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Protection of Steel with an Electrodeposited Superhydrophobic Cu-Zn Coating in Hydrogen Sulfide-Containing Environments

https://doi.org/10.61852/2949-3412-2026-4-2-130-141

Abstract

A superhydrophobic coating (SHPC) on steel obtained by electrodepositing copper and zinc followed by treatment with an ethanol solution of myristic acid is characterized by a contact angle of 157 ±2°. Exposure of coated steel samples for 10 days in the gas and liquid phases of NACE and NaCl (50 g/L) solutions containing 400 mg/L H2S demonstrated a protective effect of over 90% in the gas phase and approximately 15% lower in the liquid phase. At the same time, the coating's superhydrophobicity was maintained. Using potentiodynamic polarization and impedance spectroscopy, it was shown that in a NACE+400 mg/L H2S environment, the coating slows down the anodic process on steel.

About the Authors

L. D. Rodionova
G.R. Derzhavin Tambov State University
Russian Federation

Tambov, 392000



L. E. Tsygankova
G.R. Derzhavin Tambov State University
Russian Federation

Tambov, 392000



A. A. Dyakov
G.R. Derzhavin Tambov State University
Russian Federation

Tambov, 392000



D. A. Gorlov
G.R. Derzhavin Tambov State University
Russian Federation

Tambov, 392000



I. A. Lomakina
G.R. Derzhavin Tambov State University
Russian Federation

Tambov, 392000



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Review

For citations:


Rodionova L.D., Tsygankova L.E., Dyakov A.A., Gorlov D.A., Lomakina I.A. Protection of Steel with an Electrodeposited Superhydrophobic Cu-Zn Coating in Hydrogen Sulfide-Containing Environments. Title in english. 2026;(2):130-141. (In Russ.) https://doi.org/10.61852/2949-3412-2026-4-2-130-141

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