Influence of ZIF-8 on the inhibition effect of aspartates for atmospheric corrosion of mild steel
https://doi.org/10.61852/2949-3412-2025-3-1-137-163
Abstract
This study aims to develop a novel volatile corrosion inhibitor for mild steel by preparing a nanocomposite (ZIF-AD) through a salt-forming reaction between aspartic acid (AD) and din-butylamine, with zeolitic imidazolate framework-8 (ZIF-8) as the template material. The ZIF-8's porous structure is beneficial to disperse AD molecules, reducing agglomeration and enhancing volatility. Under ambient atmosphere, ZIF-AD achieves corrosion inhibition properties through volatilization and adsorption. It demonstrates that a protective film is formed on mild steel surfaces, effectively inhibiting the cathodic process of corrosion. Compared to AD alone, the incorporation of ZIF-8 increased the inhibition efficiency to 91%. These findings highlight the potential of ZIF-AD as a highly efficient corrosion inhibitor for mild steel in atmospheric environments.
About the Authors
H. Yang
Шанхайский университет электроэнергетики
China
China
L. Ma
Шанхайский университет электроэнергетики
China
China
D. Zhang
Шанхайский университет электроэнергетики
China
China
S. An
Шанхайский университет электроэнергетики
China
China
Z. Cui
Шанхайский университет электроэнергетики
China
China
N. N. Andreev
ФГБУН Институт физической химии и электрохимии им. А.Н. Фрумкина Российской академии наук (ИФХЭ РАН)
Russian Federation
Russian Federation
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For citations:
Yang H., Ma L., Zhang D., An S., Cui Z., Andreev N.N. Influence of ZIF-8 on the inhibition effect of aspartates for atmospheric corrosion of mild steel. Title in english. 2025;(1):137-163. (In Russ.) https://doi.org/10.61852/2949-3412-2025-3-1-137-163
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