Adsorption and passivation of copper by substituted triazoles in neutral solutions
https://doi.org/10.61852/2949-3412-2025-3-4-80-93
Abstract
The adsorption and passivation effects of substituted 3-amino-1,2,4-triazoles (3-R-3-AT) containing electron-donating or electron-withdrawing substituents on copper were studied in neutral solutions. Compounds with electron-withdrawing substituents R=C6H5- and C3H7SO2- exhibit higher adsorption capacity than similar compounds with electron-donating R. The adsorption isotherms of C6H5-3-AT and 5-C3H7SO2-3-AT on the oxidized copper surface in a borate buffer solution at a constant potential of E=0.0 V are described by the complete Temkin equation with free energies of adsorption 93 and 96 kJ/mol, respectively. The minimum concentration that suppresses the first active dissolution peak on copper is lower for substituted 3-R-3-AT than for 3-AT itself.
About the Authors
M. O. Agafonkina
Frumkin Institute of Physical Chemistry and Electrochemistry Russian Academy of Sciences
Russian Federation
Russian Federation
31-4, Leninsky prospect, 119071, Moscow
N. P. Andreeva
Frumkin Institute of Physical Chemistry and Electrochemistry Russian Academy of Sciences
Russian Federation
Russian Federation
31-4, Leninsky prospect, 119071, Moscow
References
1. I. Dugdale and J.B. Cotton, An electrochemical investigation on the prevention of staining of copper by benzotriazole, Corros. Sci., 1963, 2, 69–75. doi: 10.1016/s0010938x(63)80001-3
2. J.I. Bregman, Corrosion Inhibitors, 1963, New York, The MacMillan Company.
3. Ю.И. Кузнецов и Л.П. Подгорнова, Ингибирование коррозии металлов гетероциклическими хелатореагентами, Итоги науки и техники. Серия: Коррозия и защита от коррозии, 1989, М.: ВИНИТИ, 15, 132–184.
4. O. Hollander, Structure-activity relationships of triazole copper-corrosion inhibitors: Rational Development of enhanced activity inhibitors, In the book: Reviews on Corrosion Inhibitor Science and Technology. V. 2. Edited by A. Raman and P. Labine. 1993. Houston: NACE International. II-13-1 - XIII-12.
5. V. Brusic, Corrosion inhibitors in the electronic industry. In the book: Reviews on Corrosion Inhibitor Science and Technology. V. 2. Edited by A. Raman and P. Labine. 1996. Houston: NACE International. XIII-1 - XIII-12
6. Yu.I. Kuznetsov and L.P. Kazansky, Physicochemical aspects of metal protection by azoles as corrosion inhibitors, Russ. Chem. Rev., 2008, 77, 219–232. doi: 10.1070/RC2008V077N03ABEH003753
7. S.M. Milić and M.M. Antonijević, Some aspects of copper corrosion in presence of benzotriazole and chloride ions, Corros. Sci., 2009, 51, 28–34. doi: 10.1016/j.corsci.2008.10.007
8. H. Gerengi, K. Darowicki, G. Bereket and P. Slepski, Evaluation of corrosion inhibition of brass-118 in artificial seawater by benzotriazole using Dynamic EIS, Corros. Sci., 2009, 51, 2573–2579. doi: 10.1016/j.corsci.2009.06.040
9. M. Finšgar and I. Milošev, Inhibition of copper corrosion by 1,2,3-benzotriazole: a review, Corros. Sci., 2010, 52, 2737–2749. doi: 10.1016/j.corsci.2010.05.00
