Field tests of the efficiency of a chamber inhibitor in the protection of metals in the tropics
Abstract
The results of field tests of the effectiveness of a mixed chamber inhibitor (a mixture of octadecylamine and benzotriazole) for the protection of metals in the tropics are presented. It is shown that the chamber treatment of metals with this mixture with the packaging of processed samples in plastic bags:
– provides full protection of copper, brass and galvanized steel in humid, marine and coastal tropical climates for up to 9 months;
– provides full protection of steel in humid and coastal tropical climates for up to 9 months and in marine tropical climates for up to 3 months.
About the Authors
A. Yu. LuchkinRussian Federation
Leninsky pr. 31/4, 119071 Moscow
O. A. Goncharova
Russian Federation
Leninsky pr. 31/4, 119071 Moscow
T. T. Trang
Viet Nam
63 Nguyen Van Huyen, Nghia Do, Cau Giay, Hanoi
S. G. Gubin
Russian Federation
Leninsky pr. 33, 119071 Moscow
S. V. Bel’skii
Russian Federation
Leninsky pr. 31/4, 119071 Moscow
N. N. Andreev
Russian Federation
Leninsky pr. 33, 119071 Moscow
V. A. Karpov
Russian Federation
Leninsky pr. 33, 119071 Moscow
References
1. ГОСТ 9.014-78 ЕСЗКС. Временная противокоррозионная защита. Общие требования.
2. А.А. Михайлов, Ю.М. Панченко и Ю.И. Кузнецов, Атмосферная коррозия и защита металлов. – Тамбов: изд-во Першина, 2016, 555 с.
3. E. Vuorinen, E. Kálmán and W. Focke, Introduction to Vapour Phase Corrosion Inhibitors in Metal Packaging, Surf. Eng., 2004, 20(4), 281–284. doi: 10.1179/026708404225016481
4. Zhenyu Chen, Ling Huang, Guoan Zhang, Yubing Qiu and Xingpeng Guo, Benzotriazole as a volatile corrosion inhibitor during the early stage of copper corrosion under adsorbed thin electrolyte layers, Corros. Sci., 2012, 65, 214–222. doi: 10.1016/j.corsci.2012.08.019
5. S. Zehra, M. Mobin and R. Aslam, 3–Corrosion inhibitors: an introduction, Fundamentals and Industrial Applications, 2022, 47–67. doi: 10.1016/B978-0-323- 85405-4.00022-7
6. A.H. Al-Moubaraki and I.B. Obot, Top of the line corrosion: causes, mechanisms, and mitigation using corrosion inhibitors, Arabian J. Chem., 2021, 14, 103–116. doi: 10.1016/j.arabjc.2021.103116
7. Y. Amani, A. Mohammady and H. Rauofi, Volatile Corrosion Inhibitors Polymer Films, Polymerization, 2018, 8(2), 29–39. doi: 10.22063/BASPARESH.2018.2003.1376
8. N.N. Andreev and Yu.I. Kuznetsov, Volatile Inhibitors of Metal Corrosion. 1. Vaporization, Int. J. Corros. Scale Inhib., 2012, 1, 16–25. doi: 10.17675/2305-6894-2012-1-1-016-025
9. N.N. Andreev and Yu.I. Kuznetsov, Volatile inhibitors of metal corrosion. II. Interaction of systems being protected with the environment and corrosion prevention conditions, Int. J. Corros. Scale Inhib., 2012, 2, 146–153. doi: 10.17675/2305-6894-2012-1-2-146-153
10. N.N. Andreev and Yu.I. Kuznetsov, Volatile Inhibitors of Metal Corrosion. III Principles and methods of efficiency estimation, Int. J. Corros. Scale Inhib., 2013, 1, 39–52. Doi: 10.17675/2305-6894-2013-2-1-039-052
11. S. Gangopadhyay and P.A. Mahanwar, Recent developments in the volatile corrosion inhibitor (VCI) coatings for metal: a review, J. Coat. Technol. Res., 2018, 15, 789– 807. doi: 10.1007/s11998-017-0015-6
12. B. Valdez, M. Schorr, N. Cheng, E. Beltran and R. Salinas, Technological applications of volatile corrosion inhibitors, Corros. Rev., 2018, 36(3), 227–238. doi: 10.1515/corrrev-2017-0102
13. V.I. Vigdorovich, L.E. Tsygankova and L.G. Knyazeva, Universality of Volatile Corrosion Inhibitors in Terms of Agricultural Production Requirements, Russ. Agricult. Sci., 2019, 45, 307–311. doi: 10.3103/S1068367419030182
14. Y.I. Kuznetsov, N.N. Andreev and A.I. Marshakov, Physicochemical Aspects of Metal Corrosion Inhibition, Russ. J. Phys. Chem., 2020, 94, 505–515. doi: 10.1134/S0036024420030152
15. N. Cheng and B. Valdez Salas, Optimization and characterisation of commercial waterbased volatile corrosion inhibitor, Int. J. Corros. Scale Inhib., 2019, 8(2), 366–386. doi: 10.17675/2305-6894-2019-8-2-16
16. J. Brekan, K. Lanzo and T. Kovacs-Taborda, Volatile Corrosion Inhibitor (VCI) Testing – Pitfalls and Surprises in Routine Test Methods, CORROSION 2021, Virtual, April 2021.
