Изучение и моделирование адсорбции железо (II) и фосфат- ионов на магнетите в слабокислых и слабощелочных средах
https://doi.org/10.61852/2949-3412-2026-4-2-154-175
Аннотация
В результате проведенного моделирования адсорбции железо (II) и фосфат-ионов на поверхности оксида железа при различных значениях рН было показано, что двойной электрический слой (ДЭС), возникающий на границе раздела оксид железа/раствор электролита, оказывает существенное влияние на адсорбционные явления. Особенно велика роль величины концентрации ионов водорода и потенциала на границе раздела оксид железа/раствор электролита. При описании адсорбции, обращается внимание на необходимость учёта кислотно-основных равновесий, возникающий на границе раздела оксид железа/раствор электролита. Найдено, что закономерности адсорбционного поведения железо (II) и фосфат-ионов в каждом случаи описываются набором пяти равновесий, имеющих место на границе оксид железа/раствор электролита, которые соответствуют идеям трехслойной модели (Triplet layer model, TLM).
Об авторах
А. В. Кузин
Московский педагогический государственный университет;
МГТУ им. Н.Э. Баумана
Россия
Россия
Москва
В. В. Кузнецов
МГТУ им. Н.Э. Баумана
Россия
Россия
Москва
В. А. Шелонцев
Омская гуманитарная академия
Россия
Россия
Омск
Е. А. Елисеева
МГТУ им. Н.Э. Баумана
Россия
Россия
Москва
С. Л. Березина
МГТУ им. Н.Э. Баумана
Россия
Россия
Москва
А. С. Самадов
Таджикский национальный университет
Таджикистан
Таджикистан
Душанбе
Список литературы
1. R.M. Cornell, The Iron Oxides: Structure, Properties, Reactions, Occurrences and Uses / M. Cornell Rochelle, Schwertmann Udo. Wiley, 2003, 664 p.
2. G. Sposito The Environmental Chemistry of Aluminum. 2nd Ed. Boca Raton, FL: СRC Press, 1996, 480 p.
3. D.A. Dzombak and F.M. Morel Surface Complexation Modeling: Hydrous Ferric Oxide. Wiley, 1990, 416 p.
4. M.A. Blesa, A.D. Weisz, P.J. Morando, J.A. Salfity, G.E. Magaz and A.E. Regazzoni, The interaction of metal oxide surfaces with complexing agents dissolved in water, J. Coord. Chem. Rev., 2000, 196, 31–63. doi: 10.1016/S0010-8545(99)00005-3
5. J.A. Devis and J.O. Lackie, Surface ionization and complexation at the oxide/water interface, J. Colloid Interface Sci., 1978, 67, No. 1, 90–107.
6. G.A. Parks, The study of the zero point of change of oxide, Chem. Rev., 1965, 65, 177–183.
7. E.A. Deliyanni, E.N. Peleka and N.K. Lazaridis, Comparative study of phosphates removal from aqueous solutions by nanocrystalline akaganeite and hybrid surfactant-akaganeite, Sep. Purif. Technol., 2007, 52, 478–486. doi: 10.1016/j.seppur.2006.05.028
8. M.I. Tejedor-Tejedor and M.A. Anderson, The protonation of phosphate on the surface of goethite as studied by CIR-FTIR and electrophoretic mobility, Langmuir, 1990, 6, 602–611.
9. P. Persson, N. Nilsson and S. Sjoberg, Structure and bonding of orthophosphate ions at the iron oxide-aqueous interface, J. Colloid Interface Sci., 1996, 177, 263–275.