10. Zh. Chen, L. Huang, G. Zhang, Y. Qiu and X. Guo, Benzotriazole as a volatile corrosion inhibitor during the early stage of copper corrosion under adsorbed thin electrolyte layers, Corros. Sci., 2012, 65, 214–222. doi: 10.1016/J.CORSCI.2012.08.019
11. Yu.I. Kuznetsov, Тriazoles as a class of multifunctional corrosion inhibitors. A review. Part I. 1,2,3-benzotriazole, its derivatives. Copper, zinc and their alloys, Int. J. Corros. Scale Inhib., 2018, 7, no. 3, 271–307. doi: 10.17675/2305-6894-2018-7-3-1
12. L.B. Coelho, M. Mouanga, M.-E. Druart, I. Recloux, D. Cossement, M.-G. Olivier. A SVET study of the inhibitive effects of benzotriazole and cerium chloride solely and combined on an aluminium/copper galvanic coupling model, Corros. Sci., 2016, 110, 143–156. doi: 10.1016/j.corsci.2016.04.036
13. D. Gopi, K.M. Govindaraju, C. Prakash, D.M. Angeline Sakila and L. Kavitha, A study on new benzotriazole derivatives as inhibitors on copper corrosion in ground water, Corros. Sci., 2009, 51, 2259–2265. doi: 10.1016/j.corsci.2009.06.008
14. L.P. Kazansky, I.A. Selyanonov and Yu.I. Kuznetsov, Angle resolved XPS of monomolecular layer of 5-chlorobenzotriazole on oxidized metallic surface, Appl. Surf. Sci., 2012, 259, 385–392. doi: 10.1016/j.apsusc.2012.07.056
15. G. Trabanelli, A. Frignani, C. Monticelli and F. Zucchi, Alkyl-benzotriazole derivatives as inhibitors of iron and copper corrosion, Int. J. Corros. Scale Inhib., 2015, 4, no 1, 96–107. doi: 10.17675/2305-6894-2015-4-1-096-107
16. Z. Wang, Yu. Gong, C. Jing, H. Huang, H. Lia, S. Zhanga and F. Gao, Synthesis of dibenzotriazole derivatives bearing alkylene linkers ascorrosion inhibitors for copper in sodium chloride solution: A newthought for the design of organic inhibitors, Corros. Sci., 2016, 113, 64–77. doi: 10.1016/j.corsci.2016.10.005
17. M.O. Agafonkina, N.P. Andreeva, Yu.I. Kuznetsov and S.F. Timashev, Substituted Benzotriazoles as Inhibitors of Copper Corrosion in Borate Buffer Solutions, Russ. J. Phys. Chem. A, 2017, 91, no. 8, 1414–1421. doi: 10.1134/S0036024417080027
18. Yu.I. Kuznetsov, M.O. Agafonkina, N.P. Andreeva, I.A. Arkhipushkin and L.P. Кazanskii, Inhibiting the Corrosion of MNZh5-1 Alloy in Neutral Solutions of 5Chloro-1,2,3-Benzotrialzole, Russ. J. of Phys. Chem. A, 2017, 91, no 11, 2226–2233. doi: 10.1134/s0036024417110127
19. M. Оhsawa and W. Suetaka, Spectro-electrochemical studies of the corrosion inhibition of copper by mercaptobenzothiazole, Corros. Sci., 1979, 19, no 10, 709– 722. doi: 10.1002/chin.198003020
20. Yu.I. Kuznetsov, New possibilities of metal corrosion inhibition by organic heterocyclic compounds, Int. J. Corros. Scale Inhib., 2012, 1, no 1, 3–15. doi: 10.17675/2305-6894-2012-1-1-003-015
21. L.P. Kazansky, I.A. Selyaninov and Yu.I. Kuznetsov, Adsorption of 2- mercaptobenzothiazole on copper surface from phosphate solutions, Appl. Surf. Sci., 2012, 258, no 18, 6807–6813. doi: 10.1016/j.apsusc.2012.03.097
22. L.P. Kazansky, Yu.E. Pronin and I.A. Arkhipushkin, XPS study of adsorption of 2mercaptobenzothiazole on a brass surface, Corros. Sci., 2014, 89, 21–29. doi: 10.1016/j.corsci.2014.07.055
