Protection of copper and MNZh5-1 alloy from corrosion by succency and alkenylsuction acids salts in chloride solution
https://doi.org/10.61852/2949-3412-2023-1-4-114-130
Abstract
The adsorption, protective and passivating effect of sodium salts of succinic, itaconic and a blend of alkenylsuccinic acids (SKAP-25) on the oxidized surface of copper and copper–nickel alloy MNZh5-1 in neutral buffer and chloride solutions was studied. The adsorption of sodium succinate and itaconate is adequately described by the full Temkin isotherm equation with the value of the free energy of adsorption (-Δ𝐺0𝑎) on oxidized copper at E=0.0 V being 77.4 and 65.4 kJ/mol, respectively. The values of (-Δ𝐺0𝑎) for these corrosion inhibitors on the preoxidized MNZh5-1 alloy electrode are 89.3 and 58.3 kJ/mol, respectively. Such values of (-Δ𝐺0𝑎) suggest chemisorption interaction of these organic anions with the oxidized surface of copper and its alloy. Corrosion tests of copper and alloy MNZh5-1 in solutions for 7 days showed that a formulation of SKAP with the sodium salt of 2-mercaptobenzothiazole.
About the Authors
Yu. I. Kuznetsov
A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Russian Federation
Russian Federation
119071
Leninskii pr. 31
Moscow
I. A. Kuznetsov
A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Russian Federation
Russian Federation
119071
Leninskii pr. 31
Moscow
N. P. Andreeva
A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Russian Federation
Russian Federation
119071
Leninskii pr. 31
Moscow
M. O. Agafonkina
A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Russian Federation
Russian Federation
119071
Leninskii pr. 31
Moscow
References
1. N. Kovačević, I. Milošev and A. Kokalj, How relevant is the adsorption bonding of imidazoles and triazoles for their corrosion inhibition of copper, Corros. Sci., 2017, 124, 25–34. Doi: 10.1016/j.corsci.2017.04.021
2. N.K. Allam, A.A. Nazeer and E.A. Ashour, A review of the effects of benzotriazole on the corrosion of copper and copper alloys in clean and polluted environments, J. Appl. Electrochem., 2009, 39, 961–969. doi: 10.1007/s10800-009-9779-4
3. M. Finšgar and I. Milošev, Inhibition of copper corrosion by 1,2,3-benzotriazole : A review, Corros. Sci., 2010, 52, 2737–2749. doi: 10.1016/j.corsci.2010.05.002
4. M. Petrović Mihajlović, M.M. Antonijević, Copper Corrosion Inhibitors. Period 2008–2014. A Review, Int. J. Electrochem. Sci., 2015, 10, 1027–1053. url
5. S.M. Milić, M.M. Antonijević and M.B. Petrović, Films formed on copper surface in chloride media in the presence of azoles, Corros. Sci., 2009. 51. 1228–1237. doi: 10.1016/j.corsci.2009.03.026
6. Yu.I. Kuznetsov, Triazoles as a class of multifunctional corrosion inhibitors. A review. Part I. 1,2,3-Benzotriazole and its derivatives. Copper, zinc and their alloys, Int. J. Corros. Scale Inhib., 2018, 7(3), 271–307. doi: 10.17675/2305-6894-2018-7-3-1
7. H. Huang, Z. Wang,Y. Gong, F. Gao, Z. Luo, S. Zhang and H. Li, Water soluble corrosion inhibitors for copper in 3.5 wt % sodium chloride solution. Corros. Sci., 2017, 123, 339–350. doi: 10.1016/j.corsci.2017.05.009
8. H. Otmacic Curkovic, E. Stupnisek-Lisac and H. Takenouti, The influence of pH value on the efficiency of imidazole based corrosion inhibitors of copper, Corros. Sci., 2010, 52(2), 398–405 doi: 10.1016/j.corsci.2009.09.026
9. E. Rocca, G. Bertrand, C. Rapin and J.C. Labrune, Inhibition of copper aqueous corrosion by non-toxic linear sodium heptanoate: mechanism and ECAFM study, J. Electroanal. Chem., 2001, 503, 133–140. doi: 10.1016/S0022-0728(01)00384-9
10. M. Оhsawa and W. Suetaka, Spectro-electrochemical studies of the corrosion inhibition of copper by mercaptobenzothiazole, Corros Sci., 1979; 19(10), 709–722.
11. G. Rajkumar and M.G. Sethuraman, Corrosion protection ability of self-assembled monolayer of 3-amino-5-mercapto-1,2,4-triazole on copper electrode, Thin Solid Films, 2014, 562, 32–36. doi: 10.1016/j.tsf.2014.03.074.