10. Y. Arai and D.L. Sparks, ATR-FTIR spectroscopic investigation on phosphate adsorption mechanisms at the ferrihydrite-water interface, J. Colloid Interface Sci., 2001, 241, 317–326. Doi: 10.1006/jcis.2001.7773
11. C. Luengo, M. Brigante, J. Antelo and M. Avena, Kinetics of phosphate adsorption on goethite: comparing batch adsorption and ATR-IR measurements, J. Colloid Interface Sci., 2006, 300, 511–518. doi: 10.1016/j.jcis.2006.04.015
12. J. Antelo, M. Avena, S. Fiol, R. Lopez and F. Arce, Effects of pH and ionic strength on the adsorption of phosphate and arsenate at the goethite-water interface, J. Colloid Interface Sci., 2005, 285, 476–486. doi: 10.1016/j.jcis.2004.12.032
13. R. Chitrakar, S. Tezuka, A. Sonoda, K. Sakane, K. Ooi and T. Hirotsu, Phosphate adsorption on synthetic goethite and akaganeite, J. Colloid Interface Sci., 2006, 298, 602–608. Doi: 10.1016/j.jcis.2005.12.054
14. L. Li and R. Stanforth, Distinguishing adsorption and surface precipitation of phosphate on goethite (alphaFeOOH), J. Colloid Interface Sci., 2000, 230, 12–21. doi: 10.1006/jcis.2000.7072
15. B.N. Bijsterbosch, Electrical Double Layers at Interface Between Colloidal Materials and Ionic Solutions. In Trends in Interfacial Electrochemistry, Ed. A.F. Silva. N.Y. Riedel Publishing Company, 1986, 187–204.
16. Б.Б. Дамаскин и О.А. Петрий, Введение в электрохимическую кинетику. М.: Высшая школа. 1983, 400 с.
17. С.И. Печенюк, Ю.П. Семушина и Л.Ф. Кузьмич, Оценка содержания и природы сорбционных центров оксигидроксидов железа (III) и циркония(IV), Изв. АН. Серия хим, 2005, № 8, 1736–1741.
18. G. Sposito, On the surface complexation model of the oxide-aqueous solution interface, J. Colloid Interface Sci., 1983, 91, 329–340. doi: 10.1016/0021-9797(83)90345-4
19. J.P. Gustafsson, Modelling molybdate and tungstate adsorption to ferrihydrite, J. Chem. Geol., 2003, 200, 105–115. doi: 10.1016/S0009-2541(03)00161-X
20. J. Westall and H. Hohl, A comparison of electrostatic models for the oxide/solution interface, Adv. Colloid Interface Sci., 1980, 12, 265–294. doi: 10.1016/0001-8686(80)80012-1
21. J.A. Devis, R.D. James and J.O. Lackie, Surface ionization and complexation at the oxide/water interface, J. Colloid Interface Sci., 1978, 63, No. 3, 480–499. doi: 10.1016/S0021-9797(78)80009-5
22. J.A. Devis and J.O. Lackie, Adsorption of anions, J. Colloid Interface Sci., 1980, 74(1), 32–43. doi: 10.1016/0021-9797(80)90168-X
23. A.L. Herbelin and J.C. Westall, FITEQL 4.0: A Computer Program for Determination of Chemical Equilibrium Constants from Experimental Data. Technical Report 99-01. Department of Chemistry, Oregon State University, 1999.
24. И.Г. Горичев и В.В. Батраков, Поверхностный заряд как функция потенциала на границе раздела оксид/электролит, Электрохимия. 1992. 28, №1, 14–18.
25. G.R. Wiese, R.O. James, D.E. Jates and T.W. Healy Electrochemistry of the colloid/water interface, Intern. Rev. Sci., 1976, 6, 53–103.
26. E.J. Elzinga and D. Sparks, Phosphate adsorption onto hematite: an in situ ATR-FTIR investigation of the effects of pH and loading level on the mode of phosphate surface complexation, J. Colloid Interface Sci. 2007, 308, 53–70. doi: 10.1016/j.jcis.2006.12.061
27. J. Kim, W. Li, B.L. Philips and C.P. Grey, Phosphate adsorption on the iron oxyhydroxides goethite (α-FeOOH), akaganeite (α-FeOOH), and lepidocrocite (α-FeOOH): a 31P NMR study, J. Energy Environ. Sci., 2011, 4, 4298–4305. doi: 10.1039/C1EE02093E
