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Application of ellipsometry to study the adsorption of corrosion inhibitors on metals from aqueous solutions and vapor phase

Abstract

The article continues the analysis of the application of the ellipsometry method for the study metal corrosion inhibitors and considered joint, as well as induced adsorption of inhibitors and compositions based on them. Examples are given determination of the sizes of adsorbed monolayers, kinetics of their growth. Apart from already have become a common application of ellipsometry for the study of adsorption inhibitors from the aqueous phase, the application of this method for volatile corrosion inhibitors and chamber corrosion inhibitors.

About the Author

N. P. Andreeva
A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Russian Federation

Leninsky pr. 31, 119071 Moscow



References

1. Р. Аззам и Н. Башара, Эллипсометрия и поляризованный свет, М.: Мир, 1981, 583 с.

2. M. Born and E. Wolf, Principles of optics, Pergamon press, Oxford-London-Edinburgh- New York, Paris-Frankfurt, 1968, 720 р.

3. Г.С. Ландсберг, Оптика, М.: Наука, 1976, 927 с.

4. С.А. Ахманов и С.Ю. Никитин, Физическая оптика, М.: Издательство Московского Университета, 1998, 656 с.

5. В.А. Кизель, Отражение света, М.: Наука, 1973, 352 с.

6. М.М. Горшков, Эллипсометрия, М.: Советское радио, 1974, 200 с.

7. В.И. Пшеницын, М.И. Абаев, и Н.Ю. Лызлов, Эллипсометрия в физико- химических исследованиях, Ленинград: Химия. Ленинградское отд-ние, 1986, 152 с.

8. А.В. Ржанов, К.К. Свиташев, А.И. Семененко, Л.В. Семененко и В.К. Соколов, Основы эллипсометрии, Новосибирск: Наука, 1078, 424 с.

9. McCrackin, A Fortran Program for Analysis of Ellipsometer Measurement, Natl. Bur. Std., Technical Note 479, Washington, 1969.

10. F.L. McCrackin, E. Passaglia, R.R. Stromberg and H. Steinberg, Measurement of the Thickness and Refractive Index of Very Thin Films and the Optical Properties of Surfaces by Ellipsometry, J. Res. Natl. Bur. Std.–A. Physics and Chemistry, 1963, 67, 363–377. doi: 10.6028/jres.067A.040

11. А.В. Ржанова, Эллипсометрия: теория, методы, приложения, Новосибирск: Наука, Сибирское отд-ние, 1987, 192 с.

12. N.P. Andreeva, Yu.I. Kuznetsov and Kh.S. Shikhaliev, The use of ellipsometry for studying adsorption of organic corrosion inhibitors from aqueous solutions on metals. Review. Part 1. Methods for obtaining adsorption isotherms, Int. J. Corros. Scale Inhib., 2022, 11, 1716–1733. doi: 10.17675/2305-6894-2022-11-4-20

13. N.P. Andreeva, Yu.I. Kuznetsov and Kh.S. Shikhaliev, The use of ellipsometry for studying the adsorption of organic corrosion inhibitors from aqueous solutions on metals. Review. Part 2. Adsorption of salts of organic acids and azoles, Int. J. Corros. Scale Inhib., 2023, 12, 560–585. doi: 10.17675/2305-6894-2023-12-2-10

14. R.F.V. Villamil, G.G.O. Cordeiro, J. Matos, E. D’Elia and S.M.L. Agostinho, Effect of sodium dodecylsulfate and benzotriazole on the interfacial behavior of Cu/Cu(II), H2SO4, Mater. Chem. Phys., 78, 448–452. doi: 10.1016/S0254-0584(02)00347-4

15. Karpagavalli Ramji, D.R. Cairns and S. Rajeswari, Synergistic inhibition effect of 2- mercaptobenzothiazole and Tween-80 on the corrosion of brass in NaCl solution, Appl. Surf. Sci., 254, 4483–4493. doi: 10.1016/j.apsusc.2008.01.031

16. Da-Quan Zhang, Qi-RuiCai, Xian-Ming He, Li-Xin Gao and G.S. Kim, Corrosion inhibition and adsorption behavior of methionine on copper in HCl and synergistic effect of zinc ions, Mater. Chem. Phys., 114, 612–617. doi: 10.1016/j.matchemphys.2008.10

17. G. Mu, X. Li and G. Liu, Synergistic inhibition between tween 60 and NaCl on the corrosion of cold rolled steel in 0.5 M sulfuric acid, Corros Sci, 2005, 47, 1932–1952. doi: 10.1016/j.corsci.2004.09.020

18. I. Sekine and Y. Hirakawa, Effect of 1-Hydroxyethylidene-1, 1-Diphosphonic Acid on the Corrosion of SS 41 Steel in 0.3% Sodium Chloride Solution, Corrosion, 1986, 42, 272–277. doi: 10.5006/1.3584904

19. M. Hosseini and F.L. Stijn Mertens and Mohammed R. Arshadi, Synergism and antagonism in mild steel corrosion inhibition by sodium dodecylbenzenesulphonate and hexamethylenetetramine, Corros Sci, 45, 1473–1489. doi: 10.1016/S0010-938X(02)00246-9

20. Yu.I. Kuznetsov, N.P. Andreeva, N.P. Sokolova and R.A. Bulgakova, Joint adsorption of oleic and phenylanthranilic acids at passive iron, Prot. Met. Phys. Chem. Surf., 2003, 39, 462–467. doi: 10.1023/A:1025898803486

21. Yu.I. Kuznetsov, N.P. Andreeva, N.P. Sokolova and R.A. Bulgakova, Adsorption of the inhibiting anions on passive iron from an aqueous solution, Prot. Met. Phys. Chem. Surf., 2001, 37, 519–524. doi: 10.1023/A:1012851110325

22. Yu.I. Kuznetsov, Organic Inhibitors of Corrosion of Metals, Plenum Press: New York and London, 1996, 283 p.

23. C. Hansch and A. Leo, Substituent Constants for Correlation Analysis in Chemistry and Biology, Wiley-Interscience: New York. 1979, 339 pp.