23. M. Finšgar, EQCM and XPS analysis of 1,2,4-triazole and 3-amino-1,2,4-triazole as copper corrosion inhibitors in chloride solution, Corros. Sci., 2013, 77, 350–359. doi: 10.1016/j.corsci.2013.08.026
24. Yu.I. Kuznetsov, M.O. Agafonkina, Kh.S. Shikhaliev, N.P. Andreeva and A.Yu. Potapov, Adsorption and passivation of copper by triazoles in neutral aqueous solution, Int. J. Corros. Scale Inhib., 2014, 3, no. 2, 137–148. doi: 10.17675/23056894-2014-3-2-137-148
25. G. Rajkumar and M.G. Sethuraman Corrosion protection ability of self-assembled monolayer of 3-amino-5-mercapto-1,2,4-triazole on copper electrode, Thin Solid Films, 2014, 562, 32–36. doi: 10.1016/j.tsf.2014.03.074
26. Yu.I. Kuznetsov, М.О. Agafonkina, N.P. Andreeva, Kh.S. Shikhaliev and А.Yu. Potapov, Adsorption and passivation properties of S-containing heterocyclic compounds on copper, Int. J. Corros. Scale Inhib., 2022, 11, no. 2, 796–811. doi: 10.17675/2305-6894-2022-11-2-23
27. Z. Khiati, A.A. Othman, M. Sanchez-Moreno, M.-C. Bernard, S. Joiret, E.M.M. Sutter and V. Vivier, Corrosion inhibition of copper in neutral chloride media by a novel derivative of 1,2,4-triazole, Corros. Sci., 2011, 53, no. 10, 3092–3099. doi: 10.1016/j.corsci.2011.05.042
28. Yu.I. Kuznetsov, Kh.S. Shikhaliev, M.O. Agafonkina, N.P. Andreeva, A.M. Semiletov, A.A. Chirkunov, A.Yu. Potapov and V.E. Solov’ev, Formation of passivating layers by 1,2,4-triazole derivatives on copper in aqueous solutions, Rus. J. Phys. Chem. A, 2017, 91, no 12, 2458–2465. doi: 10.1134/S0036024417120147
29. A.A. Chirkunov, Yu.I. Kuznetsov, Kh.S. Shikhaliev, M.O. Agafonkina, N.P. Andreeva, L.P. Kazansky and A.Yu. Potapov, Adsorption of 5-alkyl-3-amino-1,2,4-triazoles from aqueous solutions and protection of copper from atmospheric corrosion, Corros. Sci., 2018, 144, 230–236. doi: 10.1016/j.corsci.2018.08.056
30. W.W. Frenier, Review of Green Chemistry Corrosion Inhibitors for Aqueous Systems, Proceedings of 9th Europ. Symp. on Corros. Inhibitors, 2000, University of Ferrara (Italy), 1, 1–38
31. А.Н. Верещагин, Индуктивный эффект. Константы заместителей для корреляционного анализа, 1988, М.: Наука, 111 с. ISBN 5-02-001413-3
32. M.A. Ghaly, E. Elbendary, I. Shehata, E.-H. El-Sayed and S.M. Bayomi, Synthesis, Antimicrobial Activity, DNA-Binding Affiniti and Molekular Docking of Certain 1,2,4-Triasolo[1,5-a]Pyrimidines as Nalidix Acid Isoteres, J. Am. Sci., 2012, 8, no 10, 617–628.
33. C.A. Lipinski, J.L. LaMattina and L.A. Hohnke, Pseudosymmetry and bioisosterism in biaryl pyridyl competitive histamine H2-receptor antagonists, J. Med. Chem., 1985, 28, no 11, 1628–1636. doi: 10.1021/jm00161a005
34. K. Sasse, H. Niedrig, Kohlensaure-Derivaate von 3-Alkylthio-5-amino- und – Alkylsulfonyl-5-amino-1,2,4-triazolen, Angew. Chem., 1981, 93, no 7, 835–836. doi: 10.1002/ange.19810930946
35. С.М. Десенко и В.Д. Орлов, Азагетероциклы на основе непредельных ароматических кетонов, Харьков, Фолио, 1998, с. 121, 122. ISBN 966-03-0518-4.
Review
For citations:
Agafonkina M.O., Andreeva N.P. Adsorption and passivation of copper by substituted triazoles in neutral solutions. Title in english. 2025;(4):80-93. (In Russ.) https://doi.org/10.61852/2949-3412-2025-3-4-80-93
Views:
41
Email this article 