28. E.J. Elzinga and R. Kretzschmar, In situ ATR-FTIR spectroscopic analysis of the co-adsorption of orthophosphate and Cd(II) onto hematite, Geochim. Cosmochim. Acta, 2013, 117, 53–64. doi: 10.1016/j.gca.2013.04.003
29. M.A.G. Hinkle, Z. Wang, D.E. Giammar and J.G. Catalano, Interaction of Fe(II) with phosphate and sulfate on iron oxide surfaces, Geochim. Cosmochim. Acta. 2015, 158, 130–146. Doi: 10.1016/j.gca.2015.02.030
30. G. Horanyi and P. Joo, Some peculiarities in the specific adsorption of phosphate ions on hematite and gamma-Al2O3 as reflected by radiotracer studies, J. Colloid Interface Sci., 2002, 247, 12–17. doi: 10.1006/jcis.2001.8103
31. X. Huang, Intersection of isotherms for phosphate adsorption on hematite, J. Colloid Interface Sci., 2004, 271, 296–307.doi: 10.1016/j.jcis.2003.12.007
32. A. Breeuwsma and J. Lyklema, Physical and chemical adsorption of ions in the electrical double layer on hematite (α-Fe2O3), J. Colloid Interface Sci., 1973, 43, 437–448. doi: 10.1016/0021-9797(73)90389-5
33. X. Huang, G.D. Foster, R.V. Honeychuck and J.A. Schreifels, The Maximum of Phosphate Adsorption at pH 4.0: Why It Appears on Aluminum Oxides but Not on Iron Oxides, Langmuir, 2009, 25, no. 8, 4450–4461. Doi: 10.1021/la803302m
34. T. Sugimoto, A. Muramatsu, K. Sakata and D. Shindo, Characterization of Hematite Particles of Different Shapes, J. Colloid Interface Sci., 1993, 158, 420–428. doi: 10.1006/jcis.1993.1274
35. C. Colombo, V. Barron and J. Torrent, Phosphate adsorption and desorption in relation to morphology and crystal properties of synthetic hematites, Geochim. Cosmochim. Acta, 1994, 58, 1261–1269. doi: 10.1016/0016-7037(94)90380-8
36. V. Barron, M. Herruzo and J. Torrent, Phosphate Adsorption by Aluminous Hematites of Different Shapes, Soil Sci. Soc. Am. J., 1988, 52, 647–651. doi: 10.2136/sssaj1988.03615995005200030009x
37. С.И. Печенюк и Ю.П. Семушина, Сорбция фосфат-ионов на оксигидроксидах Fe(III), Zr(IV) и Cr(III) из водных растворов электролитов, Журнал физической химииб 2007, 81, №8, 1473–1478.
38. Y.F. Lin, H.W. Chen, C.C. Chang, W.C. Hung and C.S. Chiou, Enhanced adsorption of phosphate from aqueous solution using iron hydroxide/modified diatomite, J. Chem. Technol. Biotechnol., 2011, 86, no. 11, 1449–1456. Doi: 10.1002/jctb.2665
39. A. Zach-Maor, R. Semiat and H. Shemer, Adsorption–desorption mechanism of phosphate by immobilized nano-sized magnetite layer: Interface and bulk interactions, J. Colloid Interface Sci., 2011, 363, 608–614. doi: 10.1016/j.jcis.2011.07.062
40. K.M. Giannoulis, G.Z. Tsogas, D.L. Giokas and A.G. Vlessidis, Dispersive micro-solid phase extraction of ortho-phosphate ions onto magnetite nanoparticles and determination as its molybdenum blue complex, J. Talanta, 2012, 99, 62–68. Doi: 10.1016/j.talanta.2012.05.021
41. A. Zach-Maor, R. Semiat and H. Shemer, Fixed bed phosphate adsorption by immobilized nano-magnetite matrix: experimental and a new modeling approach, J. Adsorption, 2011, 17, 929–936. doi: 10.1007/s10450-011-9371-1
42. T.J. Daou, S. Begin-Colin, J.M. Greneche, F. Thomas, A. Derory, P. Bernhardt, P. Legare and G. Pourroy, Phosphate Adsorption Properties of Magnetite-Based Nanoparticles, J. Chem. Mater., 2007, 19, 4494–4505. doi: 10.1021/cm071046v
43. N. Karapinara, E. Hoffmann and H.H. Hahn, P-recovery by secondary nucleation and growth of calcium phosphates on magnetite mineral, J. Water research., 2006, 40, 1210–1216. Doi: 10.1016/j.watres.2005.12.041
44. X. Li, Y. Tang and G. Ge, Preparation and ξ-potential characterization of highly dispersible phosphate – functionalized magnetite nanoparticles, Sci. China Phys. Mech. Astron, 2011, 54, no. 10, 1766–1770. doi: 10.1007/s11433-011-4481-z
