Preview

Title in english

Advanced search

Сorrosion behavior of mild steel in ammonium sulfate environments depending on temperature

Abstract

In the present article the corrosion behavior of St3 mild steel in a liquid mineral fertilizer (LMF), namely in (NН4)24 at different concentrations (5, 10, 25, 40% and in a prototype liquid fertilizer LikviFors brand NS 8:9) and temperatures (20, 35, 50 and 65°C) was studied. The evaluation of the corrosiveness of the liquid metallurgy included the study of corrosion of steel in three areas: in the bulk of the liquid, in saturated vapors above the solution, and along the waterline. All investigated solutions of (NН4)24at 20°C are characterized by a decrease in the steel corrosion rate with time. Increasing the temperature of the LMC leads to an acceleration of corrosion of mild steel, especially along the waterline and in the vapor-gas phase.

About the Authors

G. E. G.E. Gornostaeva
A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Russian Federation

Leninskii pr. 31, 119071 Moscow



G. V. Redkina
A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Russian Federation

Leninskii pr. 31, 119071 Moscow



References

1. А.Х. Шеуджен, В.Т. Куркаев и Н.С. Котляров, Агрохимия: Учебное пособие, Под ред. А.Х. Шеуджена. 2-е изд., перераб. и доп., Майкоп, Афиша, 2006, 1075 с.

2. Б.А. Ягодин, Ю.П. Жуков и В.И. Кобзаренко, Агрохимия, М.: Колос, 2002, 584 с.

3. F. F. Mozheiko, T.N. Potkina and I.I. Goncharik, Effect of inhibitors on corrosion resistance of carbon steel in suspensed liquid combined fertilizer, Russ. J. Appl. Chem, 2008, 81(9), 1705–1709. doi: 10.1134/S1070427208090437

4. С.Д. Эвенчик и А.А. Бродский, Технология фосфорных и комплексных удобрений. М.: Химия, 1987, 464 с.

5. D. Ivanova, K. Kamburova, P. Kirilov and L. Fachikov, Mild steel corrosion resistance in liquid fertilizer solutions, J. Chem. Technol. Metall., 2010, 45, 53–58. url: https://journal.uctm.edu

6. L. Fachikov, D. Ionova and B. Tzaneva, Corrosion of low-carbon steels in aqueous solutions of ammonium sulfate mineral fertilizer, J. Chem. Technol. Metall., 2006, 41, 21–24. url: https://journal.uctm.edu

7. В.А. Милюткин и С.А. Толпекин, Жидкие азотные и азотосеросодержащие удобрения на базе КАС – эффективная альтернатива твердым минеральным удобрениям, Проблемы современной аграрной науки, 2020, 71–74.

8. В.С. Пахомов, Коррозия металлов и сплавов: Справочник: в 2 кн. Книга 2, М.: Наука и технология, 2013, 544 с.

9. Г.Я. Воробьева. Коррозионная стойкость материалов в агрессивных средах химических производств: Справочное пособие, М.: Химия. 1975. 816 с.

10. И.Я. Клинов, Коррозия химической аппаратуры и коррозионностойкие материалы: Учебное пособие. М.: Машгиз, 1960. 511 с.

11. P.V. Popovych and Z.B. Slobodyan, Corrosion and electrochemical behaviors of 20 steel and st. 3 steel in ammonium sulfate and nitrophoska. Mater. Sci., 2014, 49(6), 819–826. doi: 10.1007/s11003-014-9679-6

12. P. Popovych, O. Shevchuk, L. Poberezhna and M. Mazur, Performance of bearing steel structures of vehicle used in transportation of aggressive agricultural materials, J. Taibah Univ. Sci., 2019, 13(1), 563–569. doi: 10.1080/16583655.2019.1607811

13. G.E. Gornostaeva, G.V. Redkina and Yu.I. Kuznetsov, Corrosion of mild steel and protection against it in environments of a liquid mineral fertilizer–ammonium sulphate, Int. J. Corros. Scale Inhib., 2022, 11, 1802–1818. doi: 10.17675/2305- 6894-2022-11-4-25

14. А.Л. Коуль и Ф.С. Ризенфельд, Очистка газа, М.: Недра, 1968, 392 с. 15. Г.Е. Горностаева, Г.В. Редькина и Ю.И. Кузнецов, Ингибирование коррозии низкоуглеродистой стали в растворах сульфата аммония, Успехи химии в химии и химической технологии. Сб. науч. тр., М.: РХТУ им. Д. И. Менделеева, 2023, 37, 33–35.


Review

For citations:


G.E. Gornostaeva G.E., Redkina G.V. Сorrosion behavior of mild steel in ammonium sulfate environments depending on temperature. Title in english. 2023;(3):51-63. (In Russ.)

Views: 294


Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 License.