12. G. Chan-Rosado and M.A. Pech-Canul, Influence of native oxide film age on the passivation of carbon steel in neutral aqueous solutions with a dicarboxylic acid, Corros. Sci., 2019, 153, 19–31. doi: 10.1016/j.corsci.2019.03.033
13. F. Capriolim, A. Martinellim, V. DiCastrom and F. Decker, Effect of various terminal groups on long-term protective properties of aromatic SAMs on copper in acidic environment. J. Electroanal. Chem., 2013, 693, 86–94. doi: 10.1016/j.jelechem.2013.01.025
14. M.O. Agafonkina, Yu.I. Kuznetsov and N.P. Andreeva, Inhibitor Properties of Carboxylates and Their Adsorption on Copper from Aqueous Solutions, Russ. J. Phys. Chem. A, 2015, 89(6), 1070–1076. doi: 10.1134/S0036024415060023
15. E. Abelev, D. Starosvetsky, and Y. Ein-Eli, Enhanced Copper Surface Protection in Aqueous Solutions Containing Short-Chain Alkanoic Acid Potassium Salts, Langmuir, 2007, 23, 11281–11288 doi: 10.1021/la701434e
16. G.T. Hefter, N.A. North and S.H. Tan, Organic corrosion inhibitors in neutral solutions. Part 1. Inhibition of steel, copper and aluminum by straight chain carboxylates, Corrosion, 1997, 53, 657–667. doi: 10.5006/1.3290298
17. K. Aramaki and T. Shimura, Self-assembled monolayers of carboxylate ions on passivated iron for preventing passive film breakdown, Corros. Sci., 2004, 46, 313–328. doi: 10.1016/S0010-938X(03)00156-2
18. U. Rammelt, S. Köhler and G. Reinhard, Electrochemical characterization of the ability of dicarboxylic acid salts to the corrosion inhibition of mild steel in aqueous solutions, Corros. Sci., 2011, 53, 3515–3520. doi: 10.1016/j.corsci.2011.06.023
19. D. Lahem, M. Poelman, F. Atmani and M.G. Olivier, Synergistic improvement of inhibitive activity of dicarboxylates in preventing mild steel corrosion in neutral aqueous solutions, Corros. Eng., Sci. Technol., 2012, 47, 463–471. doi: 10.1179/1743278212Y.0000000030
20. G. Chan-Rosado and M.A. Pech-Canul, Influence of native oxide film age on the passivation of carbon steel in neutral aqueous solutions with a dicarboxylic acid, Corros. Sci., 2019, 153, 19–31. doi: 10.1016/j.corsci.2019.03.033
21. G. Žerjav and I. Milošev, Carboxylic Acids as Corrosion Inhibitors for Cu, Zn and Brasses in Simulated Urban Rain, Int. J. Electrochem. Sci., 2014, 9, 2696–2715.
22. A.D. Mercer, The properties of carboxilates as corrosion inhibitors for steel and other metals in neutral aqueous solutions, In Proceeding of the 5<sup>th</sup> Europ. Symp. on Corros. Inhib., Ferrara (Italy), 1980, 2, 563–581.
23. Yu.I. Kuznetsov, I.А. Kuznetsov and D.B. Vershok, Copper corrosion protection in neutral media by dicarboxylic acid salts, Int. J. Corros. Scale Inhib., 2019, 8(4), 1022–1034. doi: 10.17675/2305-6894-2019-8-4-13
24. ТУ 2499-080-05015207-2003. Назначение: добавка к антикоррозионному составу для устранения ржавления металлических поверхностей.
25. ГОСТ 492–2006. Никель, сплавы никелевые и медно-никелевые, обрабатываемые давлением. Марки.
26. R.M. Azzam and N.M. Bashara, Ellipsometry and Polarized Light, North-Holland, Amsterdam, 1977, 529 p.
27. P. Silva-Bermudez, S.E. Rodil and S. Muhl, Albumin adsorption on oxide thin films studied by spectroscopic ellipsometry, Appl. Surf. Sci., 2011, 258, 1711–1718. doi: 10.1016/j.apsusc.2011.10.020
28. L. Wang, C. Zhao, M.H.G. Duits, F. Mugele and I. Siretanu, Detection of ion adsorption at solid–liquid interfaces using internalreflection ellipsometry, Sens. Actuators, B, 2015, 210, 649–655. Doi: 10.1016/j.snb.2014.12.127
29. М.О. Agafonkina, N.P. Andreeva, Yu.I. Kuznetsov and S.F. Timashev, Substituted Benzotriazoles as Inhibitors of Copper Corrosion in Borate Buffer Solutions, Russian J. of Phys. Chem A., 2017, 91(8), 1414–1421 doi: 10.1134/S0036024417080027
30. M.O. Agafonkina, I.A. Kuznetsov, N.P. Andreeva and Yu.I. Kuznetsov, Copper protection with sodium salts of lower dicarboxylic acids in neutral aqueous solution. Int. J. Corros. Scale Inhib., 2020, 9(3), 1000–1013 doi: 10.17675/2305-6894-2020-9-3-13.
31. M.O. Agafonkina, I.A. Kuznetsov, Yu.I. Kuznetsov, O.Yu. Grafov and N.P. Andreeva, Corrosion inhibition of MNZh alloy with sodium salts of lower dicarboxylic acids in neutral aqueous solution, Int. J. Corros. Scale Inhib., 2021, 10(1), 349–367 doi: 10.17675/2305-6894-2020-10-1-20
Review
For citations:
Kuznetsov Yu.I., Kuznetsov I.A., Andreeva N.P., Agafonkina M.O. Protection of copper and MNZh5-1 alloy from corrosion by succency and alkenylsuction acids salts in chloride solution. Title in english. 2023;(4):114-130. (In Russ.) https://doi.org/10.61852/2949-3412-2023-1-4-114-130
Views:
193
Email this article 