24. L.P. Hammet, Physical Organic Chemistry, New York: McGraw–Hill Book Company G.T, 1970

25. Yu.I. Kuznetsov and N.P. Andreeva, The Designing of Nanometer–Sized Passive Films at Metal Surfaces Using Organic Inhibitors, Russ. J. Electrochem., 2012, 48, 442–449. doi: 10.1134/S102319351204009X

26. Yu.I. Kuznetsov, N.H. Andreeva, N.P. Sokolova and R.A. Bulgakova, Joint adsorption of oleic and phenylanthranilic acids at passive iron, Prot. Met. Phys. Chem. Surf., 2003, 39, 462–467. doi: 10.1023/A:1025898803486

27. Yu.I. Kuznetsov and N.P. Andreeva, On the coadsorption of mephenaminate and phenylundecanoate anions at passive iron, Prot. Met. Phys. Chem. Surf., 2005, 41, 531- 535. doi: 10.1007/s11124-005-0075-3

28. L.P. Kazansky, Yu.I. Kuznetsov, N.P. Andreeva and Y.G. Bober, Self-assembled monolayers of flufenaminate anions on mild steel surface formed in aqueous solution, Appl. Surf. Sci., 2010, 257, 1166-1174. doi: 10.1016/j.apsusc.2010.07.077

29. O.Yu. Grafov, L.P. Kazansky, S.V. Dubinskaya and Yu.I. Kuznetsov, Adsorption of depocolin and inhibition of copper dissolution in aqueous solutions, Int. J. Corros. Scale Inhib., 2019, 8, 549–559. doi: 10.1134/S2070205119070074

30. Yu.I. Kuznetsov, M.O. Agafonkina, N.P. Andreeva and L.P. Kazansky, Adsorption of dimegin and inhibition of copper dissolution in aqueous solutions, Сorros. Sci., 2015, 100, 535–543. doi: 10.1016/j.corsci.2015.08.028

31. O.Y. Grafov, M.O. Agafonkina, N.P. Andreeva, L.P. Kazansky and Yu.I. Kuznetsov, Adsorption of Depocolin and Dimegin on Nickel from Neutral Aqueous Solutions, Prot. Met. Phys. Chem. Surf., 2019, 55, 1304–1310. doi: 10.1134/S2070205119070074

32. Yu.I. Kuznetsov, Kh.S. Shikhaliev, M.O. Agafonkina, N.P. Andreeva, A.M. Semiletov, A.A. Chirkunov, A.Yu. Potapov and V.E. Solov’ev, Formation of Passivating Layers by 1,2,4-Triazole Derivatives on Copper in Aqueous Solutions, Russ. J. Phys. Chem., 2017, 91, 2458–2465. doi: 10.1134/S0036024417120147

33. S.Z. Roginsky and J. Zeldovich, The catalytic oxidation of carbon monoxide on manganese dioxid, Acta Physicochim, U.R.S.S, 1934, 1, 554–594.

34. G. Reinhard and U. Kunzelmann, Characterization of the interactions of vapour phase inhibitors on metal surfaces by ellipsometry, Werkst. Korros., 1987, 38, 110–114. doi: 10.1002/maco.19870380303

35. Ю.И. Кузнецов, А.В. Агафонкин и О.О. Зель, Летучие ингибиторы атмосферной коррозии металлов на основе азометинов, Коррозия: материалы, защита, 2009, 4, 17–23

36. Ю.И. Кузнецов, Н.Н. Андреев, О.А. Гончарова и А.В. Агафонкин, О защите металлов от коppозии пpи конденсации на них влаги летучими ингибитоpами, Коррозия: материалы, защита, 2009, 10, 29–33

37. A.V. Agafonkin, Yu.I. Kuznetsov and N.P. Andreeva, Formation of Protective Nano - Layers on Metals Formed by N-Benzylbenzylidenimine and (3-Aminopropyl) - Triethoxysilane from Gas–Vapor Phase, Prot. Met. Phys. Chem. Surf., 2011, 47, 866– 872. doi: 10.1134/S2070205111070021

38. A.Ю. Лучкин, O.A. Гончарова, Н.Н. Андреев и Ю.И. Кузнецов, Защита стали обработкой смесью паров октадециламином, 1,2,3-бензотриазолом и их смесью при повышенной температуре, Коррозия: материалы, защита, 2017, 12, 20–26.

39. O.A. Goncharova, N.N. Andreev, A.Y. Luchkin, Y.I. Kuznetsov, N.P. Andreeva, and S.S. Vesely, Protection of copper by treatment with hot vapors of octadecylamine, 1,2,3- benzotriazole, and their mixtures, Werkst. Korros., 2019, 70, 161–168. doi: 10.1002/maco.201810366


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Andreeva N.P. Application of ellipsometry to study the adsorption of corrosion inhibitors on metals from aqueous solutions and vapor phase. Title in english. 2023;(3):88-101. (In Russ.)

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