Protection of metals from corrosion in the vapor phase. Overview. Part 1. Volatile corrosion inhibitors
Abstract
Protection of metals in neutral environments with pH 5–9 (in humid atmospheres and various aqueous solutions) can be achieved by forming thin coatings (up to several tens of nm) on their surfaces due to adsorption and more complex chemical interaction of organic corrosion inhibitors with the protected metal. This brief review discusses the features of the formation and protection of metals in the vapor-gas phase, i.e. volatile corrosion inhibitors (VCI) mainly on iron and carbon steels, copper and zinc. The important role of VCI chemisorption and, as a consequence, the possibility of its relatively long protective aftereffect under harsh conditions of high air humidity and periodic moisture condensation on the surface of metals is shown. A method has been demonstrated for increasing the efficiency of metal protection through the combined use of VCI and volatile silanes, including their layer-by-layer adsorption on the protected metal. The ability of silanes to undergo chemical transformations when interacting with water vapor turned out to be useful for the purposeful creation of protective nanoscale coatings on metals from the vapor-gas phase on metal surfaces with delayed VCI desorption, i.e., a relatively long protective aftereffect
About the Authors
Yu. I. Kuznetsov
A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Russian Federation
Russian Federation
Sciences, Leninsky pr. 31, 119071 Moscow
N. N. Andreev
A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Russian Federation
Russian Federation
Sciences, Leninsky pr. 31, 119071 Moscow
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Kuznetsov Yu.I., Andreev N.N. Protection of metals from corrosion in the vapor phase. Overview. Part 1. Volatile corrosion inhibitors. Title in english. 2023;(2):1-15. (In Russ.)
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