On obtaining coatings with multimodal roughness on low-carbon steel by thermochemical method
Abstract
The possibility of obtaining a coating with multimodal roughness on low-carbon steel by thermal oxidation in nitrate-phosphate solution as the first step in the formation of a superhydrophobic surface was shown. To determine the coating with optimal characteristics we varied the solution composition, temperature and oxidation time. The phase composition of the obtained coating was studied. Ethanol solution of stearic acid was used as a hydrophobizing agent. It was shown that the formed superhydrophobic surface is comparable in its characteristics with the coating obtained after laser burning and has good protective properties
About the Author
D. B. VershokRussian Federation
119071 Leninskiy Prosp., Moscow
References
1. Л.Б. Бойнович и А.М. Емельяненко, Гидрофобные материалы и покрытия: принципы создания, свойства и применение, Успехи химии, 2008, 77(7), 619–638. doi: 10.1070/RC2008v077n07ABEH003775
2. S. Naha, S. Sen, I.K. Puri, Flame synthesis of superhydrophobic amorphous carbon surfaces, Carbon, 2007, 45, 1696–1716. doi:10.1016/j.carbon.2007.04.015
3. Y. Zhou, B. Wang, X. Song, E. Li, G. Li, S. Zhao and H. Yan, Control over the wettability of amorphous carbon films in a large range from hydrophilicity to superhydrophobicity, Appl. Surf. Sci., 2006, 253(5), 2690–2694. doi: 10.1016/j.apsusc.2006.05.118
4. С.В. Гнеденков, В.С. Егоркин, С.Л. Синебрюхов, И.Е. Вялый, А.М. Емельяненко и Л.Б. Бойнович, Супергидрофобные защитные покрытия на сплаве алюминия, Вестник ДВО РАН, 2014, 2, 52–61.
5. A. Hozumi and O. Takai, Preparation of Ultra Water Repellent Films by Microwave Plasma Enhanced CVD. Thin Solid Film, 1997, 303(1–2), 222–225. doi: 10.1016/S0040-6090(97)00076-X
6. Способ придания супергидрофобных свойств поверхности металла. Патент RU 2605401, Л.Б. Бойнович и А.М. Емельяненко Дата публ. 20.12.2016.
7. G.V. Redkina, A.S. Sergienko and Y.I. Kuznetsov, Hydrophobic and anticorrosion properties of thin phosphonate–siloxane films formed on a laser textured zinc surface, Int. J. Corros. Scale Inhib., 2020. 9(4), 1550–1563. doi: 10.17675/2305-6894-2020-9-4-23
8. A.M. Semiletov, A.A. Kudelina and Y.I. Kuznetsov, New prospects in the application of superhydrophobic coatings and corrosion inhibitors, Int. J. Corros. Scale Inhib., 2022. 11(3), 1388–1400. doi: 10.17675/2305-6894-2022-11-3-28
9. D.A. Alpysbaeva, D.B. Vershok, A.M. Emel’yanenko, O.V. Batishchev, Yu.I. Kuznetsov and L.B. Boinovich, Superhydrophobization of low-carbon steel with conversion coatings, Prot. Met. Phys. Chem. Surf., 2014, 50(7), 898–902. doi: 10.1134/S207020511407003X
10. П.К. Лаварко, Оксидные покрытия металлов. М., Машгиз, 1963. 186 с.
Review
For citations:
Vershok D.B. On obtaining coatings with multimodal roughness on low-carbon steel by thermochemical method. Title in english. 2023;(2):30-36. (In Russ.)