Protection of low-carbon steel in hydrochloric acid solution with mixtures of inhibitors containing surfactants
https://doi.org/10.61852/2949-3412-2024-2-1-60-74
Abstract
The corrosion of low-carbon steel in 2 M HCl was studied in the temperature range t = 25-95°C. For this environment, the possibility of creating mixed corrosion inhibitors (CIs) containing surfactants – catamin AB and cocamidopropylbetaine (CAPB) – has been considered. It has been shown that the compositions catamin AB + urotropine and CAPB + urotropine are promising for the creation of effective CIs steel in 2 M HCl. The optimal total content of mixtures of CIs in an aggressive environment is 5 mM. The molar ratio of surfactant and urotropine in mixtures of CIs is 1:9. The composition of 0,5 mM CAPB + 4,5 mM urotropine effectively slows down the corrosion of 08PS steel in 2 M HCl at t≤60°C, ensuring a steel corrosion rate of no higher than 3.9 g/(m2×h). At t = 60°C, steel corrosion slows down by 27 times. The composition of 0,5 mM catamin AB + 4,5 mM urotropine inhibits steel corrosion more strongly. A significant decrease in the corrosion rate of steel in its presence is observed at t≤80°C, when it does not exceed 6.9 g/(m2×h). The corrosion process at t = 80°C is slowed down 90 times. It is noted that replacing single-component CIs with two-component mixtures makes it possible to increase the efficiency of steel protection and reduce the consumption of the most expensive components used for their production.
About the Authors
Ya. G. Avdeev
A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Russian Federation
Russian Federation
Leninskii pr. 31, 119071, Moscow
T. E. Andreeva
A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Russian Federation
Russian Federation
Leninskii pr. 31, 119071, Moscow
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For citations:
Avdeev Ya.G., Andreeva T.E. Protection of low-carbon steel in hydrochloric acid solution with mixtures of inhibitors containing surfactants. Title in english. 2024;(1):60-74. (In Russ.) https://doi.org/10.61852/2949-3412-2024-2-1-60-74
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