.M. Bastidas, E. Cano and E.M. 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The authors declare that there are no conflicts of interest present.