Влияние имидазолатного каркаса ZIF-8 на ингибирующий эффект аспартатов при атмосферной коррозии низкоуглеродистой стали
https://doi.org/10.61852/2949-3412-2025-3-1-137-163
Аннотация
Цель данного исследования – разработка нового нанокомпозитного летучего ингибитора коррозии (ZIF-AD) низкоуглеродистой стали за счет реакции между аспарагиновой кислотой и ди-н-бутиламином (AD) на цеолитном имидазолатном каркасе (zeolitic imidazolate framework-8, ZIF-8). Пористая структура ZIF-8 способствует распределению молекул аспарагиновой кислоты, уменьшая их агломерацию и повышая летучесть. Ингибирующее действие ZIF-AD в условиях окружающей среды достигается благодаря летучести этого соединения и его способности к адсорбции. Показано, что при использовании ингибитора на поверхности стали образуется защитная пленка, эффективно подавляющая катодную реакцию. Полученные результаты показывают, что ZIF-AD может потенциально использоваться в качестве высокоэффективного ингибитора коррозии низкоуглеродистой стали в атмосферных условиях.
Ключевые слова
летучий ингибитор коррозии,
низкоуглеродистая сталь,
атмосферная коррозия,
аспарагиновая кислота,
ZIF-8
При поддержке: Работа выполнена при поддержке Национального фонда естественных наук Китая (52071198) и Открытого фонда Шанхайской ведущей лаборатории защиты материалов и современных материалов в электроэнергетике, а также Министерства образования и науки РФ.
Об авторах
Хайни Ян
Шанхайский университет электроэнергетики
Китай
Китай
Шанхай 201306
Лян Ма
Шанхайский университет электроэнергетики
Китай
Китай
Шанхай 201306
Дацюань Чжан
Шанхайский университет электроэнергетики
Китай
Китай
Шанхай 201306
Сифэй Ань
Шанхайский университет электроэнергетики
Китай
Китай
Шанхай 201306
Чжэньи Цуй
Шанхайский университет электроэнергетики
Китай
Китай
Шанхай 201306
Н. Н. Андреев
ФГБУН Институт физической химии и электрохимии им. А.Н. Фрумкина Российской академии наук (ИФХЭ РАН)
Россия
Россия
19071, Москва, Ленинский проспект, д.31, корп. 4
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Рецензия
Для цитирования:
Ян Х., Ма Л., Чжан Д., Ань С., Цуй Ч., Андреев Н.Н. Влияние имидазолатного каркаса ZIF-8 на ингибирующий эффект аспартатов при атмосферной коррозии низкоуглеродистой стали. Коррозия: защита материалов и методы исследований. 2025;(1):137-163. https://doi.org/10.61852/2949-3412-2025-3-1-137-163
For citation:
Yang H., Ma L., Zhang D., An S., Cui Z., Andreev N.N. Influence of ZIF-8 on the inhibition effect of aspartates for atmospheric corrosion of mild steel. Title in english. 2025;(1):137-163. (In Russ.) https://doi.org/10.61852/2949-3412-2025-3-1-137-163
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