45. A. Zach-Maor, R. Semiat and H. Shemer, Synthesis, performance, and modeling of immobilized nano-sized magnetite layer for phosphate removal, J. Colloid Interface Sci., 2011, 357, 440–446. doi: 10.1016/j.jcis.2011.01.021
46. T.J. Daou, G. Pourroy, S. Begin-Colin, J.M. Greneche, C. Ulhaq-Bouillet, P. Legare, P. Bernhardt, C. Leuvrey and G. Rogez, Hydrothermal Synthesis of Monodisperse Magnetite Nanoparticles, J. Chem. Mater., 2006, 18, 4399–4404. doi: 10.1021/cm060805r
47. D.R. Hatter, The use and importance of nitroaromatic chemicals in the chemical industry, Toxicity of Nitroaromatic Compounds (D.E. Rickert, editors), 1985, 1–13
48. J. Klausen, S.P. Trober, S.B. Haderlein and R.P. Schwarzenbach, Reduction of Substituted Nitrobenzenes by Fe(II) in Aqueous Mineral Suspensions, Environ. Sci. Technol., 1995, 29, 2396–2404. doi: 10.1021/es00009a036
49. T.P. Klupinski, Y.P. Chin and S.J. Traina, Abiotic degradation of pentachloronitrobenzene by Fe(II): Reactions on goethite and iron oxide nanoparticles, Environ. Sci. Technol., 2004, 38, 4353–4360. doi: 10.1021/es035434j
50. F.B. Li, X.G. Wang, Y.T. Li, C.S. Liu, F. Zeng, L.J. Zhang, M.D. Hao and H.D. Ruan, Enhancement of the reductive transformation of pentachlorophenol by soil colloids, J. Colloid Interface Sci., 2008, 321, 332–341. doi: 10.1016/j.jcis.2008.02.033
51. W. Stumm and B. Sulzberger, The cycling of iron in natural environments: Considerations based on laboratory studies of heterogeneous redox processes, Geochim. Cosmochim. Acta, 1992, 56, 3233–3257. doi: 10.1016/0016-7037(92)90301-X
52. L. Tao, F. Li, Chunhua Feng and K. Sun, Reductive Activity of Adsorbed Fe(II) on Iron (Oxyhydr)Oxides for 2-Nitrophenol Transformation, Clays Clay Miner., 2010, 58, no. 5, 682–690. doi: 10.1346/CCMN.2010.0580507
53. M.M. Benjamin and J.O. Leckie, Multiple-site adsorption of Cd, Cu, Zn, and Pb on amorphous iron oxyhydroxide, J. Colloid Interface Sci., 1981, 79, 209–221. doi: 10.1016/0021-9797(81)90063-1
54. G.V. Nano and T.J. Strathmann, Ferrous iron sorption by hydrous metal oxides, J. Colloid Interface Sci., 2006, 297, 443–454. doi: 10.1016/j.jcis.2005.11.030
55. B.H. Jeon, B.A. Dempsey and W.D. Burgos, Kinetics and Mechanisms for Reactions of Fe(II) with Iron(III) Oxides, Environ. Sci. Technol., 2003, 37, 3309–3315. doi: 10.1021/es025900p
56. L. Charlet, E. Liger and P. Gerasimo, Decontamination of TCE- and U-rich waters by granular iron: role of sorbed Fe(II), J. Environ. Eng., 1998, 124, 25–30. doi: 10.1061/(ASCE)0733-9372(1998)124:1(25)
57. E. Liger, L. Charlet and P. Van Cappellen, Surface catalysis of uranium(VI) reduction by iron(II), Geochim. Cosmochim. Acta., 1999, 63, 2939–2955. doi: 10.1016/S0016-7037(99)00265-3
Рецензия
Для цитирования:
Кузин А.В., Кузнецов В.В., Шелонцев В.А., Елисеева Е.А., Березина С.Л., Самадов А.С. Изучение и моделирование адсорбции железо (II) и фосфат- ионов на магнетите в слабокислых и слабощелочных средах. Коррозия: защита материалов и методы исследований. 2026;(2):154-175. https://doi.org/10.61852/2949-3412-2026-4-2-154-175
For citation:
Kuzin A.V., Kuznetsov V.V., Shelontsev V.A., Eliseeva E.A., Berezina S.L., Samadov A.S. Study and modeling of iron (II) and phosphate ions adsorption on magnetiteightly acid and slightly alkaline environments. Title in english. 2026;(2):154-175. (In Russ.) https://doi.org/10.61852/2949-3412-2026-4-2-154-175
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