17. Z. Belarbi, B. George, N. Moradighadi, D. Young, S. Nesic, M. Singer and R.P. Nogueira, Volatile Corrosion Inhibitor for Prevention of Black Powder in Sales Gas Pipelines, CORROSION 2018, Phoenix, Arizona, USA, April 2018.
18. O. Seckin and Na Qi, Processing Temperatures & Mass Loss of Vapor Corrosion Inhibitors, CORROSION 2021, Virtual, April 2021.
19. O.A. Goncharova, N.N. Andreev, A.Yu. Luchkin, Yu.I. Kuznetsov, N.P. Andreeva and S.S. Vesely, Protection of copper by treatment with hot vapours of octadecylamine, 1,2,3-benzotriazole and their mixtures, Mater. Corros., 2019, 70, 161–168. doi: 10.1002/maco.201810366
20. A.Y. Luchkin, O.A. Goncharova, I.A. Arkhipushkin, N.N. Andreev and Y.I. Kuznetsov, The effect of oxide and adsorption layers formed in 5- chlorobenzotriazole vapors on the corrosion resistance of copper, J. Taiwan Inst. Chem. Eng., 2020, 117, 231–241. doi: 10.1016/j.jtice.2020.12.005
21. O.A. Goncharova, A.Yu. Luchkin, Yu.I. Kuznetsov, N.N. Andreev, N.P. Andreeva and S.S. Vesely, Octadecylamine, 1,2,3-benzotriazole and a mixture thereof as chamber inhibitors of steel corrosion, Int. J. Corros. Scale Inhib., 2018, 2, 203–212. 10.17675/2305-6894-2018-7-2-7
22. O.A. Goncharova, Yu.I. Kuznetsov, N.N. Andreev, A.Yu. Luchkin, N.P. Andreeva and D.S. Kuznetsov, A new corrosion inhibitor for zinc chamber treatment, Int. J. Corros. Scale Inhib., 2018, 7, 340–350. doi: 10.17675/2305-6894-2018-7-3-5
23. A.Y. Luchkin, O.A. Goncharova, N.P. Andreeva, V.E. Kasatkin, S.S. Vesely, Y.I. Kuznetsov and N.N. Andreev, Mutual Effects of Components of Protective Films Applied on Steel in Octadecylamine and 1,2,3-Benzotriazole Vapors, Materials, 2021, 14, 7181. doi: 10.3390/ma14237181
24. O.A. Goncharova, A.Y. Luchkin, N.P. Andreeva, V.E. Kasatkin, S.S. Vesely, N.N. Andreev and Y.I. Kuznetsov, Mutual Effect of Components of Protective Films Applied on Copper and Brass from Octadecylamine and 1,2,3-Benzotriazole Vapors, Materials, 2022, 15, 1541. doi: 10.3390/ma15041541
25. H.-L. Zhang, D.-Q. Zhang, L.-X. Gao, Y.-Y. Liu, H.-B. Yan, S.-L. Wei and T.-F. Ma, Vapor phase assembly of benzotriazole and octadecylamine complex films on aluminum alloy surface, J. Coat. Technol. Res., 2021, 18, 435–446. doi: 10.1007/s11998-020-00405-5
Review
For citations:
Luchkin A.Yu., Goncharova O.A., Trang T.T., Gubin S.G., Bel’skii S.V., Andreev N.N., Karpov V.A. Field tests of the efficiency of a chamber inhibitor in the protection of metals in the tropics. Title in english. 2023;(2):16-29. (In Russ.)