Monitoring of Ellipsometric Parameters for Studying Adsorption of Organic Compounds on Metal Surfaces from Aqueous Solutions
https://doi.org/10.61852/2949-3412-2025-3-4-1-16
Abstract
The article presents an analysis of the application of the ellipsometric method for studying the adsorption of organic compounds on metal surfaces in aqueous neutral solutions. The interaction of both individual compounds and their substituted compounds on the surface of copper, zinc and iron from a neutral borate buffer pH 7.4 is considered. The dependence of the free energy of adsorption on the physicochemical characteristics of a number of compounds is revealed.
About the Authors
N. P. AndreevaRussian Federation
Leninsky prospect, 31-4, 119071, Moscow
M. O. Agafonkina
Russian Federation
Leninsky prospect, 31-4, 119071, Moscow
References
1. A.G. Akimov, I.L. Rozenfel'd, Optical Methods in Corrosion-electrochemical Studies, Russ. Chem. Rev., 1974, 43 (4), 251–262. doi: 10.1070/RC1974v043n04ABEH001804
2. В.И. Пшеницын, М.И. Абаев и Н.Ю. Лызлов, Эллипсометрия в физикохимических исследованиях, Ленинград: Химия. Ленинградское отделение, 1986, 152 с.
3. А.В. Ржанов, К.К. Свиташев, А.И. Семененко, Л.В. Семененко и В.К. Соколов, Основы эллипсометрии, Новосибирск: Наука, 1078, 424 с.
4. McCrackin, A Fortran Program for Analysis of Ellipsometer Measurement, Natl. Bur. Std., Technical Note 479, Washington, 1969.
5. F.L. McCrackin, E. Passaglia, R.R. Stromberg and H. Steinberg, Measurement of the Thickness and Refractive Index of Very Thin Films and the Optical Properties of Surfaces by Ellipsometry, J. Res. Natl. Bur. Std.–A. Physics and Chemistry, 1963, 67A, no. 4, 363–377. doi: 10.6028/jres.067A.040
6. N.P. Andreeva, Yu.I. Kuznetsov and Kh.S. Shikhaliev, The use of ellipsometry for studying adsorption of organic corrosion inhibitors from aqueous solutions on metals. Review. Part 1. Methods for obtaining adsorption isotherms, Int. J. Corros. Scale Inhib., 2022, 11, no. 4, 1716–1733. doi: 10.17675/2305-6894-2022-11-4-20
7. N.P. Andreeva, Yu.I. Kuznetsov and Kh.S. Shikhaliev, The use of ellipsometry for studying the adsorption of organic corrosion inhibitors from aqueous solutions on metals. Review. Part 2. Adsorption of salts of organic acids and azoles, Int. J. Corros. Scale Inhib., 2023, 12, no. 2, 560–585. doi: 10.17675/2305-6894-2023-12-2-10
8. Yu.I. Kuznetsov, Organic Inhibitors of Corrosion of Metals, New York and London: Plenum Press, 1996, 283 р.
9. Н.П. Андреева и Ю.И. Кузнецов, Эллипсометрическое изучение адсорбции фенилантранилат-аниона на железе, Защита металлов, 1989, 25, № 2, 214.
10. M.O. Agafonkina, N.P. Andreeva, Yu.I. Kuznetsov and S.F. Timashev, Substituted Benzotriazoles as Inhibitors of Copper Corrosion in Buffer Borate, Russ. J. Phys. Chem. A, 2017, 91, no 8, 1410–1417. doi:10.1134/S0036024417080027
11. I.A. Kuznetsov, A.A. Chirkunov, Yu.I. Kuznetsov, Kh.S. Shikhaliev, M.O. Agafonkina, N.P. Andreeva and Yu.A. Kovygin, Protection of copper against corrosion in neutral solutions by salts of 2-alkylmalonic acids, Int. J. Corros. Scale Inhib., 2022, 11, no. 3, 1401–1417. doi: 10.17675/2305-6894-2022-11-3-29
12. M.O. Agafonkina, Yu.I. Kuznetsov, N.P. Andreeva, Kh.S. Shikhaliev and Yu.A. Kovygin, Adsorption and protective properties of alkylmalonic acids’ derivatives on zinc in a neutral chloride solution, Int. J. Corros. Scale Inhib., 2024, 13, no. 4, 2438–2453. doi: 10.17675/2305-6894-2024-13-4-30
13. M.V. Vinnichenko, M.T. Pham, T. Chevolleau, L.V Poperenko, M.F. Maitz, In situ ellipsometric investigation of stainless steel corrosion behavior in buffered solutions with amino acids, Appl. Surf. Sci., 2003, 207, 176–182.
14. B.A. Noskov, A.V. Akentiev, D.O. Grigoriev, G. Loglio and R. Miller, Ellipsometric study of nonionic polymer solutions, J. Colloid Interface Sci., 2005, 282, 38–45. doi: 10.1016/j.jcis.2004.08.068
15. Q.R. Huang, C.H. Wang, Surface laser light scattering studies of the air/poly(N vinyl 2 pyrrolidone) water solution interface, J. Chem. Phys., 1996, 105, 6546–6552. doi: 10.1063/1.472463
16. B.A. Noskov, A.V. Akentiev, A.Yu. Bilibin, D.O. Grigoriev, G. Loglio, I.M. Zorin and R. Miller, Adsorption kinetics of non-ionic polymers: an ellipsometric study, Mendeleev Commun., 2005, 15, 198–200.doi: 10.1070/MC2005v015n05ABEH002040
17. B.A. Noskov, A.V. Akentiev, D.O. Grigoriev, G. Loglio and R. Miller, Ellipsometric study of nonionic polymer solutions, J. Colloid Interface Sci., 2005, 282, no. 1, 38–45. doi: 10.1016/j.jcis.2004.08.068
18. I.P. Purcell, R.K. Thomas, J. Penfold and A.M. Howe, Adsorption of SDS and PVP at the air/water interface, Colloids Surf., A, 1995, 94, 125–130. doi: 10.1016/09277757(94)02980-6
19. M. Harke, R. Teppner, O. Schulz, H. Orendi and H. Motschmann, Description of a single modular optical setup for ellipsometry, surface plasmons, waveguide modes, and their corresponding imaging techniques including Brewster angle microscopy, Rev. Sci. Instr., 1997, 68, 3130–3134. doi: 10.1063/1.1148256
20. J.A. De Feijter, J. Benjamins and F.A. Veer, Ellipsometry as a tool to study the adsorption behaviour of synthetic and biopolymers at the air-water interface, Biopolymers, 1978, 17, 1759–1772. doi: 10.1002/bip.1978.360170711
21. D.E. Graham and M.C. Phillips, Proteins at liquid interfaces: III. Molecular structures of adsorbed films, J. Colloid Interface Sci., 1979, 70, 427–439. doi: 10.1016/00219797(79)90050-x
Review
For citations:
Andreeva N.P., Agafonkina M.O. Monitoring of Ellipsometric Parameters for Studying Adsorption of Organic Compounds on Metal Surfaces from Aqueous Solutions. Title in english. 2025;(4):1-16. (In Russ.) https://doi.org/10.61852/2949-3412-2025-3-4-1-16